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毕业论文网 > 任务书 > 材料类 > 高分子材料与工程 > 正文

芳族羟甲基单体微孔有机物的合成及其应用任务书

 2020-06-03 22:05:35  

1. 毕业设计(论文)的内容和要求

毕业设计(论文)的内容和要求: 毕业论文内容: 毕业论文是对大学四年学习情况以及对所做的课题情况的反映,其内容应该包括: a) 查阅相关文献资料,提出实验计划,明确实验内容。

b) 写出文献综述,了解本课题最新研究进展 c) 认真实验,确定最佳工艺条件。

通过实验研究芳族羟甲基单体微孔有机物对对硝基苯酚的吸附能力,及以其为基体材料负载贵金属催化剂对对硝基苯酚催化性能的影响。

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2. 参考文献

[1] Dong, Z., Le, X., Liu, Y., Dong, C., Ma, J. (2014). Metal organic framework derived magnetic porous carbon composite supported gold and palladium nanoparticles as highly efficient and recyclable catalysts for reduction of 4-nitrophenol and hydrodechlorination of 4-chlorophenol. Journal of Materials Chemistry A, 2(44), 18775-18785. [2] Hu, H., Xin, J. H., Hu, H., Wang, X., Miao, D., Liu, Y. (2015). Synthesis and stabilization of metal nanocatalysts for reduction reactions - a review. Journal of Materials Chemistry A, 3(21), 11157-11182. [3] Lee, J., Park, J. C., Song, H. (2008). A Nanoreactor Framework of a Au@SiO2 Yolk/Shell Structure for Catalytic Reduction of p-Nitrophenol. Advanced Materials, 20(8), 1523-1528. [4] Li, H., Meng, B., Chai, S.-H., Liu, H., Dai, S. (2016). Hyper-crosslinked [small beta]-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules. Chemical Science, 7(2), 905-909. [5] Li, J., Liu, C.-y., Liu, Y. (2012). Au/graphene hydrogel: synthesis, characterization and its use for catalytic reduction of 4-nitrophenol. Journal of Materials Chemistry, 22(17), 8426-8430. [6] Liu, R., Mahurin, S. M., Li, C., Unocic, R. R., Idrobo, J. C., Gao, H., . . . Dai, S. (2011). Dopamine as a Carbon Source: The Controlled Synthesis of Hollow Carbon Spheres and Yolk-Structured Carbon Nanocomposites. Angewandte Chemie International Edition, 50(30), 6799-6802. [7] Luo, Y. L., Zhang, S. C., Ma, Y. X., Wang, W., Tan, B. (2013). Microporous organic polymers synthesized by self-condensation of aromatic hydroxymethyl monomers. Polymer Chemistry, 4(4), 1126-1131. [8] Wang, Y., Wei, G., Zhang, W., Jiang, X., Zheng, P., Shi, L., Dong, A. (2007). Responsive catalysis of thermoresponsive micelle-supported gold nanoparticles. Journal of Molecular Catalysis A: Chemical, 266(1#8211;2), 233-238. [9] Xia, Y., Deng, X., Yan, S., Gao, C., Ma, C., Jin, L. (2015). Nanoporous gold film: fabrication and role as a catalytic reactor. Dalton Transactions, 44(26), 11929-11934. [10] Xia, Y., Li, T., Ma, C., Gao, C., Chen, J. (2014). Au/montmorillonite/polyaniline nanoflakes: facile fabrication by self-assembly and application as catalyst. RSC Advances, 4(39), 20516-20520. [11] Yang, M.-Q., Pan, X., Zhang, N., Xu, Y.-J. (2013). A facile one-step way to anchor noble metal (Au, Ag, Pd) nanoparticles on a reduced graphene oxide mat with catalytic activity for selective reduction of nitroaromatic compounds. CrystEngComm, 15(34), 6819-6828. [12] Zhang, H., Yang, X. (2010). Synthesis of tetra-layer polymer composite microspheres and the corresponding hollow polymer microspheres with Au nanoparticles functionalized movable cores. Polymer Chemistry, 1(5), 670-677.

3. 毕业设计(论文)进程安排

毕业设计(论文)进程安排: 2016.12~2017.1检索国内外相关文献和专著,了解微孔聚合物的研究进展,初步选定原料及反应条件,制定实验初步方案。

2017.1~2017.3 合成芳族羟甲基单体微孔聚合物,并对其结构和性能进行表征和分析,对实验方案进行改进。

2017.3~2017.5 制备负载贵金属催化剂,对对硝基苯酚进行吸附和催化测试。

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