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毕业论文网 > 任务书 > 材料类 > 高分子材料与工程 > 正文

乙烯基离子液体共聚物的聚合与表面能研究任务书

 2020-06-04 20:26:06  

1. 毕业设计(论文)的内容和要求

主要内容包括: 通过共聚甲基丙烯酸甲酯和丙烯酸六氟丁酯,重点研究该掺混体系的表面能与相分离行为。

将离子液体与该共聚物进行混合,并通过小角x射线衍射方法(saxs)进行相分离行为研究,从而归纳出离子液体掺入对嵌段共聚物相分离的影响规律。

具体分为: 第一周~第二周:文献查阅 查阅有关离子液体以及嵌段共聚物方面的文献,要求学习并掌握利用中国期刊网、ca、ei、elsevier等查阅文献,不少于30篇。

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2. 参考文献

[1]吉海燕.甲基丙烯酸乙酯的”活性”/可控阴离子聚合.高分子材料科学与工程,2007,23 -2 [2]胡自强.以维生素C为还原剂、AGET_ATRP为引发体系引发的甲基丙烯酸甲酯活性自由基聚合.华东理工大学学报(自然科学版)2008-08 [3]杨武.反向原子转移自由基聚合法在铜表面接枝聚离子液体刷.西北师范大学学报(自然科学版)2010,46 -3 [4]李达.离子液体在自由基聚合反应中的应用研究进展.高分子通报,2006-7 [5]杨美珠.离子液体在原子转移自由基聚合反应中的研究进展.广东化工,2007-10 [6]张二琴.离子液体及其在高分子合成中的应用.开封教育学院学报,2009,29 -4 [7]闫振龙.有机非金属盐阴离子聚合研究进展.高分子通报,2014,04-002 [8]赵大成.室温离子液体中的聚合反应.化学进展,2005,17-4 [9]周严霞.基于离子液体微乳液中的AGETATRP及聚离子液体的自组装研究 .苏州大学硕士学位论文,2012 [10]吴连斌.甲基咪唑乙酸盐介质中CuBr催化的MMA活性聚合.高分子功能学报,2008,21 -4 [11]张红燕 .以离子液体为溶剂的原子转移自由基聚合反应研究.东华大学硕士学位论文,2008 [12]孙颖.单电子转移活性自由基聚合法制备水溶性聚合物.东北石油大学硕士学位论文,2011 [13]班璐 .活性_可控自由基聚合的分子印迹整体柱的制备及性能评价.天津医科大学硕士学位论文,2013 [14]邓之俊.基于碱性离子液体和磺基水杨酸催化剂的活性自由基聚合.苏州大学硕士学位论文,2013 [15]丁伟.离子液体中单电子转移活性自由基聚合法制备星形聚丙烯酰胺.应用化学,2011,28-10 [16]陈敏.碱性离子液体催化金属调节的甲基丙烯酸的电子转移活化原子转移自由基聚合.应用化学,2014,31 -5 [17]周艳青.离子液体在高分子合成中的应用.化工技术与开发,2014,43-5 [18]杨美珠.离子液体在原子转移自由基聚合反应中的研究进展.广东化工,2007,34 -134 [19]Hang Zhang.Fabrication of an ionic liquid-based macroporous polymer monolithic column via atom transfer radical polymerization for the separation of small molecules.Talanta,149 (2016) 62#8211;68 [20]Guoxiang Wang.Preparation of poly(methyl methacrylate) by ATRP using initiators for continuous activator regeneration (ICAR) in ionic liquidmicroemulsions.Polymer 53 (2012) [21]Lin Chun-xiang.Preparation of cellulose graft poly(methyl methacrylate) copolymers by atom transfer radical polymerization in an ionic liquid.Carbohydrate Polymers, 78 (2009) 432#8211;438 [22]Athina Anastasaki.Synthesis of Well-Defined Poly(acrylates) in Ionic Liquids via Copper(II)-Mediated Photoinduced Living Radical Polymerization.AmericanChemical Society,5140 [23]Hou Chen.Application of novel ionic liquids for reverse atomtransfer radical polymerization of methacrylonitrile without any additionalligand.Shanghai JiaoTongJUniversity,2009 [24]Guo-Xiang Wang.Reactivity ratios of controlledliving copolymerization.J Polym Res (2013) 2080 [25]Adrian J. Carmichael.Copper(I) mediated living radical polymerisation in an ionic liquid.The Royal Society of Chemistry 2000,1237#8211;1238 [26]Yi-bo Wu.Cationic polymerization of isobutyl vinyl ether in an imidazole-based ionic liquid characteristics and mechanism.Polymer Chemistry, 2015, 6, 2560 [27]Guoyou Cui.Organostibine-Mediated Controlled-Living Radical Polymerization of Methyl.Macromolecular_Chemistry_and_Physics,2010 [28]Jing Ma.SET-LRP_of_acrylonitrile_in_ionic_liquids_without_any_ligand.OURNAL OF POLYMER SCIENCE PART A POLYMER CHEMISTRY 2012, 50, 609#8211;613 [29Fast and green living cationic ring openingpolymerization of 2-ethyl-2-oxazoline in ionic liquids under microwaveirradiation.The Royal Society of Chemistry 2006, 3797#8211;3799 [30]Clement Appiah.Hierarchically Mesostructured Polyisobutylene-Based IonicLiquids.Macromol. Rapid Commun. 2016, DOI 10.1002marc.201600020 [31]Shuo Feng.Highly Controlled Organotellurium-Mediated Living RadicalPolymerization (TERP) in Ionic Liquids (ILs). The New Role of ILs inRadical Reactions.American Chemical Society,2012, 1, 146#8722;149 [32]Chunxiang Lin.Functionalization of chitosan via single electron transfer living radical polymerization in an ionic liquid and its antimicrobial activity.J. APPL. POLYM. SCI. 2015, DOI 10.1002APP.42754 [33]Chenyang Xing.Local Grafting of Ionic Liquid in Poly(vinylidenefluoride) Amorphous Region and the Subsequent Microphase SeparationBehavior in Melt.Macromol. Rapid Commun. 2016, DOI 10.1002marc.201600228 [34]Segolene Brusseau.Nitroxide-Mediated ControlledLiving Radical Copolymerization of Methyl Methacrylate with a Low Amount of Styrene in Ionic Liquid.Macromolecules 2011, 44, 215#8211;220 [35]Julia.Ryan.FirstNitroxide-Mediated Controlled-Living Free.al-2004-Macromolecular_Rapid_Communications.MacromolRapid Commun. 2004, 25, 930#8211;934 [36]Roy Diana Vagelos Laboratories.Catalytic Effect of Ionic Liquids in the Cu2O 2,20-bipyridine Catalyzed Living Radical Polymerization of Methyl Methacrylate Initiated with Arenesulfonyl Chlorides. [37]akeshi Ueki and Ryo Yoshida.Recent aspects of self-oscillating polymeric materialsdesigning self-oscillating polymers coupled with supramolecular chemistryand ionic liquid science.Phys. Chem. Chem. Phys., 2014, 16,

3. 毕业设计(论文)进程安排

17. 2.22-17. 2.28 文献查阅,了解课题 17. 2.29-17.3.13 英文文献翻译以及完成开题报告 17.3.14-17.4.1 按照实验计划进行试验 17.4.2-17.4.4 清明节休假 17.4.5-17.4.27 按照实验计划进行试验 17.4.28-17.4.30 进行中期检查 17.5.1-17.5.3 劳动节休假 17.5.4-17.5.31 进行实验并整理数据 17.6.1-17.6.14 撰写完成毕业论文 17.6.15-17.6.21 毕业论文答辩

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