基于ABE发酵产物制备液体燃料的研究任务书
2020-06-06 09:50:41
1. 毕业设计(论文)的内容和要求
1,了解生物质能源的意义以及制备生物质能源的路径,本课题的意义和现阶段国内外课题组在这一方面的进展;
2,了解本课题实验过程中氧化体系的建立和羟醛缩合反应的进展以及常规有机实验优化反应的过程;
3,了解不同催化剂对反应体系的影响以及如何构建高效,绿色环保的催化剂催化反应体系;
2. 参考文献
1. durre, p. new insights and novel developments in clostridial acetone/butanol/isopropanol fermentation. appl. microbiol. biotechnol. 49, 639-648 (1998).
2. durre, p. fermentative butanol production bulk chemical and biofuel. ann. n y acad. sci. 1125, 353-362 (2008).
3. jones, d.t. amp; woods, d.r. acetone-butanol fermentation revisited. microbiol. rev. 50, 484-524 (1986).
4. green, e.m. fermentative production of butanol-the industrial perspective. curr. opin. biotechnol. 22, 337#8211;343 (2011).
5. huber, g.w., cortright, r.d. amp; dumesic, j.a. renewable alkanes by aqueous-phase reforming of biomass-derived oxygenates. angew. chem. int. ed. engl. 43, 1549-1551 (2004).
6. dellomonaco, c., clomburg, j.m., miller, e.n. amp; gonzalez, r. engineered reversal of the β-oxidation cycle for the synthesis of fuels and chemicals. nature 476, 355#8211;360 (2011).
7. m. guerbet, c. r. acad.sci. 1899, 128,511-513.
8. w. markownikoff, p. zuboff, ber.dtsch. chem. ges. 1901, 34,3246 #8211;3249.
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11. l.e.gast, e. d. bitner,j.c.cowan, h. m. teeter, j. am. oil chem. soc. 1958, 35,703-707.
3. 毕业设计(论文)进程安排
1,阅读文献,完成开题报告;
2,建立实验计划,先完成醇氧化到醛的反应体系;
3,以氧化后的醛为底物进行羟醛缩合反应;