1. 毕业设计（论文）的内容和要求

以苯部分加氢得到的环己烯为原料，以廉价易得且稳定的醋酸为反应夹带剂，开展10 万吨/年环己烯酯化法生产醋酸环己酯的工艺设计，反应原子经济性高、环己醇收率高，具有经济环保的双重优势。

2. 参考文献

[1] 单祥磊. 环己烯水合制备环己醇催化反应过程的研究[D]. 上海:华东理工大学, 2011. [2] 张莹，张晓娟，唐丽华. 环己烷氧化制环己醇和环己酮技术的研究进展[J]. 广州化工，2012, 40(10): 14-16. [3] 郭治武，金海波，佟泽明. 环己酮、环己醇制备技术进展[J]. 化工进展, 2006, 25(8): 852-858. [4] Fang D R, Lu J Y, Zhang H M. Catalysts for Hydration of Cyclohexene With Zeolites[J]. Catalysis Surveys from Japan, 1997, 1(2): 241-246. [5] Yuan P Q, Liu Y, Bai F, et al. Hydration of Cyclohexene in Sub-critical Water over WOx-ZrO2 Catalysts[J]. Catalysis Communications, 2011, 12(8): 753-756. [6]吴济民，戴新民，陈聚良. 环己烯水合反应生成环己醇工艺条件的优化[J]. 化工进展, 2003, 22(11): 1222-1224. [7] Chakrabrati A, Sharma M M. Cyclohexanol from Cyclohexene via Cyclohexyl Acetate: Catalysis by Ion-Exchange Resin and Acid-treated Clay[J]. Reactive Polymers, 1992, 18(2):107-115. [8] Steyer F, Freund H, Sundmacher K. A Novel Reactive Distillation Process for the Indirect Hydration of Cyclohexene to Cyclohexanol Using a Reactive Entrainer[J]. Industrial and Engineering Chemistry Research, 2008, 47(23): 9581-9587. [9] Zhou F, Tang J H, Fei Z Y. et al. Efficient Cyclohexyl Acrylate Production by Direct Addition of Acrylic Acid and Cyclohexene over SBA-15-SO3H[J]. Journal of Porous Materials, 2014, 21(2): 149-155. [10] 董森，彭胜，郭学华. 阳离子交换树脂催化合成乙酸环己酯[J]. 日用化学工业, 2012,42(4): 285-287. [11] 靳敬敬，李芳，杨丽红. HZSM-5催化乙酸环己酯水解反应[J].石油学报(石油化工), 2014, 30(1): 169-174. [12] Stankiewicz A. Reactive separations for process intensification: An industrial perspective[J]. Chemical Engineering and Processing, 2003, 42(3): 137~144. [13] Khaledi R，Bishnoi P R. Amethod for modeling two-and three-phase reactive distillation columns[J]. Industrial and Engineering Chemistry Research, 2006, 45(17):6007-602. [14] Qiu T, Kuang J L, Lin H D, et al. Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst[J]. Chinese Journal of Chemical Engineering, 2011, 19(5): 808-814. [15] Katariya A, Freund H, Sundmacher K. Two-step reactive distillation proeessfor eyelohexanol produetion from cyelohexene[J]. Industrialand Engineering Chemistry Research. 2009, 48(21):9534-9545. [16] Steyer F, Freund H, Sundmaeher K. A novel reaetive distillation process for the indirect hydration of eyclohexene to cyelohexanol using a reactive entrainer[J]. Industrial and Engineering Chemistry Research. 2008, 47(23):9581-9587. [17] Schoenmakers H, Buhler W. Distillation column with external reactors - An alternative to the reaction column[J]. Chemie Ingenieur Technik, 1982, 54(2): 163. [18] Ye J C, Huang J L, Lin H D, et al. Evaluation of Reactive Distillation and Side Reactor Configuration for Direct Hydration of Cyclohexene to Cyclohexanol[J]. Industrial and Engineering Chemistry Research. 2014, 53:1461-1469.

3. 毕业设计（论文）进程安排

2月20日～3月10日：查阅文献，翻译外文文献，完成开题报告； 3月11日～4月05日：进行流程模拟，完成物料衡及能量衡算，绘制物料流程图； 4月06日～4月15日：绘制管道及仪表流程图，完成设备设计和选型； 4月16日～4月25日：完成设备布置，并绘制车间平立面布置图； 4月26日～5月25日：完善各部分工作，撰写设计报告和计算说明书； 5月26日～6月15日：修改论文，准备答辩。