1. 毕业设计（论文）的内容和要求

内容： 吸附制冷是利用固体吸附剂对吸附质（制冷剂）的吸附过程而获得冷量，可用太阳能或工业余热驱动等低品位热能，具有绿色环保、结构简单、运行费用低、无噪音和应用范围广等诸多优点。

mil-101是一类新型微孔/中孔材料，具有比表面积大、孔径大小及表面基团可调等优点，是最有应用前景的mofs材料之一。

现如今，吸附制冷方面的研究，主要从吸附制冷工质对、吸附床传热传质以及系统循环及结构等方面推动吸附制冷技术的发展。

2. 参考文献

[1] 崔群, 陶刚, 姚虎卿. 固体吸附制冷吸附剂的研究进展[J]. 南京化工大学学报 (自然科学版), 1999, 6: 033. [2] 王如竹, 王丽伟, 吴静怡. 吸附式制冷理论与应用[M]. 科学出版社, 2007. [3] Askalany A A, Salem M, Ismael I M, et al. An overview on adsorption pairs for cooling[J]. Renewable and Sustainable Energy Reviews, 2013, 19: 565-572. [4] F#233;rey G, Mellot-Draznieks C, Serre C, et al. A chromium terephthalate-based solid with unusually large pore volumes and surface area[J]. Science, 2005, 309(5743): 2040-2042. [5] Zhengqiu R U I, Quanguo L I, Qun C U I, et al. Adsorption refrigeration performance of shaped MIL-101-water working pair[J]. Chinese Journal of Chemical Engineering, 2014, 22(5): 570-575. [6] Jeremias F, Fr#246;hlich D, Janiak C, et al. Water and methanol adsorption on MOFs for cycling heat transformation processes[J]. New Journal of Chemistry, 2014, 38(5): 1846-1852. [7] Akiyama G, Matsuda R, Sato H, et al. Effect of functional groups in MIL-101 on water sorption behavior[J]. Microporous and Mesoporous Materials, 2012, 157: 89-93. [8] Ma L, Yang H, Wu Q, et al. Study on adsorption refrigeration performance of MIL-101-isobutane working pair[J]. Energy, 2015, 93: 786-794. [9] Sur A, Das R K. Review of Technology Used to Improve Heat and Mass Transfer Characteristics of Adsorption Refrigeration System[J]. International Journal of Air-Conditioning and Refrigeration, 2016, 24(02): 1630003. [10] Girnik I S, Aristov Y I. Making adsorptive chillers more fast and efficient: The effect of bi-dispersed adsorbent bed[J]. Applied Thermal Engineering, 2016, 106: 254-256. [11] Li A, Thu K, Ismail A B, et al. Performance of adsorbent-embedded heat exchangers using binder-coating method[J]. International Journal of Heat and Mass Transfer, 2016, 92: 149-157. [12] Gliemann H, W#246;ll C. Epitaxially grown metal-organic frameworks[J]. Materials Today, 2012, 15(3): 110-116. [13] Campagnol N, Van Assche T, Boudewijns T, et al. High pressure, high temperature electrochemical synthesis of metal#8211;organic frameworks: films of MIL-100 (Fe) and HKUST-1 in different morphologies[J]. Journal of Materials Chemistry A, 2013, 1(19): 5827-5830. [14] Jeremias F, Henninger S K, Janiak C. High performance metal#8211;organic-framework coatings obtained via thermal gradient synthesis[J]. Chemical Communications, 2012, 48(78): 9708-9710. [15] Freni A, Bonaccorsi L, Calabrese L, et al. SAPO-34 coated adsorbent heat exchanger for adsorption chillers[J]. Applied Thermal Engineering, 2015, 82: 1-7. [16] Kummer H, F#252;ldner G, Henninger S K. Versatile siloxane based adsorbent coatings for fast water adsorption processes in thermally driven chillers and heat pumps[J]. Applied Thermal Engineering, 2015, 85: 1-8. [17] Kummer H, Baumgartner M, H#252;genell P, et al. Thermally driven refrigeration by methanol adsorption on coatings of HKUST-1 and MIL-101 (Cr)[J]. Applied Thermal Engineering, 2017, 117: 689-697.

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 备 注 2016-03-02#8212;03-10 查阅国内外有关文献，做文献综述；拟订实验方案。

2016-03-11#8212;05-12 按照实验要求进行各种实验工作。

2016-05-12#8212;05-23 进行实验数据的处理，开始撰写论文。