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毕业论文网 > 任务书 > 化学化工与生命科学类 > 化学工程与工艺 > 正文

Cu/ZnO催化剂上糠醛气相选择性加氢制2-甲基呋喃任务书

 2020-06-10 22:08:01  

1. 毕业设计(论文)的内容和要求

查阅相关文献了解目前糠醛气相加氢制2-甲基呋喃的研究现状,了解相关催化剂的制备方法,对论文的研究方向有较深入的认识。

培养学生独立思考及动手做实验的能力,养成良好的科研习惯。

学会查找和阅读文献;学会应用相关实验设备和分析仪器。

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2. 参考文献

[1] Melero J A, Iglesias J, Garcia A. Biomass as renewable feedstock in standard refinery units. Feasibility, opportunities and challenges.[J]. Energy Environmental Science, 2012, 5(6):7393-7420. [2] Agirrezabal-Telleria I, Gandarias I, Arias P L. Production of furfural from pentosan-rich biomass: Analysis of process parameters during simultaneous furfural stripping[J]. 2013, 143C(9):258-264. [3] Centi G, Santen R A V. Catalysis for Renewables: From Feedstock to Energy Production[M]. Wiley-VCH, 2007. [4] Zeitsch KJ. The chemistry and technology of furfural and its many by- products. Amsterdam: Elsevier; 2000. [5] Bozell J J, Petersen G R. Technology development for the production of biobased products from biorefinery carbohydrates - the US Department of Energy's "Top 10" revisited.[J]. Green Chemistry, 2010, 12(4):539-554. [6] 苗小培, 冯海强, 黄文氢. 纳米级CuO催化剂的制备及其糠醛加氢催化性能[J]. 石油化工, 2015, 44(08):975-979. [7] 吴静, 孔令艳. 铜系无 Cr 负载型糠醛加氢制 2#8212;甲基呋喃催化剂的制备, 表征及催化性能[J]. 石油化工, 2002, 31(10): 799-802. [8] 高玉晶, 孟祥春. 用于糠醛气相加氢制2#8212;甲基呋喃的新型合金催化剂研制[J]. 吉林大学学报(理学版), 2000(01):102-104. [9] BEHRENS M, BRENNECKE D, GIRGSDIES F. Understanding the complexity of a catalyst synthesis: Co-precipitation of mixed Cu, Zn, Al hydroxycarbonate precursors for Cu/ZnO/Al2O3 catalysts investigated by titration experiments [J]. Appl Catal A, 2011, 392(1): 93-102. [10] Zheng H Y, Zhu Y L, Teng B T, et al. Towards understanding the reaction pathway in vapour phase hydrogenation of furfural to 2-methylfuran[J]. Journal of Molecular Catalysis A Chemical, 2006, 246(1):18-23. [11] Yang J, Zheng H Y, Zhu Y L, et al. Effects of calcination temperature on performance of Cu#8211;Zn#8211;Al catalyst for synthesizing γ-butyrolactone and 2-methylfuran through the coupling of dehydrogenation and hydrogenation[J]. Catalysis Communications, 2004, 5(9):505-510. [12] Meyer C I, Marchi A J, Monzon A, et al. Deactivation and regeneration of Cu/SiO2 catalyst in the hydrogenation of maleic anhydride. Kinetic modeling[J]. Applied Catalysis A General, 2009, 367(1):122-129. [13] Yan K, Wu G, Lafleur T, et al. Production, properties and catalytic hydrogenation of furfural to fuel additives and value-added chemicals[J]. Renewable Sustainable Energy Reviews, 2014, 38(3):663-676. [14] 孔令艳. 糠醛常压气相加氢制2-甲基呋喃无Cr催化剂的研究[D]. 沈阳化工学院, 2002. [15] 仇建伟, 张凤媛, 严世强. 溶胶-凝胶法负载型催化剂上糠醛加氢制备2-甲基呋喃[J]. 辽宁化工, 2006, 35(6):311-313. [16] 吴世华, 魏伟. 不同方法制备的Cu#8212;Cr/γ#8212;Al2O3的结构及其对糠醛加氢制2-甲基呋喃反应的催化性能[J]. 催化学报, 2003, 24(01):27-31. [17] 杨骏, 郑洪岩, 朱玉雷. Cu-Cr-Ca-Ba催化剂上糠醛加氢制备2-甲基呋喃[J]. 化学研究, 2004, 15(01):16-19.

3. 毕业设计(论文)进程安排

2016/12/23-2017/01/13阅读相关文献; 2017/02/13-2017/05/10完成相关实验; 2017/05/11-2017/05/24对数据进行整理、分析; 2017/05/25-2017/06/09完成论文的撰写,准备答辩。

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