1. 毕业设计（论文）的内容和要求

1. 掌握查阅中外文文献资料的方法并通过查阅文献，了解课题的背景、意义，并撰写开题报告。

2. 学习实验室安全管理规程，对气体吸附、仪器分析、实验操作等学科复习，为活性测试、性能分析打下基础。

3. 主要研究多孔氮化碳材料的制备并进行改性，并对制备的材料进行co2吸附性能的测试，掌握xrd、sem等表征方法，并对表征结果进行解释说明。

2. 参考文献

[1] Liu J, Wang H, Antonietti M. Graphitic carbon nitride "reloaded": emerging applications beyond (photo)catalysis[J]. Chemical Society Reviews, 2016, 45(8):2308-2326. [2] Wang X, Maeda K, Chen X, et al. Polymer semiconductors for artificial photosynthesis: hydrogen evolution by mesoporous graphitic carbon nitride with visible light[J]. Journal of the American Chemical Society, 2009, 131(5):1680-1683. [3] Deng Q F, Liu L, Lin X Z, et al. Synthesis and CO2 capture properties of mesoporous carbon nitride materials[J]. Chemical Engineering Journal, 2012, 203(5):63-70. [4]Sayari A, Belmabkhout Y. Process for the preparation of 2-aminomethylpiperidine[J]. Journal of the American Chemical Society, 2008, 132(18):6312-6312. [5] Mello M R, Phanon D, Silveira G Q, et al. Amine-modified MCM-41 mesoporous silica for carbon dioxide capture[J]. Microporous Mesoporous Materials, 2011, 143(1):174-179. [6] Lakhi, Kripal S, Park D H, Joseph S, et al. Effect of Heat Treatment on the Nitrogen Content and Its Role on the CO2 Adsorption Capacity of Highly Ordered Mesoporous Carbon Nitride[J]. Chemistry An Asian Journal, 2017, 12(5):595-560. [7] Sayari A, Belmabkhout Y. CO2 deactivation of supported amines: does the nature of amine matter?[J]. Langmuir the Acs Journal of Surfaces Colloids, 2012, 28(9):4241-4247. [8] Kou J, Sun L B. Fabrication of nitrogen-doped porous carbons for highly efficient CO2 capture: rational choice of a polymer precursor[J]. Journal of Materials Chemistry A, 2016, 4(44):17299-17307. [9] Bourrelly S, Llewellyn P L, Serre C, et al. Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47[J]. Journal of the American Chemical Society, 2005, 127(39):13519-21. [10] Dontsova D, Pronkin S, Wehle M, et al. Triazoles: A New Class of Precursors for the Synthesis of Negatively Charged Carbon Nitride Derivatives[J]. Chemistry of Materials, 2015, 27(15):424-503. [11] Su F, Lu C, Kuo S C, et al. Adsorption of CO2 on Amine-Functionalized Y-Type Zeolites[J]. Energy Fuels, 2010, 24(2):1441-1448. [12] Lee C W, Roh K C, Kim K B. A highly ordered cubic mesoporous silica/graphene nanocomposite[J]. Nanoscale, 2013, 5(20):9604-9608. [13] Chen C, Kim J, Yang D A, et al. Carbon dioxide adsorption over zeolite-like metal organic frameworks (ZMOFs) having a sod, topology: Structure and ion-exchange effect[J]. Chemical Engineering Journal, 2011, 168(3):1134-1139. [14] Talapaneni S N, Mane G P, Mano A, et al. Synthesis of nitrogen-rich mesoporous carbon nitride with tunable pores, band gaps and nitrogen content from a single aminoguanidine precursor[J]. Chemsuschem, 2012, 5(4):700-708. [15] Yao Z, Yan J, Zhu Y, et al. Hydrogen evolution by a metal-free electrocatalyst[J]. Nature Communications, 2014, 5(4):3783. [16] Sher Shah M S, Zhang K, Park A R, et al. Single-step solvothermal synthesis of mesoporous Ag-TiO2-reduced graphene oxide ternary composites with enhanced photocatalytic activity[J]. Nanoscale, 2013, 5(11):5093-101. [17] Yang S T, Kim J, Ahn W S. CO2 adsorption over ion-exchanged zeolite beta with alkali and alkaline earth metal ions[J]. Microporous Mesoporous Materials, 2010, 135(1):90-94.

3. 毕业设计（论文）进程安排

2018.3.3-3.15 查阅课题资料，确定实验思路，翻译文献。

2018.3.15-4.2 实验准备，熟悉实验操作，进行初步探索。

2018.4.3-4.30 进行一系列实验合成与产物表征。