基于3d-4f金属构建纳米稀土材料的设计合成及性质的研究任务书
2020-06-26 19:48:28
1. 毕业设计(论文)的内容和要求
内容: 本课题毕业论文最终分为四个章节,研究背景,实验表征,结果讨论,结论展望。
要求: 掌握熟练查阅中外文文献资料的方法,了解课题的研究背景以及研究意义。
文献阅读篇数至少不低于20篇,同时,翻译一篇相关的外文文献。
2. 参考文献
1. Zheng, X.-Y.; Kong, X.-J.; Zheng, Z.-P; Long, L.-S.; Zheng, L.-S. High-Nuclearity Lanthanide-Containing Clusters as Potential Molecular Magnetic Coolers. Acc. Chem. Res. 2018, 51, 517-525. 2. Zheng, X.-Y.; Xie, Y.; Kong, X.-J.; Long, L.-S.; Zheng, L.-S. Recent Advances in the Assembly of High-Nuclearity Lanthanide Clusters. Coord. Chem. Rev. 2017, DOI: 10.1016/j.ccr.2017.10.023. 3. Zheng, X.-Y.; Kong, X.-J.; Long, L.-S. Synthesis and Structures of Lanthanide#8722;Transition Metal Clusters. In Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials; Zheng, Z., Ed.; Springer: Berlin, 2017; 51#8722;96. 4. Zheng, X.-Y.; Peng, J.-B.; Kong, X.-J.; Long, L.-S.; Zheng, L.-S. Mixed-anion templated cage-like lanthanide clusters: Gd27 and Dy27. Inorg. Chem. Front. 2016, 3, 320#8722;325. 5. Zhou, Y.; Zheng, X. Y.; Cai, J.; Hong, Z. F.; Yan, Z. H.; Kong, X. J.; Ren, Y. P.; Long, L. S.; Zheng, L. S. Three Giant Lanthanide Clusters Ln37 (Ln = Gd, Tb, and Eu) Featuring a Double-Cage Structure. Inorg. Chem. 2017, 56, 2037#8722;2041. 6. Qin, L.; Zhou, G. J.; Yu, Y. Z.; Nojiri, H.; Schro#776;der, C.; Winpenny, R. E.; Zheng, Y. Z. Topological Self-Assembly of Highly Symmetric Lanthanide Clusters: A Magnetic Study of Exchange-Coupling ”Fingerprints” in Giant Gadolinium (III) Cages. J. Am. Chem. Soc. 2017, 139(45), 16405-16411. 7. Chen, W. P.; Liao, P. Q.; Yu, Y.; Zheng, Z.; Chen, X. M.; Zheng, Y. Z. A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni64RE96} for Gas Separation and Magnetic Cooling Applications. Angew. Chem., Int. Ed. 2016, 55, 9375#8722;9379. 8. Zheng, X. Y.; Jiang, Y. H.; Zhuang, G. L.; Liu, D. P.; Liao, H. G.; Kong, X. J.; Long, L. S.; Zheng, L. S. A Gigantic Molecular Wheel of {Gd140}: A New Member of the Molecular Wheel Family. J. Am. Chem. Soc. 2017, 139(50), 18178-18181. 9. Kong, X.J.; Ren, Y.P.; Chen, W.X.; Long, L.S.; Zheng, Z.P.; Huang, R.B.; Zheng, L.S. A Four-Shell, Nesting Doll-like 3d-4f Cluster Containing 108 Metal Ions, Angew. Chem. Int. Ed. 2008, 47, 2398 #8211;2401. 10. Peng, J. B.; Zhang, Q. C.; Kong, X. J.; Zheng, Y. Z.; Ren, Y. P.; Long, L. S.; Huang, R. B.; Zheng, L. S.; Zheng, Z. High-nuclearity 3d#8722;4f clusters as enhanced magnetic coolers and molecular magnets. J. Am. Chem. Soc. 2012, 134, 3314#8722;3317.
3. 毕业设计(论文)进程安排
第一周查阅资料,学习相关理论知识,熟悉研究方向并翻译一篇英文文献;第二周在学习一定理论知识的基础上,了解所用实验仪器的相关操作,进行安全性实验教育学习;第三周至第五周正式开始实验部分,并完成开题报告及其相关部分;第六周至第九周进行实验并完成中期小结及其相关部分;第九周至第十三周完成实验部分内容并完成实验数据处理的总结,准备撰写论文的材料;第十三周至第十五周完成毕业生论文写作,完善相关毕业材料。