1. 毕业设计（论文）的内容和要求

通过共沉淀法制备不同载体的负载型铜基催化剂，用于生物质原料糠醛加氢制高附加值产品2-甲基呋喃，通过多种表征手段探究影响反应性能的关键因素，为新型催化剂的开发提供理论依据。

论文要求：学生能够明确实验目的，对实验过程有整体规划与认识，在了解课题背景、完成文献阅读任务的基础上，整合催化剂制备方法、实验反应数据与催化剂表征结果，对整过实验过程给出自己合理的总结与推测。

2. 参考文献

[1] MARISCAL R, MAIRELES-TORRES P, OJEDA M, SADABA I, GRANADOS M L. Furfural: a renewable and versatile platform molecule for the synthesis of chemicals and fuels[J]. Energy Environmental Science, 2016, 9(4): 1144-1189. [2] VAN PUTTEN R, VAN DER WAAL J C, DE JONG E, RASRENDRA C B, HEERES H J, DE VRIES J G. Hydroxymethylfurfural, a versatile platform chemical made from renewable resources[J].Chemical Reviews, 2013,113(3): 1499-1597. [3] PACE V, HOYOS P, CASTOLDI L, DE JONG E, ALCANTARA A R. 2-Methyltetrahydrofuran (2-MeTHF): a biomass-derived solvent with broad application in organic chemistry[J]. Chemsuschem, 2012, 5(8): 1369-1379. [4] NAKAGAWA Y, TAKADA K,TAMURA M, TOMISHIGE K. Total hydrogenation of furfural and 5-hydroxymethylfurfural over supported Pd-Ir alloy catalyst[J].Acs Catalysis, 2014, 4(8): 2718-2726. [5] YAN K, CHEN A C. Selective hydrogenation of furfural and levulinic acid to biofuels on the ecofriendly Cu-Fe catalyst[J]. Fuel, 2014,115: 101-108. [6] YAN K, LIAO J Y, WU X, XIE X M. A noble-metal free Cu-catalyst derived from hydrotalcite for highly efficient hydrogenation of biomass-derived furfural and levulinic acid[J]. Rsc Advances, 2013.,3(12): 3853-3856. [7] YAN K,CHEN A C. Efficient hydrogenation of biomass-derived furfural and levulinic acid on the facilely synthesized noble-metal-free Cu-Cr catalyst[J]. Energy, 2013,58: 357-363. [8] LANGE J P, VAN DER HEIDE E, PRICE R, VAN BUIJTENEN J, PRICE R. Furfuralu a promising platform for lignocellulosic biofuels[J]. Chemsuschem, 2012, 5(1): 150-166. [9] ZHENG H Y, ZHU Y L, BAI Z Q, HUANG L, XIANG H W, LI Y W. An environmentally benign process cyclohexanone and 2-methylfuran[J]. Green Chemistry, 2006, 8(1): 107-109. [10] ZHENG H Y, ZHU Y L, HUANG L, ZENG Z Y, WAN H J, LI Y W. Study on Cu-Mn-Si catalysts for synthesis of cyclohexanone and 2-methylfuran through the coupling process[J] . Catalysis Communications, 2008, 9(3): 342-348. [11] LESSARD J, MORIN J F, WEHRUNG J F, MAGNIN D, CHORNET E. High yield conversion of residual pentoses into furfural via zeolite catalysis and catalytic hydrogenation of furfural to 2-methylfuran[J]. Topics in Catalysis,2010,53(15-18): 1231-1234. [12] CHANG X, LIU A F, CAI B, LUO J C, WU W B, YU J T. Catalytic transfer hydrogenation of furfural to 2-methylfuran and 2-methyltetrahydrofuran over bimetallic copper-palladium catalysts[J]. Chemsuschem, 2016, 9(23): 3330-3337. [13] HUTCHINGS G S, LUC W, LU Q, ZHOU Y, VLACHOS D G, JIAO F. Nanoporous Cu-Al-Co alloys for selective furfural hydrodeoxygenation to 2-methylfuran[J]. Industrial Engineering Chemistry Research, 2017,56(14): 3866-3872. [14] POPA T, ZHANG Y L, JIN E L, FAN M H. An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol[J].Applied Catalysis A-General, 2015, 505: 52-61. [15] DING T M, TIAN H S, LIU J C, WU W B, YU J T. Highly active Cu/SiO2 catalysts for hydrogenation of diethyl malonate to 1,3-propanediol[J].Chinese Journal of Catalysis, 2016. 37(4): 484-493. [16] LI F, LU C S, LI X N. The effect of the amount of ammonia on the Cu0/Cu ratio of Cu/SiO2 catalyst for the hydrogenation of dimethyl oxalate to ethylene glycol[J]. Chinese Chemical Letters,2014,25(11): 1461-1465. [17] YIN A Y, GUO X Y, DAI W L, FAN K N. Effect of initial precipitation temperature on the structural evolution and catalytic behavior of Cu/SiO2 catalyst in the hydrogenation of dimethyloxalate[J]. Catalysis Communications, 2011, 12(6): 412-416. [18] PERNICONE N, FANTINEL T, BALDAN C, RIELLO P, PINNA F. On the measurement of copper surface area by oxygen chemisorption[J]. Applied Catalysis A-General, 2003. 240(1-2): 199-206. [19] Huang Z W, Cui F, Xue J J, ZUO J L, CHEN J, XIA C G. Cu/SiO2 catalysts prepared by hom- and heterogeneous deposition-precipitation methods: texture,structure,and catalytic performance in the hydrogenolysis of glycerol to 1,2-propanediol [J]. Catalysis Today, 2012, 183(1): 42-51. [20] Zhang C C, WANG D H, ZHU M Y, YU F, DAI B. Effect of Different Nano-Sized Silica Sols as Supports on the Structure and Properties of Cu/SiO2 for Hydrogenation of Dimethyl Oxalate[J]. Catalysts, 2017, 7(3): 12.

3. 毕业设计（论文）进程安排

起讫日期 工作内容 2018.2.1-2018.3.8 课题相关文献的阅读 2018.3.9-2018.5.1 实验内容（催化剂制备、反应考察、测试与表征） 2018.5.8-2018.5.28 实验数据的处理与图谱分析 2018.5.29-2018.6.10 毕业论文的撰写