1. 毕业设计（论文）的内容和要求

1、主要研究内容 （1）研究四唑类y-2的热危险性：完成该物质的差示扫描量热实验(dsc)与绝热量热实验(arc)，得到基本的热危险性参数，如起始分解温度、分解峰值温度、分解热等。

运用热分析动力学方程计算y-2分解的活化能、指前因子和反应级数。

根据四唑类y-2的不回归温度和自加速分解温度，评估四唑类y-2的热危险性。

2. 参考文献

[1]弗朗西斯#183;施特塞尔.化工工艺的热安全#8212;风险评估与工艺设计[M].北京:科学出版社,2009. [2]胡荣祖等.热分析动力学(第二版)[M].北京:科学出版社,2008. [3 ]Li-Bai Xiao, et al. Thermal behavior and safety of dihydroxylammonium 5,5#8217;-bistetrazole-1,1#8217;-diolate[J]. Thermal Analysis and Calorimetry,2016,123:653-657. [4] Jaidann M, Roy S, Rachid HA, Lussier LS. A DFT theoretical study of heats of formation and detonation properties of nitrogen-rich explosives[J]. Hazard Materials,2010,176:165#8211;73 [5] You JS, Kanga SC, Kweonb SK, et al. Thermal decomposition kinetics of GAP ETPE/RDX-based solid propellant[J]. Thermochimica Acta,2012,537:51#8211;6. [6] Koga N. Ozawa#8217;s kinetic method for analyzing thermoanalytical curves[J]. Thermal Analysis and Calorimetry,2013,113:1527#8211;41. [7] Zhang ZY, Chen J, Liu HJ, Xiao CF. Applicability of Kissinger model in nonisothermal crystallization assessed using a computer simulation method[J]. Thermal Analysis and Calorimetry, 2014,117:783#8211;7. [8] Zhang Y, Wu H, Xu KZ, et al. Nonisothermal decomposition kinetics, specific heat capacity, and adiabatic time-to-explosion of Zn(NH3)(FOX-7)2[J]. Thermal Analysis and Calorimetry.2014,116:817#8211;23. [9] Liu R, Yang L, Zhou ZN, et al. Thermal stability and sensitivity of RDX-based aluminized explosives[J]. Thermal Analysis and Calorimetry. 2014,115:1939#8211;48. [10] Liu Y, Jiang YT, Zhang TL, et al. Thermal kinetic performance and storage life analysis of a series of high-energy and green energetic materials[J]. Thermal Analysis and Calorimetry.2015,119:659#8211;70. [11] Yi JH, Zhao FQ, Wang BZ, et al. BTATz#8211;HNIW#8211;CMDB propellants[J]. Thermal Analysis and Calorimetry. 2014,115:1227#8211;34. [12] Xu KZ, Zuo XG, Zhang H, et al. Synthesis and thermal behavior of a new high-energy organic potassium saltK(AHDNE)[J]. Thermal Analysis and Calorimetry.2012,110:585#8211;91.

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 1.6～1.17 查阅与论文有关的中英文资料，全面了解课题 2.24～3.29 整理筛选资料，完成开题报告初稿；同时，构思论文的框架结构 3.30～4. 5 完善开题报告初稿的基础上，深入细致的研究资料，完成论文概述部分的内容 4.6～4.19 选择合适的，符合要求的英语文章，逐步完成英文翻译；进一步收集、阅读相关资料和文献 4.20～5.16 完成论文的主体部分：四唑类Y-2的热危险性实验研究 5.17～5.31 完成论文的主体部分：四唑类Y-2的配合物热危险性实验研究 6.1～6.10 完成论文定稿，修改完善论文做答辩准备