1. 毕业设计（论文）的内容和要求

多孔材料因其高的比表面积和多样的孔结构在能源、催化以及生物领域有很好的应用。

磷酸锆具有优良的耐酸碱性，很好化学稳定性和热稳定性，而且无毒、机械强度高，将其做成介孔状材料就能提供相当大的比表面积，作为催化剂载体在很多催化领域特别是多相催化中表现出很好的催化效果。

介孔磷酸锆很适合充当催化剂的载体，可以预测负载活性组分后将提高其催化活性。

2. 参考文献

[1] A-lBarood A, Qabazard H, Stanislaus A.A comparative study of the HDS kinetics of straight run and coker gas oils under deep desulfurization conditions[J]. Petroleum Science and Technology, 2005 , 23(7): 749-760. [2] Ghosh P, Andrews AT, Quann R J, et al. Detailed kinetic model for the hydrodesulfurization of FCC naphtha [J].Energy Fuels, 2009, 23(12): 5743-5759. [3] 余夕志,董振国,任晓乾,等.柴油馏分加氢脱硫动力学及反应器研究进展[J]. 燃料化学学报, 2005, 33(3): 372-378. [4] 于型伟,李向进,黄明富,王弘历,刘富余.催化汽油加氢脱硫工艺技术现状及节能方向研究[J]. 石油石化节能, 2016, (6). [5] Tang T, Yin C, Wang L, et al. Good sulfur tolerance of a mesoporous Beta zeolite-supported palladium catalyst in the deep hydrogenation of aromatics [J]. Journal of Catalysis. 2008, 257(1): 125-133. [6] 薛艳.水热法合成磷酸锆介孔材料中模板剂的影响[A]. 国际分子筛协会中国委员会、全国分子筛协作组.分子筛催化与纳米技术#8212;#8212;分子筛协作组2006年学术年会论文集[C].国际分子筛协会中国委员会、全国分子筛协作组:2006.191-193. [7] Clearfield A Stynes J A. The preparation of crystalline zirconium phosphate and some observations on its ion exchange behavior [J].Journal of Inorganic and Nuclear Chemistry.1964,26(1):117-129. [8] Karlsson M, Andersson C, Hjortkjaer J. Hydroformylation of propene and 1-hexene catalyzed by a α-zirconium phosphate supported rhodium-phosphine complex[J].Journal of Molecular Catalysis A:Chemical,2001,166(00):337-343. [9] Liu W, Song Z, Ikegawa T, et al. Two step synthesis and characterization of thermally stable hexagonal zirconium phosphate [J].Materials Letters.2004,58(26):3328-3331. [10] Jimenez-Jimenez J, Maireles-Torres P, Olivera-Pastor P, et al. Surfactant-Assisted Synthesis of a Mesoporous Form of Zirconium Phosphate with Acidic Properties [J]. Advanced Materials.1998, 10(10): 812-815. [11] Wong M S, Antonelli D M, Ying J Y. Synthesis and Characterization of Phosphatide Mesoporous Zirconium Oxide [J]. Nanostructured Materials.1997, 9(1): 165-168. [12] Tian B Z, Liu X Y, Tu B, Yu C Z, Fan J, Wang L M, Stucky G D, Zhao D Y. Nature Mater , 2003, 2: 159. [13] Sinhamahapatra A，Sutradhar N, Roy B, et al. Microwave assisted synthesis of fine chemicals Insolvent-free conditions over mesoporous zirconium phosphate [J]. Applied Catalysis B; Environmental. 2011, 103(3-4): 378-387. [14] Das S K, Bhunia M K, Sinha A K, et al. Synthesis Characterization, and Biofuel Application of Mesoporous Zirconium Oxophosphates [J].ACS Catalysis.2011:493-501. [15] 韩士春.磷酸氧锆介孔材料的制备［D］.哈尔滨：哈尔滨理工大学，2005.

3. 毕业设计（论文）进程安排

（1）2018.1.12前：完成开题报告，主要包括查阅文献，撰写综述 （2）2.20-2.25：前期准备，设计实验等 （3）2.26-3.10：介孔磷酸锆的合成条件的优化 （4）3.11-5.20：对介孔磷酸锆进行掺杂及考察其加氢脱硫催化性能 （5）5.21后：撰写论文，准备答辩。