新型复合碳材料的制备及其电催化性能研究任务书
2020-06-29 20:23:21
1. 毕业设计(论文)的内容和要求
低温燃料电池已经在各领域中得到广泛的应用,电极催化剂材料(包括金属纳米粒子催化剂和载体)的优劣是影响燃料电池系统性能和效率的关键因素之一。
其中,载体直接影响着金属纳米粒子催化剂的大小、分散性、催化效率及稳定性。
某些传统的载体材料如炭黑,尽管有较大的比表面积,然而其孔径太小,不利于与反应溶液的充分接触,从而降低了催化剂的利用效率。
2. 参考文献
[1] Mazumder V, Lee Y, Sun S. Recent development of active nanoparticle catalysts for fuel cell reactions. Adv. Funct. Mater. 2010, 20(8):1224-1231. [2] Antolini E, Gonzalez E R. Alkaline direct alcohol fuel cells. J. Power Sources 2010, 195(11):3431-3450. [3] Wee J H. Applications of proton exchange membrane fuel cell systems. Renew. Sust. Energ. Rev. 2007, 11(8): 1720-1738. [4] Chen A, Holt-Hindle P. Platinum-based nanostructured materials: Synthesis, properties, and applications. Chem. Rev. 2010, 110(6): 3767-3804. [5] Bianchini C, Shen P K. Palladium-based electrocatalysts for alcohol oxidation in half cells and in direct alcohol fuel cells. Chem. Rev. 2009, 109(9):4183#8211;4206. [6] Roth C, Benker N, Theissmann R, Nichols R J, Schiffrin D J. Bifunctional electrocatalysis in Pt#8722;Ru nanoparticle systems. Langmuir 2008, 24(5): 2191-2199. [7] Gao H, Liao S, Zeng J, Xie Y. Platinum decorated Ru/C: Effects of decorated platinum on catalyst structure and performance for the methanol oxidation reaction. J. Power Sources 2011, 196(1): 54-61. [8] Liu Z, Ling X Y, Su X, Lee J Y. Carbon-supported Pt and Pt Ru nanoparticles as catalysts for a direct methanol fuel cell. J. Phys. Chem. B 2004, 108(24): 8234-8240. [9] Seweryn J, Lewera A. Electrooxidation of ethanol on carbon-supported Pt-Pd nanoparticles. J. Power Sources 2012, 205:264-271. [10] Lopes T, Antolini E, Gonzalez E. Carbon supported Pt#8211;Pd alloy as an ethanol tolerant oxygen reduction electrocatalyst for direct ethanol fuel cells. Int. J. Hydrogen Energy 2008, 33(20): 5563-5570. [11] Zhu C, Guo S, Dong S. Pd M (M = Pt, Au) bimetallic alloy nanowires with enhanced electrocatalytic activity for electro-oxidation of small molecules. Adv. Mater. 2012, 24(17): 2326-2331. [12] 新型碳复合材料负载贵金属纳米粒子催化剂的制备及其电催化性能研究_蒋丰兴 [13] 二氧化碳电化学还原中铜基催化剂的设计与优化_谢佳芳
3. 毕业设计(论文)进程安排
(1)2018.1.12前:完成开题报告,主要包括查阅文献,撰写综述 (2)2.20-2.25前期准备,设计实验等 (3)2.26-3.10:新型多孔的合成以及催化剂的制备 (4)3.11-5.20碳复合催化材料的催化性能表征及时总结