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毕业论文网 > 任务书 > 材料类 > 高分子材料与工程 > 正文

环氧树脂潜伏性固化剂的制备与研究任务书

 2020-07-01 20:53:16  

1. 毕业设计(论文)的内容和要求

论文主要内容有:对环氧树脂固化剂咪唑进行潜伏性改性;通过对实验条件的优化得到改性咪唑的产率最高化;研究改性咪唑固化环氧树脂的特性及其与环氧混合后的潜伏性。

掌握物质的表征方法,各种性能的测试方法,并了解热固性树脂的固化原理。

实验安排:第一周~第二周: 文献查阅,查阅有关环氧树脂潜伏型固化剂的相关文献,要求学习并掌握利用中国期刊网、维普、ei、ca、elsevier、欧洲 专利等查阅文献,不少于15篇。

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2. 参考文献

[1] L. Guadagno, M. Raimondo, V. Vittoria, L. Vertuccio, C. Naddeo, S. Russo, B. De Vivo, P. Lamberti, G. Spinelli, V. Tucci, Development of epoxy mixtures for application in aeronautics and aerospace, RSC Adv 4 (2014) 15474-15488. [2] J. Gu, X. Yang, Z. Lv, N. Li, C. Liang, Q. Zhang, Functionalized graphite nanoplatelets/epoxy resin nanocomposites with high thermal conductivity, Int J Heat Mass Tran 92 (2016) 15-22. [3] S.J. Park, M.K. Seo, J.R. Lee, D.R. Lee, Studies on epoxy resins cured by cationic latent thermal catalysts: the effect of the catalysts on the thermal, rheological, and mechanical properties, J Polym Sci Pol Chem 39 (2001) 187-195. [4] K. Kudo, S. Fuse, M. Furutani, K. Arimitsu, Imidazole-type thermal latent curing agents with high miscibility for one-component epoxy thermosetting resins, J Polym Sci Pol Chem 54 (2016) 2680-2688. [5] K. Suzuki, H. Horii, Y. Sugita, F. Sanda, T. Endo, Promotion effect of bifunctional five-membered cyclic dithiocarbonate on curing of one-component epoxy resin by imines as latent initiator, J Appl Polym Sci 94 (2004) 961-964. [6] K. Kudo, M. Furutani, K. Arimitsu, Imidazole derivatives with an intramolecular hydrogen bond as thermal latent curing agents for thermosetting resins, ACS Macro Lett 4 (2015) 1085-1088. [7] K. Chen, Y. Shen, M. Yeh, F.F. Wong, Complexes of imidazole with poly(ethylene glycol)s as the thermal latency catalysts for epoxy-phenolic resins, J Taiwan Inst Chem E 43 (2012) 306-312. [8] K. Arimitsu, S. Fuse, K. Kudo, M. Furutani, Imidazole derivatives as latent curing agents for epoxy thermosetting resins, Mater Lett 161 (2015) 408-410. [9] L. Feng, Y. Wang, Y. Wang, H. Liu, J. Zhao, Study on reaction kinetics of epoxy resin cured by a modified dicyandiamide, J Appl Polym Sci 127 (2013) 1895-1900. [10] 王永超, 林树东, 涂园园, 李江华, 胡继文, 李妃, 一种环氧树脂潜伏性固化剂二苯基双胍的合成与性能, 精细化工, (2016) 224-230. [11] S. Liu, J. Chen, J. Zhao, Z. Jiang, Y. Yuan, Phosphaphenanthrene-containing borate ester as a latent hardener and flame retardant for epoxy resin, Polym Int 64 (2015) 1182-1190. [12] C. Martin, G. Lligadas, J.C. Ronda, M. Galia, V. Cadiz, Synthesis of novel boron-containing epoxy-novolac resins and properties of cured products, J Polym Sci Pol Chem 44 (2006) 6332-6344. [13] Y.R. Ham, D.H. Lee, S.H. Kim, Y.J. Shin, M. Yang, J.S. Shin, Microencapsulation of imidazole curing agent for epoxy resin, J Ind Eng Chem 16 (2010) 728-733.

3. 毕业设计(论文)进程安排

第一周~第二周: 文献查阅,查阅有关环氧树脂潜伏型固化剂的相关文献,要求学习并掌握利用中国期刊网、维普、ei、ca、elsevier、欧洲 专利等查阅文献,不少于15篇。

第三周:英文文献的翻译:文献字数3000字以上 开题:完成开题报告。

第四周~第十五周:开展实验工作,主要有以下几个部分 1、改性咪唑的合成及合成条件的优化 2、对产物的表征; 3、固化性能,潜伏性及其固化产物性能的表征。

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