全文总字数：5306字

1. 毕业设计（论文）的内容、要求、设计方案、规划等

研究内容：1、通过烷基化、溴化、醛基化、还原及亲核反应等合成n，n-二( 2-吡啶甲基)胺基三聚茚衍生物；2、使用核磁共振、高分辨质谱等对所合成的化合物进行结构表征，并使用电子吸收光谱、荧光光谱及离子滴定等研究其光物理性质和离子识别行为。

具体要求：前言部分主要介绍本研究项目背景，包括国内外研究进展、存在的问题及本项目研究意义；研究内容要明确、具体详实；根据研究内容和研究目标，查阅相关国内外文献，制定出切实可行的实验方案；实验数据要及时记录，并能根据得到的实验数据及时进行数据处理和分析；实验记录应认真、清楚、准确，不得随意更改数据，更不能编凑数据。

结果分析要依据实验数据，做到有据可依有据可查；研究结论主要对实验数据进行整理、归纳，找出规律性并用所学理论进行解释，得出明确结论；附表要符合南京林业大学本科论文书写要求。

2. 参考文献（不低于12篇）

1.黄齐茂，李　清，王司卫，潘志权. β－萘并冠醚卟啉的合成及光敏活性，化学与生物工程，29（7）：22-25,2012.2.Nathalie Solladie′, Mathieu E. Walther, Haiko Herschbach, Emmanuelle Leize, Alain Van Dorsselaer, Teresa M. Figueira Duartec and Jean-Francois Nierengarten. Supramolecular complexes obtained from porphyrincrown ether conjugates and a fullerene derivative bearing an ammonium unit, Tetrahedron. 62, 19791987, 2006.3.Francis DSouza, Mohamed E. El-Khouly, Suresh Gadde, Melvin E. Zandler, Amy Lea McCarty, Yasuyaki Araki and Osamu Ito. Supramolecular triads bearing porphyrin and fullerene viatwo-point binding involving coordination and hydrogen bonding, Tetrahedron. 62, 1967-1978, 2006. 4.Stephanie L. Gould, Gerdenis Kodis, Paul A. Liddell, Rodrigo E. Palacios, Alicia Brune, Devens Gust, Thomas A. Moore and Ana L. Moore. Artificial photosynthetic reaction centers with carotenoid antennas, Tetrahedron. 62, 20742096, 2006.5. David I. Schuster,a, Shaun MacMahon, Dirk M. Guldi, Luis Echegoyen and Silvia E. Braslavsky. Synthesis and photophysics of porphyrinfullerene donoracceptor dyads with conformationally flexible linkers, Tetrahedron. 62, 19281936, 2006.6. Hisahiro Sasabe, Kei-ichiro Ikeshita, G. Abraham Rajkumar, Nobuhiro Watanabe, Nobuhiro Kihara, Yoshio Furusho, Kazuhiko Mizuno, Akiya Ogawa and Toshikazu Takata. Synthesis of [60]fullerene-functionalized rotaxanes, Tetrahedron. 62, 19881997, 2006.7. Atsuro Takai, Claude P. Gros, Jean-Michel Barbe, Roger Guilard and Shunichi Fukuzumi. Enhanced Electron-Transfer Properties of Cofacial Porphyrin Dimers through pp Interactions, Chem. Eur. J. 15, 3110 3122, 2011.8. Benoit Habermeyer, Atsuro Takai, Claude P. Gros, Maya El Ojaimi, Jean-Michel Barbe, and Shunichi Fukuzumi. Dynamics of Closure of Zinc Bis-Porphyrin Molecular Tweezers with Copper(II) Ions and Electron Transfer, Chem. Eur. J. 17, 10670-10681, 2011.9.Atsuro Takai, Claude P. Gros, Jean-Michel Barbe, and Shunichi Fukuzumi. Greatly Enhanced Intermolecular p-Dimer Formation of a Porphyrin Trimer Radical Trications through Multiple p Bonds, Chem. Eur. J. 17, 3420-3428, 2011.10. Benoit Habermeyer, Atsuro Takai, Claude P. Gros, Maya El Ojaimi, Jean-Michel Barbe, and Shunichi Fukuzumi. Dynamics of Closure of Zinc Bis-Porphyrin Molecular Tweezers with Copper(II) Ions and Electron Transfer, Chem. Eur. J. 17, 10670-10681, 2011.11. Fre′de′rique Brge′ier, Shawkat M. Aly, Claude P. Gros, Jean-Michel Barbe, Yoann Rousselin, and Pierre D. Harvey. Design and Photophysical Properties of Zinc(II) Porphyrin-Containing Dendrons Linked to a Central Artificial Special Pair, Chem. Eur. J. 17, 14643-14662, 2011.12. Benoit Habermeyer, Atsuro Takai, Claude P. Gros, Maya El Ojaimi, Jean-Michel Barbe, and Shunichi Fukuzumi. Dynamics of Closure of a Zinc Bis-Porphyrin Molecular Tweezers with Copper(II) Ions and Electron Transfer, Chem. Eur. J, 1-23, 2011.13. Karl M. Kadish, Ning Guo, Eric Van Caemelbecke, Antonella Froiio, Roberto Paolesse, Donato Monti, Pietro Tagliatesta, Tristano Boschi, Luca Prodi, Fabrizio Bolletta, and Nelsi Zaccheroni. Synthesis, Electrochemical, and Photophysical Study of Covalently Linked Porphyrin Dimers with Two Different Macrocycles, Inorg.Chem. J.37,2358-2365,1998.14. Roger Guilard, Claude P. Gros, Fre′de′ric Bolze, Francois Je′rome, Zhongping Ou, Jianguo Shao, Jean Fischer, Raymond Weiss, and Karl M. Kadish. Alkyl and Aryl Substituted Corroles. 1. Synthesis and Characterization of Free Base and Cobalt Containing Derivatives. X-ray Structure of (Me4Ph5Cor)Co(py)2 , Inorg.Chem. J.40,4845-4855,2001.15. Diana Bellows,Shawkat M. Aly, Claude P. Gros, Maya El Ojaimi, Jean-Michel Barbe, Roger Guilard, and Pierre D. Harvey. Energy Transfers in Monomers, Dimers, and Trimers of Zinc(II) and Palladium(II) Porphyrins Bridged by Rigid Pt-Containing Conjugated Organometallic Spacers, Inorg.Chem. J.48,7613-7629,2009.16. Jean-MichelBarbe, Benoit Habermeyer, TonyKhoury, ClaudeP. Gros, PhilippeRichard, PingChen andKarl M. Kadish. Three-Metal Coordination by Novel Bisporphyrin Architectures, Inorg.Chem. J.49,8929-8940,2010.17. Atsuro Takai, Mohammed Chkounda, Antoine Eggenspiller, Claude P. Gros, Mohammed Lachkar, Jean-Michel Barbe, and Shunichi Fukuzumi. Efficient Photoinduced Electron Transfer in a Porphyrin Tripod-Fullerene Supramolecular Complex via π-π Interactions in Nonpolar Media, AM. CHEM. SOC. J. 132, 4477-4489, 2010.18. 杨绳岩，吴振奕，万新军，晏娟. 卟啉-富勒烯络合物的合成，化学进展，23（6）：1123-1135，2011.19.张来新，朱海云，杨琼. 卟啉化学研究的新进展，应用化工，40（7）：1158-1174，2011.20. 杨建东，王都留. 卟啉及金属卟啉化合物的合成及应用研究进展，首都师范大学学报(自然科学版)，33（4）：14-18，2012.21. 王瑛，庄长福，张加研，秦永剑，师同顺. 不对称酰胺基卟啉的合成及表征,广州化工，40（1）：43-49，2012.22. 庄长福，王瑛，张加研，吴春华，秦永剑，师同顺. 不对称酰胺基液晶化合物的合成，表征及热分析,化工技术与开发， 41（2）：1-4，2012.23. 王凯，林笑，万幸，贾涛，张秀兰，张珩，巨修练. 钌-菲罗啉卟啉的合成及与DNA 的相互作用,高等学校化学学报， 33（12）：2663-2669，2012.24. 张来新，赵卫星. 新型卟啉及其金属配合物的合成与应用，应用化工，42（8）：1498-1500，2013.25.王瑛，庄长福，张加研，田珩，秦永剑，师同顺. 一种新型液晶化合物的合成及表征，广东化工，39（3）：10-11，2012.