全文总字数：2068字

1. 毕业设计（论文）的内容、要求、设计方案、规划等

研究内容：1）以氯化铋、噻二唑为原料合成棒状硫化铋，讨论其在不同的电解液中的电化学性能。

2）硫化铋/碳在醚类电解液中的性能，讨论碳源不同浓度下的硫化铋/碳的电化学性能。

要求：采用场发射扫描电子显微镜(fe-sem)、透射电子显微镜(tem)和高分辨透射电子显微镜(hr tem)、x-射线衍射分析(xrd)等测试手段来综合制备的硫化铋及硫化铋/碳的组成、结构、形貌，最终优化出具有优异的综合性能的合成普鲁士蓝的工艺条件。

2. 参考文献（不低于12篇）

1Sun W, Rui X, Zhang D, et al. Bismuth sulfide: A high-capacity anode for sodium-ion batteries[J]. Journal of Power Sources, 2016, 309:135-140.2Jin R, Li G, Zhang Z, et al. Carbon coated flower like Bi 2 S 3, grown on nickel foam as binder-free electrodes for electrochemical hydrogen and Li-ion storage capacities[J]. Electrochimica Acta, 2015, 173:458-464.3Zhao Y, Gao D, Ni J, et al. One-pot facile fabrication of carbon-coated Bi 2 S 3, nanomeshes with efficient Li-storage capability[J]. 纳米研究(英文版), 2014, 7(5):765-773.4Yang W, Wang H, Liu T, et al. A Bi2S3@CNT nanocomposite as anode material for sodium ion batteries[J]. Materials Letters, 2016, 167:102-105.5Luo W, Li F, Li Q, et al. Heterostructured Bi2S3-Bi2O3 Nanosheets with Built-In Electric Field for Improved Sodium Storage.[J]. Acs Applied Materials Interfaces, 2018, 10(8).6Liu S, Feng J, Bian X, et al. Advanced arrayed bismuth nanorod bundle anode for sodium-ion batteries[J]. Journal of Materials Chemistry A, 2016, 4(26).7Hwang J Y, Myung S T, Sun Y K. Sodium-ion batteries: present and future[J]. Chemical Society Reviews, 2017, 46(12):3529.8Liang H, Ni J, Li L. Bio-inspired engineering of Bi 2 S 3 -PPy yolk-shell composite for highly durable lithium and sodium storage[J]. Nano Energy, 2017, 33:213-220.9Liang H, Ni J, Li L. Bio-inspired engineering of Bi 2 S 3 -PPy yolk-shell composite for highly durable lithium and sodium storage[J]. Nano Energy, 2017, 33:213-220.10Wang C, Wang L, Li F, et al. Bulk Bismuth as a High-Capacity and Ultralong Cycle-Life Anode for Sodium-Ion Batteries by Coupling with Glyme-Based Electrolytes[J]. Advanced Materials, 2017, 29.11杨万里. 层状硫化铋复合材料的制备及电化学储钠性能研究[D]. 苏州大学, 2016.