面向气体分离MOF膜的设计与组装任务书
2020-04-22 19:45:01
1. 毕业设计(论文)的内容和要求
完成1-2张基于超分子有机笼混合基质膜的制备及其气体分离研究。
2. 参考文献
(1) Seoane, B.; Coronas, J.; Gascon, I.; Etxeberria Benavides, M.; Karvan, O.; Caro, J.; Kapteijn, F.; Gascon, J. Metal-Organic Framework Based Mixed Matrix Membranes: A Solution for Highly Efficient Co2 Capture? Chem. Soc. Rev. 2015, 44 (8), 2421-54. (2) Zou, C. C.; Li, Q. Q.; Hua, Y. Y.; Zhou, B. H.; Duan, J. G.; Jin, W. Q. Mechanical Synthesis of Cof Nanosheet Cluster and Its Mixed Matrix Membrane for Efficient Co2 Removal. ACS Appl. Mater. Interfaces 2017, 9 (34), 29093-29100. (3) Li, G.; Zhang, K.; Tsuru, T. Two-Dimensional Covalent Organic Framework (Cof) Membranes Fabricated Via the Assembly of Exfoliated Cof Nanosheets. ACS Appl. Mater. Interfaces 2017, 9 (10), 8433-8436. (4) Sun, J. K.; Zhan, W. W.; Akita, T.; Xu, Q. Toward Homogenization of Heterogeneous Metal Nanoparticle Catalysts with Enhanced Catalytic Performance: Soluble Porous Organic Cage as a Stabilizer and Homogenizer. J. Am. Chem. Soc. 2015, 137 (22), 7063-6. (5) Yang, X. C.; Sun, J. K.; Kitta, M.; Pang, H.; Xu, Q. Encapsulating Highly Catalytically Active Metal Nanoclusters inside Porous Organic Cages. Nat Catal 2018, 1 (3), 214-220.
3. 毕业设计(论文)进程安排
1. 2月-3月,完成相关前体合成; 2. 3月-4月,完成超分子有机笼制备; 3. 4月-5月,结合聚合物,实现基于超分子有机笼膜的组装和性能探索; 4. 5月-6月,总结和分析上述数据,并完成毕业论文写作和答辩。