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毕业论文网 > 任务书 > 化学化工与生命科学类 > 化学工程与工艺 > 正文

自沉积制备纳米CuMn2O4/SiO2催化甲苯燃烧性能研究任务书

 2020-04-22 19:45:13  

1. 毕业设计(论文)的内容和要求

内容:本课题以高效催化净化甲苯为出发点,采用自沉积法制备一系列负载型尖晶石催化剂,并对催化剂的物理化学性质进行表征,系统研究催化剂的结构、组成以及体相/表面结构;并在常压连续流动气固反应装置中对催化剂催化净化甲苯性能进行评价,阐明催化剂结构与性能之间的关系。

要求:1)具备文献检索、阅读和信息综合分析的能力。

(2)能够运用化学化工基础理论解决工艺问题。

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2. 参考文献

[1] Faure B, Benjamin, Alphonse P . Co-Mn-oxide spinel catalysts for CO and propane oxidation at mild temperature[J]. Applied Catalysis B: Environmental, 2016, 180:715-725. [2] Hosseini S A , Niaei A , Salari D , et al. Nanocrystalline AMn2O4 (A = Co, Ni, Cu) spinels for remediation of volatile organic compounds-synthesis, characterization and catalytic performance[J]. Ceramics International, 2012, 38(2):1655-1661. [3] Sickafus K E , Wills J M , Grimes N W . Structure of Spinel[J]. Journal of the American Ceramic Society, 1999, 82(12):3279-3292. [4] Hill R J , Craig J R , Gibbs G V . Systematics of the spinel structure type[J]. Physics and Chemistry of Minerals, 1979, 4(4):317-339. [5] Zhao Q , Yan Z , Chen C , et al. Spinels: Controlled Preparation, Oxygen Reduction/Evolution Reaction Application, and Beyond[J]. Chemical Reviews, 2017, 117(15):10121-10211. [6] Behar S , Gonzalez P , Agulhon P , et al. New synthesis of nanosized Cu-Mn spinels as efficient oxidation catalysts[J]. Catalysis Today, 2012, 189(1):35-41. [7] Hosseini S A , Alvarez-Galvan M C , Fierro J L G , et al. MCr2O4 (M=Co, Cu, and Zn) nanospinels for 2-propanol combustion: Correlation of structural properties with catalytic performance and stability[J]. Ceramics International, 2013, 39(8):9253-9261. [8] Liang X, Liu P, He H, et al. The variation of cationic microstructure in Mn-doped spinel ferrite during calcination and its effect on formaldehyde catalytic oxidation[J]. Journal of Hazardous Materials, 2016, 306:305-312. [9] Zavyalova U , Nigrovski B , Pollok K , et al. Gel-combustion synthesis of nanocrystalline spinel catalysts for VOCs elimination[J]. Applied Catalysis B Environmental, 2008, 83(3-4):221-228. [10] Saravanakumar B , Muthu Lakshmi S , Ravi G , et al. Electrochemical properties of rice-like copper manganese oxide (CuMn2O4) nanoparticles for pseudo capacitor applications[J]. Journal of Alloys and Compounds, 2017, 723:115-122. [11] Niu J, Qian H, Liu J, et al. Process and mechanism of toluene oxidation using Cu1-yMn2CeyOx/sepiolite prepared by the co-precipitation method[J]. Journal of Hazardous Materials, 2018, 357:332-340.

3. 毕业设计(论文)进程安排

第1~2周:查阅文献,搜集相关资料,了解本课题的相关知识及研究进展,并根据课题研究的内容,构想初步的实验思路和草案; 第3~4周:确定工作任务、研究思路、方法、方案,制定任务书,并完成开题报告; 第5~8周:采用自沉积法制备催化剂并进行相关表征; 第9~9周:结合期中教学检查,对毕业论文工作进展情况进行检查,总结实验中遇到的问题; 第10~12周:在常压连续流动气固反应装置上进行催化剂催化性能评价; 第13~15周:讨论总结实验结果,并完成论文,准备论文答辩。

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