1. 毕业设计（论文）的内容和要求

1.阅读合成气直接制低碳烯烃（fto）反应体系相关文献，重点是铁基催化剂，了解国内外最新研究进展，阅读英文文献20篇以上。

2.熟悉实验室常规设备和fto反应装置工作原理，并学会相应的仪器操作。

3.了解fe-n-c材料的制备方法，并能够独立完成催化剂的合成实验。

2. 参考文献

[1] H. M. T. Galvis, K. P. de Jong. Catalysts for production of lower olefins from synthesis gas: a review[J]. ACS Catalysis, 2013, 3: 2130-2149. [2] 戴伟,罗晴,王定博等. 烯烃转化生产丙烯的研究进展[J]. 石油化工, 2008, 37: 425-433. [3] M. Janardanarao. Direct catalytic conversion of synthesis gas to lower olefins[J]. Industrial Engineering Chemistry Research, 1990, 29: 1735-1753. [4] A. A. Mirzaei, R. Sarani, H. R. Azizi, et al. Kinetics modeling of Fischer-Tropsch synthesis on the unsupported Fe-Co-Ni (ternary) catalyst prepared using co-precipitation procedure[J]. Fuel, 2015, 140: 701-710. [5] 沈菊华. 德BASF开发先进的合成气制烯烃工艺[J]. 化学反应工程与工艺, 2008, 5: 480-485. [6] P. Wang, W. Chen, Fu-Kuo Chiang, et al. Synthesis of stable and low-CO2 selective #61541;-iron carbide Fischer-Tropsch catalysts[J]. Science Advances, 2018, 4: 2947-2956. [7] D. Das, G. Ravichandran, D. K. Chakrabarty, et al. Conversion of syngas to light olefins over silicalite-1 supported iron and cobalt catalysts: Effect of manganese addition[J]. Catalysis Today, 1997, 36: 285-293. [8] J. Barrault, C. Forquy, J. Menezo, et al. Selective hydrocondensation of CO to light olefins with alumina-supported iron catalysts[J]. Reaction Kinetics and Catalysis Letters, 1980, 15: 153-158. [9] H. M. T. Galvis, J. H. Bitter, C. B. Khare, et al. Supported iron nanoparticles as catalysts for sustainable production of lower olefins[J]. Science, 2012, 335: 835-838. [10] R. B. Anderson, J. F. Shultz, B. Seligman, et al. Literature review: Fischer-Tropsch synthesis. American Chemical Society, 1950, 72: 3502-3508. [11] E. B. Yeh, L. H. Schwartz, J. B. Butt, et al. Metal organic framework-mediated synthesis of highly active and stable Fischer-Tropsch catalysts. ACS Catalysis, 1985, 91: 241-253. [12] Z. Q. Yang, S. J. Guo, X. L. Pan, et al. FeN nanoparticles con#64257;ned in carbon nanotubes for CO hydrogenation[J]. Energy Environmental Science, 2011, 4: 4500-4503. [13] A. Ramirez, L. Gevers. Metal organic framework-derived iron catalysts for the direct hydrogenation of CO2 to short chain ole#64257;ns[J]. ACS Catalysis, 2018, 8: 9174-9182. [14] M. Q. Wang, W. H. Hang, H. H. Wang, et al. Pyrolyzed Fe#8722;N#8722;C composite as an efficient non-precious metal catalyst for oxygen reduction reaction in acidic medium[J]. ACS Catalysis, 2014, 4: 3928-3936. [15] B. An, K. Cheng, C. Wang, et al. Pyrolysis of metal#8722;organic frameworks to Fe3O4@Fe5C2 core#8722;shell nanoparticles for Fischer#8722;Tropsch synthesis[J]. ACS Catalysis, 2016, 6: 3610-3618.

3. 毕业设计（论文）进程安排

2019.3.1-2019.3.10 查阅收集文献资料，了解课题背景，完成开题报告的撰写，为实验做准备工作。

2019.3.11-2019.3.31 合成zn mof材料，再制备不同焙烧温度下的fe-n-c催化剂。

2019.4.1-2019.4.15 对制备出的催化剂进行各种表征测试，并且撰写中期自查表。