1. 毕业设计（论文）的内容和要求

无机颜料群青是最古老和最鲜艳的蓝色颜料，无毒害、环保，属无机颜料范畴。

它用于提白、消除白色涂料或其它白色颜料中的黄色光，耐碱、耐高温，在大气中对日晒及风雨侵蚀极其稳定。

随着环保要求的提高，无机颜料受到更多关注。

2. 参考文献

[1] Menezes R A D, Paz S P A D, Ang#233;lica R S, et al. Color and shade parameters of ultramarine zeolitic pigments synthesized from kaolin waste[J]. Materials Research. 2014, 17(suppl 1): 23-27. [2] Kowalak S, Jankowska A. Application of zeolites as matrices for pigments[J]. MICROPOROUS AND MESOPOROUS MATERIALS. 2003, 61(1-3): 213-222. [3] Berke H. The invention of blue and purple pigments in ancient times[J]. Chem. Soc. Rev. 2007, 36(1): 15-30. [4] Yuan Y, Chen H. Controlling and tuning the dispersion properties of calcined kaolinite particles in various organic solvents via stepwise modification method using 3-glycidoxypropyltrimethoxysilane and dodecylamine[J]. Applied Surface Science. 2013, 277(277): 281-287. [5] 胡鼎文，张文朴. 群青的元素组成和色调的研究[J]. 北京师范大学学报(自然科学版). 1988(03): 95-96. [6] Kajinebaf V T, Rezaeian F, Rajabi M, et al. Replacing nano-clay for kaolin in ultramarine pigments[J]. PIGMENT RESIN TECHNOLOGY. 2014, 43(1): 1-7. [7] Hamerton I, Tedaldi L, Eastaugh N. A Systematic Examination of Colour Development in Synthetic Ultramarine According to Historical Methods[J]. PLoS One. 2013, 8(2): e50364. [8] 易发成，杨剑，宋绵新，等. 利用埃洛石粘土制备群青蓝的研究[J]. 矿产综合利用. 2000(04): 8-12. [9] Gobeltz N, Demortier A, Lelieur J P, et al. Encapsulation of the chromophores into the sodalite structure during the synthesis of the blue ultramarine pigment[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS. 1998, 94(15): 2257-2260. [10] 初政伟，徐会君，王建伟，等. 废弃分子筛制备群蓝颜料研究[J]. 广东化工. 2014(12): 12-13. [11] Kowalak S, Jankowska A, Zeidler S, et al. Sulfur radicals embedded in various cages of ultramarine analogs prepared from zeolites[J]. Journal of Solid State Chemistry. 2007, 180(3): 1119-1124. [12] Menezes R A, Paz S P A, Angelica R S, et al. Synthesis of ultramarine pigments from Na-A zeolite derived from kaolin waste from the Amazon[J]. CLAY MINERALS. 2017, 52(1): 83-95. [13] 许立和. 利用SiO_2包膜技术提高群青蓝颜料耐酸性的研究[J]. 化工新型材料. 2003(03): 39-40. [14] Kowalak S, Paw#322;owska M, Milu#347;ka M, et al. Synthesis of ultramarine from synthetic molecular sieves[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 1995, 101(2): 179-185. [15] Arieli D, Vaughan D E W, Goldfarb D. New Synthesis and Insight into the Structure of Blue Ultramarine Pigments[J]. Journal of the American Chemical Society. 2004, 126(18): 5776-5788. [16] 谢凯成. 改性群青[J]. 涂料工业. 1994(06): 50.

3. 毕业设计（论文）进程安排

2019.02.25-03.25 完成翻译和开题报告 2019.03.26-03.31 准备实验材料，熟悉实验技能 2019.04.01-04.30 完成群青的制备和表征 2019.05.01-05.20 完成群青的改进和性能测试 完成中期检查 2019.05.21-06.06 完成毕业论文和答辩ppt