1. 毕业设计（论文）的内容和要求

1. 学会采用各种文献检索手段对特定课题进行检索的方法，培养阅读中外文献资料的能力。

2. 培养综合运用所学专业知识分析、解决实际问题的能力。

3．培养独立开展实验研究、独立思考和分析问题与现象,并解决问题,完成课题的工作能力。

2. 参考文献

[1]罔翠红,李紅艳,路嫉,蔡清海.CO2电催化还原产物最新研究进展[J].化学工程师，2010，(7): 42-45． [2] Chu, S. Majumdar, A. Opportunities and challenges for a sustainable energy future. Nature 488, 294#8211;303 (2012). [3] Huang, J.; Buonsanti, R. Colloidal Nanocrystals as Heterogeneous Catalysts for Electrochemical CO2 Conversion. Chem. Mater. 2019, 31, 13#8722;25. [4] Reske, R.; Mistry, H.; Behafarid, F.; Roldan Cuenya, B.; Strasser, P. Particle size effects in the catalytic electroreduction of CO(2) on Cu nanoparticles. J. Am. Chem. Soc. 2014, 136, 6978#8722;6986. [5] Ren, D.; Deng, Y. L.; Handoko, A. D.; Chen, C. S.; Malkhandi, S.; Yeo, B. S. Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts. ACS Catal.2015, 5, 2814#8722;2821. [6] Kim, D.; Resasco, J.; Yu, Y.; Asiri, A. M.; Yang, P. Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold-copper bimetallic nanoparticles. Nat.Commun. 2014, 5, 5948. [7] Hoang, T. T. H.; Verma, S.; Ma, S.; Fister, T. T.; Timoshenko, J.; Frenkel, A. I.; Kenis, P. J. A.; Gewirth, A. A. Nanoporous CopperSilver Alloys by Additive-Controlled Electrodeposition for the Selective Electroreduction of CO2 to Ethylene and Ethanol. J. Am. Chem. Soc. 2018, 140, 5791#8722;5797. [8] Wang, Y.; Wang, D.; Dares, C. J.; Marquard, S. L.; Sheridan, M.V.; Meyer, T. J. CO2 reduction to acetate in mixtures of ultrasmall (Cu) n,(Ag) m bimetallic nanoparticles. Proc. Natl. Acad. Sci. U. S. A.2018, 115, 278#8722;283. [9] Gilroy, K. D.; Ruditskiy, A.; Peng, H. C.; Qin, D.; Xia, Y.Bimetallic Nanocrystals: Syntheses, Properties, and Applications. Chem. Rev. 2016, 116, 10414#8722;72. [10] Ruditskiy, A.; Peng, H. C.; Xia, Y. Shape-Controlled Metal Nanocrystals for Heterogeneous Catalysis. Annu. Rev. Chem. Biomol. Eng. 2016, 7, 327#8722;48. [11] Wang, X.; Ruditskiy, A.; Xia, Y. N. Rational design and synthesis of noble-metal nanoframes for catalytic and photonic applications. Natl. Sci. Rev. 2016, 3, 520#8722;533. [12] Hong, J. W.; Kim, D.; Lee, Y. W.; Kim, M.; Kang, S. W.; Han, S.W. Atomic-distribution-dependent electrocatalytic activity of Au-Pd bimetallic nanocrystals. Angew. Chem., Int. Ed. 2011, 50, 8876#8722;80. [13] Feng, Y.; He, J.; Wang, H.; Tay, Y. Y.; Sun, H.; Zhu, L.; Chen, H. An unconventional role of ligand in continuously tuning of metalmetal interfacial strain. J. Am. Chem. Soc. 2012, 134, 2004#8722;7. [14] Xia, Y.; Gilroy, K. D.; Peng, H. C.; Xia, X. Seed-Mediated Growth of Colloidal Metal Nanocrystals. Angew. Chem., Int. Ed. 2017,56, 60#8722;95. [15] Liu, X.; Xiao, J.; Peng, H.; Hong, X.; Chan, K.; Norskov, J. K. Understanding trends in electrochemical carbon dioxide reduction rates. Nat. Commun. 2017, 8, 15438. [16] Huang, X.; Li, Y.; Zhou, H.; Zhong, X.; Duan, X.; Huang, Y. Simplifying the creation of dumbbell-like Cu-Ag nanostructures and their enhanced catalytic activity. Chem. - Eur. J. 2012, 18, 9505#8722;9510.

3. 毕业设计（论文）进程安排

1．1-4周：阅读相关文献，了解专业背景，完成翻译。

2．5-8周：熟悉实验室的仪器设备，掌握基本的制备过程#8212;#8212;催化剂的合成、电极的制备。

3．9-12周：采用xrd、sem、bet、tem等对粉体进行表征，测试催化剂的各种基本性质。