Ce、La掺入对Ni/NaF自热重整乙酸乙酯制氢的影响任务书
2020-05-01 08:42:29
1. 毕业设计(论文)的内容和要求
1.毕业论文主要内容 本课题开展类地沟油酯(乙酸乙酯)与水共重整制氢的基础研究,重点探讨ce、la掺入对ni/naf自热重整乙酸乙酯制氢的影响。
2.毕业论文主要要求 ①学生应高度重视毕业设计(论文)工作,严格要求自己,自觉遵守学习纪律和各项规章制度。
②毕业设计(论文)期间,实行考勤制度,一般不准请假,确因特殊情况需要请假时,须按照学校有关规定执行。
2. 参考文献
[1] Kapran A Y , Orlyk S M . Hydrogen Production in Methanol Reforming on Modified Copper#8211;Zinc Catalysts: A Review[J]. Theoretical and Experimental Chemistry, 2017, 53(1):1-16. [2] Es A C A C , Es A C . Hydrogen production through glycerol steam reforming using Co catalysts supported on SBA-15 doped with Zr, Ce and La[J]. Journal of Energy Chemistry, 2017, 26(1):42. [3] Akri M , Pronier, St#233;phane, Chafik T , et al. Development of nickel supported La and Ce-natural illite clay for autothermal dry reforming of methane: Toward a better resistance to deactivation[J]. Applied Catalysis B: Environmental, 2017, 205:519-531. [4] Tang M , Liu K , Roddick D M , et al. Enhanced lattice oxygen reactivity over Fe2O3/Al2O3 redox catalyst for chemical-looping dry (CO2) reforming of CH4: Synergistic La-Ce effect[J]. Journal of Catalysis, 2018, 368:38-52. [5] Wang F , Xu L , Shi W , et al. Thermally stable Ir/Ce0.9La0.1O2 catalyst for high temperature methane dry reforming reaction[J]. Nano Research, 2017, 10(2):364-380. [6] Adamu S , Razzak S A , Hossain M M . Fluidizable Ni/Ce-meso-Al 2 O 3, for gasification of glucose: Effect of catalyst reduction on hydrogen selectivity[J]. Journal of Industrial and Engineering Chemistry, 2018:S1226086X18301709. [7] Phongboonchoo Y , Thouchprasitchai N , Pongstabodee S . Hydrogen production with a low carbon monoxide content via methanol steam reforming over Cu x Ce y Mg z /Al 2 O 3, catalysts: Optimization and stability[J]. International Journal of Hydrogen Energy, 2017:S0360319917310571. [8] Bimbela F , J. Aacute;brego, Puerta R , et al. Catalytic steam reforming of the aqueous fraction of bio-oil using Ni-Ce/Mg-Al catalysts[J]. Applied Catalysis B Environmental, 2017, 209:346-357. [9] Rosha P , Mohapatra S K , Mahla S K , et al. Biogas reforming for hydrogen enrichment by ceria decorated over nickel catalyst supported on titania and alumina[J]. International Journal of Hydrogen Energy, 2018. [10] Li X , Yan B , Zhang J , et al. Hydrogen production by aqueous phase reforming of phenol derived from lignin pyrolysis over NiCe/ZSM-5 catalysts[J]. International Journal of Hydrogen Energy, 2018, 43(2):649-658. [11] Majid T , Hossein A , Armin R , et al. Excellent catalytic performance of 3D-mesoporous KIT-6 supported Cu and Ce nanoparticles in methanol steam reforming[J]. International Journal of Hydrogen Energy, 2018, 43(24):10926-10937. [12] Li L , Jiang B , Tang D , et al. Hydrogen generation by acetic acid steam reforming over Ni-based catalysts derived from La 1?x Ce x NiO 3, perovskite[J]. International Journal of Hydrogen Energy, 2018:S0360319918305950. [13] Zhang L , Wang X , Chen C , et al. Investigation of mesoporous NiAl 2 O 4 /MO x (M = La, Ce, Ca, Mg)#8211;γ-Al 2 O 3 nanocomposites for dry reforming of methane[J]. RSC Advances, 2017, 7(53):33143-33154. [14] Bepari S , Basu S , Pradhan N C , et al. Steam reforming of ethanol over cerium-promoted Ni-Mg-Al hydrotalcite catalysts[J]. Catalysis Today, 2017, 291. [15] Han X , Yu Y , He H , et al. Hydrogen production from oxidative steam reforming of ethanol over rhodium catalysts supported on Ce#8211;La solid solution[J]. International Journal of Hydrogen Energy, 2013, 38(25):10293-10304. [16] Stekrova M , Rinta-Paavola A , Karinen R . Hydrogen production via aqueous-phase reforming of methanol over nickel modified Ce, Zr and La oxide supports[J]. Catalysis Today, 2017:S0920586117305527. [17] Zhang Q , Li L , Jiang B , et al. Hydrogen by chemical looping reforming of ethanol: The effect of promoters on La 2- x M x NiO 4- λ, ( M = Ca, Sr and Ce) oxygen carriers[J]. Chemical Engineering Science, 2017, 174. [18] Mousavi S M , Meshkani F , Rezaei M . Preparation of nanocrystalline Zr, La and Mg-promoted 10% Ni/Ce 0.95 Mn 0.05 O 2, catalysts for syngas production via dry reforming reaction[J]. International Journal of Hydrogen Energy, 2018, 43(13):6532-6538. [19] Bussi J , Musso M , Quevedo A , et al. Structural and catalytic stability assessment of Ni-La-Sn ternary mixed oxides for hydrogen production by steam reforming of ethanol[J]. Catalysis Today, 2017, 296. [20] Basile F , Mafessanti R , Fasolini A , et al. Effect of synthetic method on CeZr support and catalytic activity of related Rh catalyst in the oxidative reforming reaction[J]. Journal of the European Ceramic Society, 2018:S0955221918300748. [21] Jun Z , Japhet O , Shilong F , et al. Hydrogen production from cellulose catalytic gasification on CeO 2 /Fe 2 O 3, catalyst[J]. Energy Conversion and Management, 2018, 171:241-248.
3. 毕业设计(论文)进程安排
起讫日期 设计(论文)各阶段工作内容 2018.12.25~2018.12.31 课题任务书 2019.1.1~2019.1.14 开题报告、文献综述、英文翻译 2019.1.15~2019.2.23 试验材料准备 、设计实验方案 2019.2.24~2019.5.2 进行实验 2019.5.3~2019.5.8 实验、中期答辩 2019.5.9~2019.5.30 实验、整理实验数据、毕业论文撰写 2019.5.31~2019.6.10 毕业论文撰写、答辩