氮掺杂碳材料的制备及其催化性能研究任务书
2020-05-01 08:47:47
1. 毕业设计(论文)的内容和要求
1.毕业论文主要内容 一氧化二氮(n2o),俗称笑气,是一种重要的温室气体对臭氧层具有严重的破坏作用。
随着环境的恶化,大气中n2o的含量逐年增加。
近年来人们环保意识逐渐增加,n2o减排已经成为全世界共同关注的重要问题。
2. 参考文献
[1]Chitosan Waste-Derived Co and N Co-doped Carbon Electrocatalyst for Efficient Oxygen Reduction Reaction[J]. ChemElectroChem, 2015, 2(11):1806-1812. [2]Xu H, Yan B, Li S, et al. One-pot fabrication of N-doped graphene supported dandelion-like PtRu nanocrystals as efficient and robust electrocatalysts towards formic acid oxidation[J]. J Colloid Interface Sci, 2017, 512:96-104. [3]Balamurugan J , Thanh T D , Heo S B , et al. Novel route to synthesis of N-doped graphene/Cu#8211;Ni oxide composite for high electrochemical performance[J]. Carbon, 2015, 94:962-970. [4]Yan X L, Li H F, Wang C, et al. Melamine as a single source for fabrication of mesoscopic 3D composites of N-doped carbon nanotubes on graphene[J]. Rsc Advances, 2018, 8(22):12157-12164. [5]Atinafu D G, Dong W, Huang X, et al. One-pot synthesis of light-driven polymeric composite phase change materials based on N-doped porous carbon for enhanced latent heat storage capacity and thermal conductivity[J]. Solar Energy Materials Solar Cells, 2018, 179. [6]Chen X , Liang Y , Wan L , et al. Construction of porous N-doped graphene layer for efficient oxygen reduction reaction[J]. Chemical Engineering Science, 2018:S0009250918302021. [7]Jiang H , Zhao T , Shi L , et al. First-Principles Study of Nitrogen-, Boron-Doped Graphene and Co-Doped Graphene as the Potential Catalysts in Nonaqueous Li-O-2 Batteries[J]. Journal of Physical Chemistry C, 2016, 120:6612-6618. [8]Cong H P , Wang P , Gong M , et al. Facile synthesis of mesoporous nitrogen-doped graphene: An efficient methanol#8211;tolerant cathodic catalyst for oxygen reduction reaction[J]. Nano Energy, 2014, 3:55-63. [9]Na W, Ma W, Ren Z, et al. Template synthesis of nitrogen-doped carbon nanocages#8211;encapsulated carbon nanobubbles as catalyst for activation of peroxymonosulfate[J]. Inorganic Chemistry Frontiers, 2018. [10]Yang L , Xu G , Ban J , et al. Metal-organic framework-derived metal-free highly graphitized nitrogen-doped porous carbon with a hierarchical porous structure as an efficient and stable electrocatalyst for oxygen reduction reaction[J]. Journal of Colloid and Interface Science, 2018. [11]Wu Z , Song M , Zhang Z , et al. Porous two-dimensional layerd molybdenum compounds coupled with N-doped carbon based electrocatalysts for hydrogen evolution reaction[J]. Applied Surface Science, 2019, 465:724-729. [12]Zhu Q , Deng H , Su Q , et al. A free-standing nitrogen-doped porous carbon foam electrode derived from melaleuca bark for lithium-sulfur batteries[J]. Electrochimica Acta, 2018. [13]Xue S , Duihai T , Wenting Z , et al. Molten salt synthesis of Co-entrapped, N-doped porous carbon from various nitrogen precursors as efficient electrocatalysts for hydrogen evolution[J]. Journal of Materials Science, 2018. [14]Cobalt Nanoparticles Embedded in Nitrogen-Doped Carbon for the Hydrogen Evolution Reaction[J]. ACS Applied Materials Interfaces, 2015, 7(15):8083-8087. [15]Yu Z, Wang X, Song X, et al. Molten salt synthesis of nitrogen-doped porous carbons for hydrogen sulfide adsorptive removal[J]. Carbon, 2015, 95:852-860. [16]Pyridinic N: A special group for enhancing direct decomposition reaction of NO over N-doped porous carbon[J]. Microporous Mesoporous Materials, 2018, 265. [17]Deng D, Novoselov K S, Qiang F, et al. Catalysis with two-dimensional materials and their heterostructures[J]. Nature Nanotechnology, 2016, 11(3):218. [18]Li J , Yin S , Dong F , et al. Tailoring Active Sites via Synergy between Graphitic and Pyridinic N for Enhanced Catalytic Efficiency of a Carbocatalyst[J]. ACS Applied Materials Interfaces, 2017, 9(23). [19]Li J , Yin S , Dong F , et al. Tailoring Active Sites via Synergy between Graphitic and Pyridinic N for Enhanced Catalytic Efficiency of a Carbocatalyst[J]. ACS Applied Materials Interfaces, 2017, 9(23). [20]Cui X , Li Y , Bachmann S , et al. Synthesis and Characterization of Iron-Nitrogen-Doped Graphene/Core-Shell Catalysts: Efficient Oxidative Dehydrogenation of N-Heterocycles[J]. Journal of the American Chemical Society, 2015:150731112037007. [21]Yang W . N,S-Codoped microporous carbon nanobelts with blooming nanoflowers for oxygen reduction[J]. Journal of Materials Chemistry A, 2016, 4(16):5834-5838. [22]Mesoporous nitrogen-doped carbons with high nitrogen contents and ultrahigh surface areas: synthesis and applications in catalysis[J]. Green Chemistry, 2016, 18.
3. 毕业设计(论文)进程安排
起讫日期 设计(论文)各阶段工作内容2018.12.23~2018.12.25 课题任务书 2018.12.25~2019.1.18 英文翻译、开题报告 2019.1.18~2019.2.21 文献综述、试验材料准备 2019.2.21~2019.3.9 设计实验方案、进行实验 2019.3.10~2019.5.2 实验 2019.5.3~2019.5.8 实验、中期答辩 2019.5.9~2019.5.30 实验、整理实验数据、毕业论文撰写 2019.5.31~2019.6.10 毕业论文撰写、答辩