负载型MoS2催化剂用于邻硝基氯苯脱硫反应性能研究任务书
2020-05-10 02:41:24
1. 毕业设计(论文)的内容和要求
邻硝基氯苯是用途广泛的有机化工原料,其应用领域非常广泛,可制备橡胶助剂、农药、染料和医药、香精香料产品,如橡胶防老剂4010na和4020系列、杀菌剂多菌灵、药品利福平、扑热息痛、氟哌酸、大红染料、香兰素等。
而工业上生产的邻硝基氯苯往往带有少量的噻吩及其衍生物,对其中的噻吩类硫化物进行脱除具有重要的意义。
本论文利用二硫化钼作为活性组分,制备负载氧化铝型催化剂。
2. 参考文献
[1] 山城. 对/邻硝基氯苯的市场现状及发展建议[J].精细与专用化学品.2013(13) [2] Desai P H , Lee S L , Jonker R J , et al . 1994 Akzo Nobel Catalysts Symposium, Noordwijk , The Netherlands [3] King D L ,Faz C ,Flynn T. Desulfurization of gasoline feedstocks for application in fuel reforming[C].Detroit,Michigan :Society of Automotive Engineers(SAE) ,2000. [4] 罗国华,徐新,佟泽民. 沸石分子筛选择吸附焦化苯中的噻吩[J]. 燃料化学学报,1999 ,27 (5) :466 - 480. [5] Ralpht Y, Arturo J H, Frances H Y. Desulfurization of transportation fuels with zeolites under ambient conditions [J]. Science, 2003, 301(4):79-81. [6] Mikhail S ,Zaki T , Khalil L. [J] . Applied Catalysis A: General , 2002 ,227(3) :265 - 278. [7] Ine R L, Benson B A, Varraveto D M. Low cost breakthrough for low sulfur gasoline[C]/1999 NPRA Annual Meeting. Texas: San Antonic, 1999. [8] Greenwood G J. Next generation sulfur removal technology [C].NPRA Annual Meeting, Texas: San Antonic, 2000. [9] 陈焕章,李永丹,赵地顺.催化裂化汽油吸附脱硫工艺研究[J].化学工程,2006, 34(7): 1-5 [10] 张艳姝,郑经堂,赵玉翠.柴油耦合氧化吸附脱硫的研究[J].山东化工, 2006, 35(3): 13-15. [11] 陈晓萍,陈爱平,刘伟.交联粘土用于催化裂化汽油吸附脱硫[J].机械工程材料,2005,29(8):62-64 [12] 安军信.先进的流化催化裂化技术[R].美国化学学会第218次会议,2000. [13] 李春义,山红红,赵博艺,.汽油催化裂化脱硫USY/ZnO/A l2O3催化剂[J].物理化学学报,2001,17(7):641-644. [14] 王鹏,陈辉,宗保宁.降低催化裂化汽油硫质量浓度的固体助剂[J].石油炼制与化工,2003,34(10):14-17. [15] Tam P S, Kittrell J R, Eldridge J W. Desulfurization of Fuel Oil by Oxidation and Extraction. 1.Enhancement of Extraction Oil Yield[j]. Ind. Eng. Chem. Res., 1990, 29: 321~324. [16] Liu W, Lei Z, Wang J. Kinetics and Mechanism of Plasma Oxidative Desulfurization in Liquid Phase[J]. Energy Fuels, 2001, 15: 38~43. [17] Nehlsen J, Benziger J, Kevrekidis I. Oxidation of Aliphatic and Aromatic Sulfides Using Sulfuric Acid[J]. Ind. Eng. Chem. Res., 2006, 45: 518~524. [18] Wang W, Wang S, Liu H, et al. Desulfurization of gasoline by a new method of electrochemical catalytic oxidation[J]. Fuel, 2007, 86: 2747~2753. [19] Qian E W. Development of Novel Nonhydrogenation Desulfurization Process: Oxidative Desulfurization of Distillate[J]. J. Jpn. Petrol. Inst., 2008, 51: 14~31. [20] Liu S, Wang B, Cui B, et al. Deep desulfurization of diesel oil oxidized by Fe (VI) systems[J].Fuel, 2008, 87: 422~428. [21] Chan N Y, Lin T, Yen T F. Superoxides: Alternative Oxidants for the Oxidative Desulfurization Process[J]. Energy Fuels, 2008, 22: 3326~3328.
3. 毕业设计(论文)进程安排
2015.12.15-2016.1.15 查阅资料,完成开题报告。
2016.2.25-2016.3.5 确定方案,学习实验过程和操作。
2016.3.5-2016.5.5 按照实验计划和要求,独立实验。