界面聚合制备聚酰胺反渗透膜的基础研究任务书
2020-05-20 21:10:57
1. 毕业设计(论文)的内容和要求
以均苯三甲酰氯和间苯二胺为水相与油相的主体物质,通过界面聚合方法制得高通量的反渗透复合膜。
要求翻译一篇与课题相关的英文文献,阅读15篇以上参考文献。
了解改变膜通量的主要因素,以及确定其通量最高时的参数。
2. 参考文献
[1] V. Gewin, Industry lured by the gains of going green, Nature, 2005, 436: 173-173 [2] C. Fritzmann, J. Lowenberg, T. Wintgens, T. Melin, State-of-the-art of reverse osmosis desalination, Desalination, 2007, 216: 1-76 [3] T. Y. Cath, A. E. Childress, M. Elimelech, Forward osmosis: Principles, applications, and recent developments, Journal of Membrane Science, 2006, 281: 70-87 [4] S. Loeb and S. Sourirajan, High flow porous membranes for separation of water from saline solutions, U.S. Patent 3.133.132, 1964 [5] J. E. Cadotte, Interfacially synthesized reverse osmosis membrane, U.S. Patent 4.277.344, 1981 [6] V. Freger, Kinetics of film formation by interfacial polycondensation, Langmuir, 2005, 21: 1884-1894 [7] V. Freger, Nanoscale heterogeneity of polyamide membranes formed by interfacial polymerization, Langmuir, 2003, 19: 4791-4797 [8] A.Prakash Rao, N.V.Desai, R.Rangarajan. Interfacially synthesized thin film RO composite membranes for seawater desalination [J]. Journal of Membrane Science, 1997, 124(2): 263-272 [9] Seung-Yeop Kwak. Relationship of relaxation property to RO permeability in aromatic polyamide thin-film-composite membranes [J]. Polymer, 1999, 40: 6361-6368 [10] Neil P. Soice, Alan R. Greenberg, William B. Krantz, Arlan D. Norman. Studies of oxidative degradation in polyamide RO membrane barrier layers using pendant drop mechanical analysis [J]. Journal of Membrane Science, 2004, 243(1-2): 345-355 [11] M.I. Iborra, J. Lora, M.I. Alcaina, J.M. Arnal. Effect of oxidation agents on RO membrane performance to brackish water desalination [J]. Desalination, 1996, 108(1-3): 83-89 [12] Shigeji Konagaya, Masaya Tokai, Hideshi Kuzumoto. RO performance and chlorine resistance of new ternary aromatic copolyamides comprising 3,4ˊ-diaminodiphenylsulfone and a comonomer with a carboxyl group [J]. Journal of Applied Polymer Science, 2001, 80: 505-513 [13] Eric M. Vrijenhoek, Seungkwan Hong, Menachem Elimelech. Influence of membrane surface properties on initial rate of colloidal fouling of RO and NF membranes [J]. Journal of Membrane Science, 2001, 188(1): 115-128 [14] S. Belfer, Y. Purinson, R. Fainshtein, Y. Radchenko, O. Kedem. Surface modification of commercial composite polyamide RO membranes [J]. Journal of Membrane Science, 1998, 139(2): 175-181 [15] Wei Zhang, Gaohong He, Ping Gao, Guohua Chen. Development and characterization of composite NF membranes and their application in concentration of antibiotics [J]. Separation and Purification Technology, 2003, 30(1): 27-35
3. 毕业设计(论文)进程安排
2015.2:查阅相关文献,了解课题背景 2015.3.1:完成英文翻译和开题报告 2015.3.10 了解制膜工艺,掌握界面聚合制膜的整个过程。
2015.3.20了解影响膜通量的因素。
2015.4.20 通过改变反应原料浓度,处理时间与温度,得到最优的反渗透复合膜。