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毕业论文网 > 任务书 > 材料类 > 材料科学与工程 > 正文

掺加BMT铌镁酸铅-钛酸铅弛豫铁电陶瓷的制备及其应变的研究任务书

 2020-06-06 11:03:43  

1. 毕业设计(论文)的内容和要求

随着电子设备及元器件向着小型、高效方向发展的需要,特别是集成电路、计算机和表面组装等电子信息技术发展的需求,使得压电材料的市场需求量与日俱增。铌镁酸铅-钛酸铅(pmn-pt)弛豫铁电陶瓷是弛豫铁电体pmn和普通铁电体pt的固溶体,pmn通过掺入pt能有效改善pmn的性能,使其具有优良的电性能,但其电致应变与无铅含铋基铁电陶瓷相比,性能又有所不及(特别是应用温度范围;故本课题组首先合成0.65pmn-0.35pt铁电陶瓷,然后掺入钛镁酸铋铁(bmt)改性pmn-pt陶瓷,最后选取合适的工艺制度制备得到性能优越的铁电陶瓷。为了顺利完成毕业论文并力求得到锻炼:

1、掌握常用的文献检索手段和方法,通过相对该同学提出的具体要求如下关文献查阅,了解常用的弛豫铁电陶瓷材料,对弛豫铁电材料的各种制备方法进行综述,要求阅读中英文文献不少于10篇。

2、在文献综述的基础上,根据毕业论文任务安排,独立制定出论文的研究方案、解决途径及工作计划,完成开题报告。

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2. 参考文献

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钟维烈. 铁电物理学[M]. 北京: 科学出版社, 2000.

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田中哲郎(日)等. 压电陶瓷材料[M]. 北京: 科学出版社, 1978.

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D. Viehland, S. Jang. The dielectric relaxation of lead magnesium niobate relaxor ferroelectrics[J]. Philosophical Magazine B, 1991, 64(3):335-344.

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张孝文.弛豫铁电材料的微结构和特性,中国科学院技术科学论坛第十、十一次学术报告会论文集[D],2004.

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Smolensky G A, Isupon V A, Agranaovska A I, et al. Ferroelectrics with diffuse phase transition[J]. Soc Phys Solid State, 1961, 2(11):2584-2594.

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Smolensky G A. Physical phenomena in ferroelectrics with diffused phase transition[J]. J Phys Soc Jpn, 1970, 28 (Supple): 26-37

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Cross L E. Relaxor ferroeolectrics[J]. Ferroelectrics, 1987, 76: 241-267.

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Viehland D, Jang S J, Cross L E, et al. Freezing of the polarization fluctuations in lead magnesium niobate relaxors[J]. J Appl Phys, 1990,68: 2916.

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Lee KM,Jang HM,Park WJ, Mechanism of 1:1 non-stoichiometric short-range ordering in La-doped Pb(Mg1/3Nb2/3)O3 relaxor ferroelectric[J]. J. Mat. Res, 1997, 12(6):1603-1613.

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Westphal V Kleemann w'Glinchuk M D.Diffuse phase transitions and random-field-induced domain states ofthe relaxor ferroelectric PbMg1/3Nb2/3O3[J]. Phys. Rev.Lett, 1992, 68(6):847-50.

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GSchrmdt, Diffusive phase-transitions[J]. Ferroelectrics,1988,78:199-206.

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T.Egami, S.Teslic, W.Dmowski, PK.Davis and L-W Chen, H.Chen, Microscopic origin of relaxor ferroelectricity in PMN and PLZT[J]. J.Koren Phys.Soc, 1998, 83(6):3298-3304.

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Zhang X W, Fang F. Study of the Structure and Dielectric Relaxation Behavior of

Pb(Mg1/3Nb2/3)O3-PbTiO3 Ferroelectric Ceramics[J]. J. Mat. Res, 1999,14(12): 4581-4586.

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Lee D H, Kim N K. Crystallographic, Dielectric, and Diffuseness Characteristics of

PZN-PT Ceramics[J]. Mat. Let, 1989, 34 (3-6): 299-304.

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Kuwata J, Uchino K, Nomura S. Phase Transitions in Pb(Zn1/3Nb2/3)O3-PbTiO3System[J]. Ferroelectric, 1981, 37: 579-582.

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Shrout T R, Chang Z P, Kim N, et al. Dielectric Behavior of Single Crystals Near the (1-x) Pb(Mg1/3Nb2/3)O3-xPbTiO3 Morphotropic Phase Boundary[J]. Ferroelectric Letter Section, 1990, 12(3): 63-69.

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Wu X J, Xu J Y, Xiao J Z, et al. Growth of Ferroelectric Lead Germanate Single Crystal by the Vertical Bridgman Method[J]. Journal of Crystal Growth, 2004, 263(1-4): 208-213.

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Zeng H R, Yu H F, Chu R Q, et al. Domain Orientation Imaging of PMN-PT Single Crystals by Vertical and Lateral Piezoelectric Force Microscopy[J]. Journal of Crystal Growth, 2004, 267(1-2): 194-198.

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Park S E, Shrout T R. Ultrahigh Strain and Piezoelectric Behavior in Relaxor Based Ferroelectric Single Crystals[J]. Journal of Applied Physics, 1997, 82(4): 1804-1811.

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Jin L, Xi Z Z, Xu Z, et al. Study of Ferroelectric Domain Morphology in PMN-32%

PT Single Crystal[J]. Ceramics International, 2004, 30: 1695-1698.

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Li Z R, Xu Z, Yao X, et al. Phase Transition and Phase Stability in [110], [001], and [111]-oriented 0.68Pb(Mg1/3Nb2/3)O3-0.32PbTiO3 Single Crystal under Electric Field[J]. Journal of Applied Physics, 2008, 104(2): 0241121-0241129.

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Lim L C, Rajan K. K. High-homogeneity High-performance Flux-grown Pb(Zn1/3Nb2/3)O3-(6-7)%PbTiO3 Single Crystals[J]. Journal of Crystal Growth, 2004, 271(3-4): 435-444.

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Uchino K. J., Electrostrictive Actuators: Materials and Applications [J]. Ceram. Bull., 1986, 65: 647-652.

[30]

Nomura S., Uchino K. J., Electrostrictive Effect in Pb(Mg1/3Nb2/3)O3-Type Materials [J]. Ferroelectrics, 1982, 41: 117-132.

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Surya M. G., Viehland D., Compositional Studies of Lanthanaum-Modified Morphotopic Phase Boundary Pb(Mg1/3Nb2/3)O3-PbTiO3 Ceramics [J]. J. Am. Ceram. Soc., 1997, 80: 477-485.

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Jae-Hwan Park, Juyoung Park, Jae-Gwan Park, Byung-Kook Kim, Yoonho Kim. Piezoelectric properties in PMN-PT relaxer ferroelectrics with MnO2 addition[J]. Journal of the European Ceramic Society , 2001, 21:1383-1386.

[33]

Methee Promsawat , Anucha Watcharapasorn and Sukanda Jiansirisomboon. Effects of ZnO nanoparticulate addition on the properties of PMNT ceramics[J]. Nanoscale Research Letters,2012,7:65.

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M. Promsawata, J.Y.Y. Wongb, Z. Renb, H.N. Tailorb, A. Watcharapasorna, c, Z.-G.Yeb, S. Jiansirisomboon. Enhancement in dielectric, ferroelectric, and electrostrictive properties of Pb(Mg1/3Nb2/3)0.9Ti0.1O3 ceramics by CuO addition[J]. Journal of Alloys and Compounds, 2014, 587:618#8211;624.

3. 毕业设计(论文)进程安排

起讫日期

设计(论文)各阶段工作内容

备 注

2016-12-16~2017-01-10

查阅文献,制定实验方案,完成开题报告

2017-01-10~2017-02-10

制备0.65PMN-0.35PT弛豫铁电陶瓷,确定合适的煅烧、烧结工艺

2017-02-11~2017-04-10

掺入BMT改性PMN-PT基陶瓷,探讨BMT含量对PMN-PT基电性能的影响

2017-04-11~2017-05-31

利用XRD,SEM和铁电仪等手段对样品组成结构和电性能进行表征

2017-06-01~2017-06-13

毕业论文的撰写,完成毕业论文的各项结束工作和毕业答辩

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