1. 毕业设计（论文）的内容和要求

本论文研究课题名称为”循环伏安法制备聚吡咯-碳载pt催化剂的性能研究”。

采用循环伏安法（cv）在碳布上合成聚吡咯膜，通过调整合成条件（电解质）、温度、扫描圈数及扫描电位等条件来控制聚吡咯膜的厚度、致密度、导电率等因素，以达到最佳载体性能。

再采用电化学沉积法将pt催化剂颗粒担载在聚吡咯膜上，形成颗粒分散的、稳定性及催化活性都很高的新型燃料电池催化剂。

2. 参考文献

[1] 任丽，王立新等. 导电聚合物及导电聚吡咯的研究进展[J]. 材料导报,2002,16(02):60-62 [2] 宫兆合，梁国正，卢婷利等. 导电聚合物的研究进展[J]. 复合材料，2003,11(29):45-47. [3] Lv P，Feng Y Y，Li Y，et al．Carbon fabric-aligned carbon nanotube /MnO2 /conducting polymers ternary composite electrodes with high utilization and mass loading of MnO2 for super-capacitors[J]. J Power Sour, 2012,220: 160-168. [4] Xian X J，Jiao L Y，Xue T, et al. Nanovenee rs: An Electroche mical Approach to Synthesizing Condu ctive Layered Nanostructures[J]. Nano Lett, 2011,5 ( 5) : 4000-4006． [5] Bhattacharjya D, Mukhopadhyay I. Controlled growth of polyaniline fractals on HOPG through potentiodynamic electropolymerization[J]. Langmuir, 2012, 28: 5893-5899 [6] Qiufeng L. Unstirred preparation of soluble electroconductive polypyrrole nanoparticles[J]. Microchim Acta, 2010( 168) : 205-213． [7] Watanabe M, Tryk D A, Wakisaka M, et al. Overview of recent developments in oxygen reduction electrocatalysis[J]. Electrochimica Acta, 2012, 84: 187-201. [8] Li B H, Chan S H. PtFeNi tri-metallic alloy nanoparticles as electrocatalyst for oxygen reduction reaction in proton exchange membrane fuel cells with ultra-low Pt loading[J]. International Journal of Hydrogen Energy, 2013, 38(8): 3338-3345. [9] 侯俊波,俞红梅, 邵志刚等. 质子交换膜燃料电池的0℃以下耐受性[J]. 电池, 2006, 37(06): 411-414. [10] 孙树成, 俞红梅, 侯俊波等. PEMFC在0℃以下环境启动的研究[J]. 电源技术, 2007, 31(08): 626-630. [11] Sumita M , Sakata K, A sai S , et al. Dispersio n o f fillers and the electrical conductivity of polymer blends filled with carbon black[J] . P olymer Bulletin , 1991 , 25: 265-271. [12] Sumita M, Sakata K, Hay akawa Y, et al. Double percolation effect on the electrical conductivity of conductive particles filled polymer blends[J]. Colloid and Polymer Science, 1992,270 : 134-139. [13] Authayanun S, Im-Orb K, Arpornwichanop A. A review of the development of high temperature proton exchange membrane fuel cells[J]. Chinese Journal of Catalysis, 2015, 36(4): 473-483. [14] Cheng W, Shubo W, Jianbo Z, et al. The Durability Research on the Proton Exchange Membrane Fuel Cell for Automobile Application[J]. PROGRESS IN CHEMISTRY, 2015, 27(4): 424-435. [15] Shih N C, Weng B J, Lee J Y, et al. Development of a 20 kW generic hybrid fuel cell power system for small ships and underwater vehicles[J]. International Journal of Hydrogen Energy, 2014, 39(6):1-8. [16] 王磊磊. 质子交换膜燃料电池膜电极稳定性研究[D]. 大连理工大学, 2007. [17] Cheng W, Shubo W, Jianbo Z, et al. The Key Materials and Components for Proton Exchange Membrane Fuel Cell[J]. PROGRESS IN CHEMISTRY, 2015, 27(2-3): 310-320. [18] 李俊, 张震. 质子交换膜燃料电池用催化剂及其稳定性改进方法研究进展[J]. 材料导报, 2011, 25(2): 48-51. [19] Chalk Steven G, Miller James E. Key challenges and recent progress in batteries, fuel cells, and hydrogen storage for clean energy systems[J]. Journal of Power Sources, 159(1): 73-80. [20] Malek K, FrancoA A. Microstructure-Based Modeling of Aging Mechanisms in Catalyst Layers of Polymer Electrolyte Fuel Cells[J]. The Journal of Physical Chemistry B, 2011, 115(13): 8088-8101. [21] Nepel T C M, Lopes P P, Paganin V A, et al. CO tolerance of proton exchange membrane fuel cells with Pt/C and PtMo/C anodes operating at high temperatures: A mass spectrometry investigation[J]. Electrochimica Acta, 2013, 8(1): 217-224. 学生在此基础上自行查阅相关文献至少10篇。

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 备 注 2016.12.12-2016.12.25 了解课题背景，查阅文献 2016.12.26-2017.1.8 文献综述，翻译外文资料，熟悉课题及实验设备 2017.1.9-2017.1.14 写出开题报告，确定实验方案 2017.2.13-2017.3.10 采用CV法制备聚吡咯膜，选择不同工艺参数对聚吡咯膜进行改进 2017.3.11-2017.4.29 选取制备成功的电极进行电化学性能测试、XRD、SEM等测试 2017.4.30-2017.5.6 中期检查 2017.5.7-2017.6.3 选取最佳催化活性的复合催化剂SEM测试，进行表征与分析. 2017.6.4-2017.6.5 实验结果及数据的分析 2017.6.6-2017.6.12 撰写毕业论文、修改论文 2017.6.13-2017.6.21 论文答辩