登录

  • 登录
  • 忘记密码?点击找回

注册

  • 获取手机验证码 60
  • 注册

找回密码

  • 获取手机验证码60
  • 找回
毕业论文网 > 任务书 > 材料类 > 材料科学与工程 > 正文

多种锂硫电池正极材料的制备及其电化学性能研究任务书

 2020-06-07 21:25:41  

1. 毕业设计(论文)的内容和要求

能源问题是21世纪最重要的几大问题之一。

截至2012年,锂离子电池可获得的电池理论比容量和电池理论比能量虽已分别达到约250 mah/g和800 wh/kg,但仍无法满足日益增长的能量需求。

而硫作为一种廉价环保的材料,因为能在2.1v下每原子吸收两个电子,所以以硫为正极可获得1675mah/g的理论比容量和2600wh/kg的理论比能量。

剩余内容已隐藏,您需要先支付后才能查看该篇文章全部内容!

2. 参考文献

[1] HERBERT D, ULAM J, Electric Dry Cells and Storage Batteries: US 3043896[P]. 1962-07-10. [2] MANTHIRAM A, FU Y Z, CHUNG S H, et al. Rechargeable Lithium-Sulfur Batteries[J]. Chem. Rev., 2014, 114(23):11751-11787. [3] GUO J C, XU Y H, WANG C S. Sulfur-Impregnated Disordered Carbon Nanotubes Cathode for Lithium-Sulfur Batteries[J]. Nano Lett., 2011, 11: 4288-4294. [4] JI X L, LEE K T, NAZAR F L. A Highly Ordered Nanostructured Carbon-Sulphur Cathode for Lithium-Sulphur Batteries[J]. Nature Materials, 2009, 8: 500-506. [5] ELAZARI R, SALITRA G, AURBACH D, et al. Sulfur-Impregnated Activated Carbon Fiber Cloth as A Binder-Free Cathode for Rechargeable Li-S Batteries[J]. Adv. Mater., 2011, 23: 5641-5644. [6] LI X L, CAO Y L, LIU J, et al. Optimization of Mesoporous Carbon Structures for Lithium-Sulfur Battery Applications[J]. J. Mater. Chem., 2011, 21: 16603. [7] WANG J L, HE Y S, YANG J. Sulfur-Based Composite Cathode Materials for High-Energy Rechargeable Lithium Batteries[J]. Adv. Mater. 2015, 27: 569-575. [8] FU C Y, GUO J C. Challenges and Current Development of Sulfur Cathode in Lithium-Sulfur Battery[J]. Current Opinion in Chemical Engineering, 2016, 13: 53-62. [9] YIN Y X, GUO Y G, WAN L J, et al. Lithium-Sulfur Batteries: Electrochemistry, Materials, and Prospects[J]. Angew. Chem. Int. Ed. 2013, 52: 13186-13200. [10] WANG D W, GENTLE R I, LU G Q M, et al. Carbon-Sulfur Composites for Li-S batteries: Status and prospects[J]. J. Mater. Chem. A, 2013, 1: 9382-9394. [11] MANTHIRAM A, FU Y Z, SU Y S, Challenges and Prospects of Lithium-Sulfur Batteries[J]. Acc. Chem. Res., 2013, 46(5):1125-1134. [12] PANG Q, NAZAR F L. Long-Life and High-Areal-Capacity Li-S Batteries Enabled by a Light-Weight Polar Host with Intrinsic Polysulfide Adsorption[J]. ACS Nano, 2016, 10: 4111-4118. [13] MA L, ZHUANG L H, ARCHER A L, et al. Enhanced Li-S Batteries Using Amine-Functionalized Carbon Nanotubes in the Cathode[J]. ACS Nano, 2016, 10: 1050-1059. [14] JI X L, EVERS S, NAZAR F L, et al. Stabilizing Lithium-Sulphur Cathodes Using Polysulphide Reservoirs[J]. Nature Communications, 2011, 2: 325. [15] LIANG Z, ZHENG G Y, CUI Y, et al. Sulfur Cathodes with Hydrogen Reduced Titanium Dioxide Inverse Opal Structure[J]. ACS Nano, 2014, 8(5):5249-5256. [16] PANG Q, KUNDU D, NAZAR F L, et al. Surface-Enhanced Redox Chemistry of Polysulphides on a Metallic and Polar Host for Lithium-Sulphur Batteries[J]. Nature Communications, 2014, 5:4759. [17] FAN Q, LIU W, WANG H L, et al. Ternary Hybrid Material for High-Performance Lithium-Sulfur Battery[J]. J. Am. Chem. Soc. 2015, 137: 12946-12953. [18] LIANG X, NAZAR F L. In Situ Reactive Assembly of Scalable Core-Shell Sulfur-MnO2 Composite Cathodes[J]. ACS Nano, 2016, 10: 4192-4198. [19] ZHENG J M, TIAN J, XIAO J, et al. Lewis Acid-Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries[J]. Nano Lett., 2014, 14: 2345-2352. [20] ZHANG B, QIN X, GAO X P, et al. Enhancement of Long Stability of Sulfur Cathode by Encapsulating Sulfur into Micropores of Carbon Spheres[J]. Energy Environ. Sci., 2010, 3: 1531-1537. [21] XU Y H, XU KANG, WANG C S, et al. Confined Sulfur in Microporous Carbon Renders Superior Cycling Stability in Li/S Batteries[J]. Adv. Funct. Mater., 2015, 25: 4312-4320. [22] FU C Y, WONG M B, GUO J C, et al. Solid State Lithiation-Delithiation of Sulphur in Subnano Confinement: A New Concept for Designing Lithium-Sulphur Batteries[J]. Chem. Sci., 2016, 7: 1224. [23] WANG D W, CHENG H M, GENTLE R I, et al. A Microporous-Mesoporous Carbon with Graphitic Structure for A High-Rate Stable Sulfur Cathode in Carbonate Solvent-Based Li-S Batteries[J]. Phys. Chem. Chem. Phys., 2012, 14: 8703-8710. [24] XIN S, GUO Y G, WAN L J, et al. Smaller Sulfur Molecules Promise Better Lithium-Sulfur Batteries[J]. J. Am. Chem. Soc., 2012, 134(45): 18510-18513. [25] HU L, ZHU Y C, QIAN Y T, et al. Optimization of Microporous Carbon Structures for Lithium-Sulfur Battery Applications in Carbonate-Based Electrolyte[J]. Small, 2017: 1603533. [26] LI Z, YUAN L X, HUANG Y H, et al. Insight inti the Electrode Mechanism in Lithium-Sulfur Batteries with Ordered Microporous Carbon Condined Sulfur as the Cathode. Adv. Energy Mater., 2014, 4: 1301473 [27] YE H, YIN Y X, GUO Y G, et al. Tuning the Porous Structure of Carbon Hosts for Loading Sulfur Toward Long Lifespan Cathode Materials for Li#8211;S Batteries[J]. J. Mater. Chem. A, 2013, 1: 6602-6608. [28] WU H B, XU R, LOU X W, et al. Embedding Sulfur in MOF-Derived Microporous Carbon Polyhedrons for Lithium-Sulfur Batteries[J]. Chem. Eur. J., 2013, 19: 10804-10808. [29] ZHANG S S. Sulfurized Carbon; A Class of Cathode Materials for High Performance Lithium/Sulfur Batteries[J]. Front. Energy Res., 2013,1: 1-9. [30] ZHENG S Y, YANG J H, WANG C S, et al. In Situ Sulfur Reduction and Intercalation of Graphite Oxides for Li-S Battery Cathodes[J]. Adv. Energy Mater., 2014, 4: 1400482. [31] MEYER B. Elemental Sulfur[J]. Chemical Reviews, 1976, 76(3): 367-388. [32] STEUDEL R. Liquid Sulfur[J]. Top Curr. Chem., 2003, 230: 81-116. [33] RAU H, KUTTY T R N, GUEDES DE CARVALHO J R F. Thermodynamics of Sulphur vapour[J]. J. Chem. Thermodynamics 1973, 5, 833-844. [34] ECKERT B, STEUDEL R. Molecular Spectra of Sulfur Molecules and Solid Sulfur Allotropes[J]. Top Curr. Chem., 2003, 231: 31-98. [35] BARLETTA E R, CLAASSEN H H, MCBETH L ROBERT. Raman Spectrum of S2[J]. The Journal of Chemical Physics, 1971, 55(11): 5409. [36] MEYER B. Solid Allotropes of Sulfur[J]. Chem. Rev., 1964, 64(4): 429-451.

3. 毕业设计(论文)进程安排

2017.01.11~2017.02.20 文献调研,开题报告 2017.02.20~2017.05.10 开展实验工作 2017.05.10~2017.05.28 中后期实验阶段及数据收集 2017.05.28~2017.06.10 数据整理,撰写论文

剩余内容已隐藏,您需要先支付 10元 才能查看该篇文章全部内容!立即支付

企业微信

Copyright © 2010-2022 毕业论文网 站点地图