磁响应纳米吸附剂的制备及其应用任务书
2020-06-10 22:03:01
1. 毕业设计(论文)的内容和要求
1. 查阅相关文献了解目前在磁响应纳米材料的研究现状,了解课题相关背景,已有成果以及存在的问题,对论文的研究方向有较深入的认识。
2. 增强分析问题解决问题的能力,培养独立思考及动手做实验的能力。
3. 了解实验仪器的具体使用方法和常规的表征方法。
2. 参考文献
1. Van de Voorde, B., et al., N/S-Heterocyclic Contaminant Removal from Fuels by the Mesoporous Metal#8211;Organic Framework Mil-100: The Role of the Metal Ion. J. Am. Chem. Soc. 2013, 135, 9849-9856. 2. Maes, M., et al., Selective Removal of N-Heterocyclic Aromatic Contaminants from Fuels by Lewis Acidic Metal#8211;Organic Frameworks. Angew. Chem. Int. Ed. 2011, 50, 4210-4214. 3. Lu, H.-Y.; Li, P.-C.; Deng, C.-L.; Ren, W.-Z.; Wang, S.-N.; Liu, P.; Zhang, H., Deep Catalytic Oxidative Desulfurization (Ods) of Dibenzothiophene (Dbt) with Oxalate-Based Deep Eutectic Solvents (Dess). Chem. Commun. 2015, 51, 10703-10706. 4. Ai, S.; Sui, H.; Li, H., Coordinative Adsorption of Thiophene with Metallic Silver/Adsorbent Cotton Prepared Via Aqueous in Situ Reduction for Desulfurization. Ind. Eng. Chem. Res. 2012, 51, 12337-12343. 5. Kogan, V. M.; Gaziev, R. G.; Lee, S. W.; Rozhdestvenskaya, N. N., Radioisotopic Study of (Co)Mo/Al2o3 Sulfide Catalysts for Hds Part Iii. Poisoning by N-Containing Compounds. Appl. Catal., A 2003, 251, 187-198. 6. Tang, T.-D.; Zhang, L.; Fu, W.-Q.; Ma, Y.-L.; Xu, J.; Jiang, J.; Fang, G.-Y.; Xiao, F.-S., Design and Synthesis of Metal Sulfide Catalysts Supported on Zeolite Nanofiber Bundles with Unprecedented Hydrodesulfurization Activities. J. Am. Chem. Soc. 2013, 135, 11437-11440. 7. Wang, S.-M., et al., A New Molybdenum Nitride Catalyst with Rhombohedral Mos2 Structure for Hydrogenation Applications. J. Am. Chem. Soc. 2015, 137, 4815-4822. 8. Savithra, G. H. L.; Muthuswamy, E.; Bowker, R. H.; Carrillo, B. A.; Bussell, M. E.; Brock, S. L., Rational Design of Nickel Phosphide Hydrodesulfurization Catalysts: Controlling Particle Size and Preventing Sintering. Chem. Mater. 2013, 25, 825-833. 9. Lewandowski, M., Hydrotreating Activity of Bulk Nib Alloy in Model Reaction of Hydrodenitrogenation of Carbazole. Appl. Catal., B 2015, 168, 322-332. 10. Li, N.; Zhu, J.; Ma, X.-L.; Zha, Q.-F.; Song, C.-S., Tailoring of Surface Oxygen-Containing Functional Groups and Their Effect on Adsorptive Denitrogenation of Liquid Hydrocarbons over Activated Carbon. AIChE J. 2013, 59, 1236-1244. 11. Nikulshin, P. A.; Minaev, P. P.; Mozhaev, A. V.; Maslakov, K. I.; Kulikova, M. S.; Pimerzin, A. A., Investigation of Co-Effect of 12-Tungstophosphoric Heteropolyacid, Nickel Citrate and Aarbon-Coated Alumina in Preparation of Niw Catalysts for Hds, Hyd and Hdn Reactions. Appl. Catal., B 2015, 176, 374-384. 12. Ju, S.-G.; Zhao, Y.-S.; Fan, H.-L.; Liang, L.-T.; Shen, F.; Miao, M.-Q., Desulfurization Behavior of Zinc Oxide Based Sorbent Modified by the Combination of Al2o3 and K2co3. Fuel 2013, 108, 80-84. 13. Wen, Y.-S.; Wang, G.; Wang, Q.; Xu, C.-M.; Gao, J.-S., Regeneration Characteristics and Kinetics of Ni/Zno-Sio2-Al2o3 Adsorbent for Reactive Adsorption Desulfurization. Ind. Eng. Chem. Res. 2012, 51, 3939-3950. 14. Ahmed, A.; Forster, M.; Clowes, R.; Bradshaw, D.; Myers, P.; Zhang, H. F., Silica Sos@Hkust-1 Composite Microspheres as Easily Packed Stationary Phases for Fast Separation. J. Mater. Chem. A 2013, 1, 3276-3286. 15. Tian, W.-H.; Sun, L.-B.; Song, X.-L.; Liu, X.-Q.; Yin, Y.; He, G.-S., Adsorptive Desulfurization by Copper Species within Confined Space. Langmuir 2010, 26, 17398-17404.
3. 毕业设计(论文)进程安排
2017.3.1-2017.3.10 查阅收集文献资料,了解课题背景,完成开题报告的撰写;为实验作准备工作。
2017.3.11-2017.3.31 合成磁性纳米吸附剂 2017.4.1-2017.4.15 对还原前后的样品进行相应的表征测试,并且撰写中期自查表 2017.4.16-2017.4.30 探索吸附剂的吸附性能,同时撰写毕业论文。