碳棒载镍前驱体制备镁镍氢化物及储氢性能研究任务书
2020-06-11 20:55:35
1. 毕业设计(论文)的内容和要求
镁基氢化物动力学性能差,吸放氢温度高,阻碍了其应用。有研究表明,纳米化和催化可以有效促进材料储氢性能。本课题在实验室已有基础上,采用碳棒载镍前驱体,通过氢化化学气相沉积法,制备纳米镁镍氢化物。本课题来源于科技创新,难度较大,工作量适中。
论文要求:翻译3000字左右的英文文献一篇,广泛查阅国内外相关文献,撰写文献综述和开题报告。在实验的基础上,整理和分析数据,完成纳米镁镍氢化物的制备,研究其储氢性能,撰写论文。
2. 参考文献
[1] Jena P. Materials for Hydrogen Storage: Past, Present, and Future[J]. Journal of Physical Chemistry Letters, 2011;2:206-211. [2] 马驰, 胡应得. 能源替代性经济分析[J]. 商业研究, 2004:42-44. [3] 张聪. 世界氢能技术研究和应用新进展[J]. 石油石化节能, 2014:56-59. [4] 胡子龙. 贮氢材料[M]. 化学工业出版社, 2002. [5] Galindo-Hernandez F, Portales B, Dominguez J M, et al. Porosity and fractal study of functionalized carbon nanofibers: Effects of the functionalization degree on hydrogen storage capacity[J]. Journal of Power Sources, 2014;269:69-80. [6] Carraro P, Elias V, Garcia Blanco A, et al. Synthesis and multi-technique characterization of nickel loaded MCM-41 as potential hydrogen-storage materials[J]. Microporous and Mesoporous Materials, 2014;191:103-11. [7] Gosalawit-Utke R, Milanese C, Javadian P, et al. 2LiBH(4)-MgH2-0.13TiCl(4) confined in nanoporous structure of carbon aerogel scaffold for reversible hydrogen storage[J]. Journal of Alloys and Compounds, 2014;599:78-86. [8] Feng Y F, Jiang H, Chen M, et al. Construction of an interpenetrated MOF-5 with high mesoporosity for hydrogen storage at low pressure[J]. Powder Technology, 2013;249:38-42. [9] Yuan J G, Zhu Y F, Li L Q. Highly efficient bimetal synergetic catalysis by a multi-wall carbon nanotube supported palladium and nickel catalyst for the hydrogen storage of magnesium hydride[J]. Chemical communications, 2014;50:6641-6644. [10] Yang J, Hirano S. Improving the Hydrogen Reaction Kinetics of Complex Hydrides[J]. Advanced materials, 2009;21:3023-3028. [11] Xiong Z T, Yong C K, Wu G T, et al. High-capacity hydrogen storage in lithium and sodium amidoboranes[J]. Nature materials, 2008;7:138-141. [12] 唐有根, 万伟华, 李民善. 储氢材料的研究进展 [J]. 功能材料信息, 2006;3:15-20. [13] Li L L, Peng B, Ji W Q, et al. Studies on the Hydrogen Storage of Magnesium Nanowires by Density Functional Theory[J]. Journal of Physical Chemistry C, 2009;113:3007-3013. [14] Huot J, Liang G, Boily S, et al. Structural study and hydrogen sorption kinetics of ball-milled magnesium hydride[J]. Journal of Alloys and Compounds, 1999;293:495-500. [15] Choi Y J, Lu J, Sohn H Y, et al. Hydrogen storage properties of the Mg-Ti-H system prepared by high-energy-high-pressure reactive milling[J]. Journal of Power Sources, 2008;180:491-497. [16] Paskevicius M, Sheppard D A, Buckley C E. Thermodynamic Changes in Mechanochemically Synthesized Magnesium Hydride Nanoparticles[J]. Journal of the American Chemical Society, 2010;132:5077-5083. [17] Aguey-Zinsou, Kondo-Francois, Ares-Fernandez, et al. Synthesis of colloidal magnesium: A near room temperature store for hydrogen[J]. Chemistry of Materials, 2008;20:376-378. [18] Ouyang L Z, Ye S Y , Dong H W, et al. Effect of interfacial free energy on hydriding reaction of Mg-Ni thin films[J]. Applied Physics Letters, 2007;90. [19] Zahiri R, Zahiri B, Kubis A, et al. Microstructural evolution during low temperature sorption cycling of Mg-AlTi multilayer nanocomposites[J]. International Journal of Hydrogen Energy, 2012;37:4215-4226. [20] Shao H Y, Liu T, Wang Y T, et al. Preparation of Mg-based hydrogen storage materials from metal nanoparticles[J]. Journal of Alloys and Compounds, 2008;465:527-533. [21] Zhu Y F, Liu Z B, Yang Y, et al. Hydrogen storage properties of Mg-Ni-C system hydrogen storage materials prepared by hydriding combustion synthesis and mechanical milling[J]. International Journal of Hydrogen Energy, 2010;35:6350-6355. [22] Gross A F, Ahn C C, Van Atta S L, et al. Fabrication and hydrogen sorption behaviour of nanoparticulate MgH2 incorporated in a porous carbon host[J]. Nanotechnology, 2009;20. [23] Nielsen T K, Manickam K, Hirscher M, et al. Confinement of MgH2 Nanoclusters within Nanoporous Aerogel Scaffold Materials[J]. Acs Nano, 2009;3:3521-3528. [24] Liu Y N, Zou J X, Zeng X Q, et al. Study on hydrogen storage properties of Mg nanoparticles confined in carbon aerogels[J]. International Journal of Hydrogen Energy, 2013;38:5302-5308. [25] Zhao-Karger Z, Hu J J, Roth A, et al. Altered thermodynamic and kinetic properties of MgH2 infiltrated in microporous scaffold[J]. Chemical communications, 2010;46:8353-8355.
3. 毕业设计(论文)进程安排
起始日期 |
设计(论文)各阶段工作内容 |
备 注 |
2016.12.12~ 2016.12.31 |
中国期刊网、维普数据库以及Elsevier数据库等数据库查阅国内外相关文献 |
|
2017.1.01 ~ 2017.1.14 |
撰写开题报告及外文文献翻译,开题报告答辩 |
|
2017.2.20 ~ 2017.3.19 |
确定纳米镁镍氢化物的制备工艺参数 |
|
2017.3.20 ~ 2017.4.20 |
中期检查与答辩 |
|
2017.4.21~ 2017.5.7 |
纳米镁镍氢化物的储氢性能测试 |
五一放假 |
2017.5.8~ 2017.5.31 |
撰写毕业论文 |
|
2017.6.01~ 2017.6.14 |
完成毕业论文及答辩 |
|
2017.6.15~ 2017.7.8 |
总结、归档 |