1. 毕业设计（论文）的内容和要求

1、论文主要内容： (1) 综述地沟油制氢的背景意义及国内外研究现状。

(2) 地沟油中各组分的分离、提纯；地沟油酯化反应；ni/al2o3重整制氢催化剂的制备，以及表征分析催化剂的微观结构和性质；以地沟油、地沟油酯化产物为原料进行部分氧化蒸汽重整反应研究，研究不同负载、焙烧温度、制备方法等条件下制备的ni/al2o3的制氢性能；深入研究催化剂的酸碱中心、材料结构、表面电子效应等的协同催化作用机理。

(3) 总结实验工作，撰写毕业论文。

2. 参考文献

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Assaf, 'Hydrogen Production by Steam Reforming of Ethanol over Co3o4/La2o3/Ceo2 Catalysts Synthesized by One-Step Polymerization Method', Applied Catalysis A: General, 483 (2014), 52-62. 3 Hongqing Chen, Hao Yu, Feng Peng, Hongjuan Wang, Jian Yang, and Minqiang Pan, 'Efficient and Stable Oxidative Steam Reforming of Ethanol for Hydrogen Production: Effect of in Situ Dispersion of Ir over Ir/La2o3', Journal of Catalysis, 269 (2010), 281-90. 4 Hongqing Chen, Hao Yu, Feng Peng, Guangxing Yang, Hongjuan Wang, Jian Yang, and Yong Tang, 'Autothermal Reforming of Ethanol for Hydrogen Production over Perovskite Lanio3', Chemical Engineering Journal, 160 (2010), 333-39. 5 K. de Boer, and P. A. Bahri, 'Supercritical Methanol for Fatty Acid Methyl Ester Production: A Review', Biomass Bioenergy, 35 (2011), 983-91. 6 S. M. de Lima, A. M. da Silva, L. O. O. da Costa, U. M. Graham, G. Jacobs, B. H. Davis, L. V. Mattos, and F. B. Noronha, 'Study of Catalyst Deactivation and Reaction Mechanism of Steam Reforming, Partial Oxidation, and Oxidative Steam Reforming of Ethanol over Co/Ceo2 Catalyst', Journal of Catalysis, 268 (2009), 268-81. 7 Sania M. de Lima, Ivna O. da Cruz, Gary Jacobs, Burtron H. Davis, Lisiane V. Mattos, and F醔io B. Noronha, 'Steam Reforming, Partial Oxidation, and Oxidative Steam Reforming of Ethanol over Pt/Cezro2 Catalyst', Journal of Catalysis, 257 (2008), 356-68. 8 F. Djani, M. Omari, and A. Mart韓ez-Arias, 'Synthesis, Characterization and Catalytic Properties of La(Ni,Fe)O3朜io Nanocomposites', Journal of Sol-Gel Science and Technology, 78 (2016), 1-10. 9 Athanasios N. Fatsikostas, and Xenophon E. Verykios, 'Reaction Network of Steam Reforming of Ethanol over Ni-Based Catalysts', Journal of Catalysis, 225 (2004), 439-52. 10 F. Frusteri, S. Freni, L. Spadaro, V. Chiodo, G. Bonura, S. Donato, and S. 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Munoz, S. Moreno, and R. Molina, 'The Effect of the Absence of Ni, Co, and Ni-Co Catalyst Pretreatment on Catalytic Activity for Hydrogen Production Via Oxidative Steam Reforming of Ethanol', International Journal of Hydrogen Energy, 39 (2014), 10074-89. 21 T. I. T. Okpalugo, P. Papakonstantinou, H. Murphy, J. McLaughlin, and N. M. D. Brown, 'High Resolution Xps Characterization of Chemical Functionalised Mwcnts and Swcnts', Carbon, 43 (2005), 153-61. 22 M. A. Olutoye, and B. H. Hameed, 'A Highly Active Clay-Based Catalyst for the Synthesis of Fatty Acid Methyl Ester from Waste Cooking Palm Oil', Applied Catalysis a-General, 450 (2013), 57-62. 23 V. Palma, F. Castaldo, P. Ciambelli, and G. Iaquaniello, 'Ceo2-Supported Pt/Ni Catalyst for the Renewable and Clean H-2 Production Via Ethanol Steam Reforming', Applied Catalysis B-Environmental, 145 (2014), 73-84. 24 John A. Posada, Akshay D. Patel, Alexander Roes, Komelis Blok, Andre P. C. Faaij, and Martin K. 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3. 毕业设计（论文）进程安排

2016.12.12-2016.12.25： 了解课题背景，查阅文献，熟悉课题及实验设备； 2016.12.26 ~ 2017.1.15：完成外文文献翻译，撰写开题报告，确定实验方案； 2017.3.14 ~ 2017.4.5： 地沟油预处理，优化制备Ni/Al2O3催化剂，测试制氢性能； 2017.4.6 ~ 2017.4.19： 中期检查与答辩； 2017.4. 20~ 2017.5.10： 考察影响因素，对催化剂进行表征分析； 2017.5.11 ~ 2017.5.15： 阅读相关文献，结合实验分析手段，探讨催化机理； 2017.5.16~ 2017.5.29： 撰写毕业论文； 2017.5.30~ 2017.6.5： 完成毕业论文及答辩； 2017.6.6~ 2017.6.14： 总结、归档。