1. 毕业设计（论文）的内容和要求

镁基储氢合金由于其理论储氢量高（mgh2为 7.6 wt.%）、资源丰富、价格低廉等优势被认为是最具潜力的储氢材料之一。

但是其动力学和热力学性能较差，制约其实际应用。

本课题组通过hcs-mm法制备的镁基储氢合金具有高容量和高活性，但完全放氢仍需523 k以上，373 k吸氢只维持几个循环。

2. 参考文献

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Structures and hydrogen storage properties of Mg95Ni5 composite prepared by hydriding combustion synthesis and mechanical milling [J]. Mater. Chem. Phys., 2008, 112: 218-222. [6] Li L L, Peng B, Ji W Q, Chen J. A quantum chemical study on magnesium (Mg)/magnesium #8211;hydrogen (Mg-H) nanowires [J]. Journal of Alloys and compounds, 2009, 484(1/2): 308-313. [7] 邹勇进, 向翠丽, 邱树君, 等. 纳米限域的储氢材料[J]. 化学进展, 2013,(01):115-121. [8] Weiyu Xie, Damien J. West, Yiyang Sun, et al. Role of nano in catalysis: Palladium catalyzed hydrogen desorption from nanosized magnesium hydride [J]. Nano Energy , 2013, 2, 742#8211;748 [9] Floriano R., Leiva D. R., Deledda S., et al. MgH2-based nanocomposites prepared by short-time high energy ball milling followed by cold rolling: A new processing route [J]. J. Hydrogen energy, 2014, 39, 4404-4413. [10] Tayeh Toufic, Awad Abdel Salam, Nakhl Michel, et al. Carbon-modified MgH2: Experimental and ab-initio Investigations [J]. Zeitschrift fur naturforschung section b-a journal of chemical sciences, 2014, 69, 804-810. [11] Nielsen T K, Manickam K, Hirscher M, et al. Confinement of MgH2 Nanoclusters within Nanoporous Aerogel Scaffold Materials[J]. ACS NANO, 2009, 3(11): 3521-3528. [12] 李志宝,孙立贤, 徐芬, 等. MgH2/PMMA 复合储氢材料的制备及其脱氢研究[J]. 电源技术, 2015,(08): 1668-1670. [13] Bin-Hao Chen, Chia-Hung Kuo, Jie-Ren Ku, et al. Highly improved with hydrogen storage capacity and fast kinetics in Mg-based nanocomposites by CNTs [J]. Journal of Alloys and Compounds, 2013, 568, 78#8211;83. [14] Vajo JJ. Influence of nano-confinement on the thermodynamics and dehydrogenation kinetics of metal hydrides. Current Opinion in Solid State and Materials Science, 2011, 15:52-61. [15] Claudia Zlotea, Michel Latroche. Role of nanoconfinement on hydrogen sorption properties of metal nanoparticles hybrids [J]. Colloids and Surfaces A: Physicochem. Eng. Aspects, 2013, 439, 117#8211;130. [16]Hosseini S S, Teoh M M, Tai S C. Hydrogen separation and purification in membranes of miscible polymer blends with interpenetration networks [J]. Polymer, 2008, 49: 1594-1603. [17]Hosseini Seyed Saeid, Chung Tai Shung. Carbon membranes from blends of PBI and polyimides for N2/CH4 and CO2/CH4 separation and hydrogen purification [J]. Journal of Membrane Science, 2017, 328(1-2): 174-185. [18] Fang Q, Zhuang Z, Gu S, et al. Designed synthesis of large-pore crystalline polyimide covalent organic frameworks [J]. Nature Communications, 2014, 5: 4503. [19] Lim, D.W, Yoon, J.W, et al. Magnesium Nanocrystals Embedded in a Metal#8211;Organic Framework: Hybrid Hydrogen Storage with Synergistic Effect on Physi- and Chemisorption [J]. Angewandte Chemie, 2012, 124(39): 9952-9955. [20] Marzia Pentimalli, Franco Padella, Aurelio La Barbera, et al. A metal hydride#8211;polymer composite for hydrogen storage applications [J]. Energy Conversion and Management, 2009, 50, 3140#8211;3146. [21] Y. Liu, Alexander Rzhevskii, S. Rigos a, et al. A study of Parylene coated Pd/Mg nanoblabes for reversible hydrogen storage [J]. J. Hydrogen energy, 2013, 38, 5019-5029. [22] Jeon, K. J, H. R. Moon, et al. Air-stable magnesium nanocomposites provide rapid and high-capacity hydrogen storage without using heavy-metal catalysts [J]. Nature Materials, 2011, 10(4): 286-290. [23] Jianmei Huang, Yurong Yan, Liuzhang Ouyang, et al. Increased air stability and decreased dehydrogenation temperature of LiBH4 via modification within poly(methylmethacrylate) [J]. Dalton Transactions Communication, 2014, 43, 410-413. [24] Rapee Gosal awit-Utke, Sukanya Meethom, Claudio Pistidda, et al. Destabilization of LiBH4 by nanoconfinement in PMMA-co-BM polymer matrix for reversible hydrogen storage [J]. J. Hydrogen energy, 2014, 39, 5019-5029. [25] Anne M . Rum inski, Rizia Bardhan, et al. Synergistic enhancement of hydrogen storage and air stability via Mg nanocrystal#8211;polymer interfacial interactions [J]. 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3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 备 注 2017.12.22~ 2017.12.31 中国期刊网、维普数据库以及Elsevier数据库等数据库查阅国内外相关文献 2017.1.04 ~ 2017.1.12 完成外文文献翻译，撰写开题报告，开题报告答辩 2017.3.12~2017.4.5 喷雾干燥工艺过程中不同聚合物添加量对材料颗粒微观结构及分散性的影响 2017.4.06~ 2017.4.19 中期检查与答辩 2017.4.20~ 2017.5.10 喷雾干燥工艺过程中不同喷雾压力对材料颗粒微观结构及分散性的影响 2017.5.11~ 2017.5.15 喷雾干燥工艺过程中不同干燥温度对材料颗粒微观结构及分散性的影响 2017.5.16~ 2017.5.29 实验数据的整理归纳，撰写毕业论文 2017.5.30~ 2017.6.5 完成毕业论文及答辩 2017.6.6~ 2017.6.14 总结、归档