1. 毕业设计（论文）的内容和要求

质子交换膜燃料电池（pemfc）是一种清洁、高效的直接将化学能转化为电能的电源装置。

它是目前用于电动汽车和便携式电源的理想电源。

然而，电极催化剂的高成本和短寿命阻碍了pemfc的工业化。

2. 参考文献

[1] Daud, W. R. W. , et al. "PEM fuel cell system control: A review." Renewable Energy (2017). [2] Sun, Ruili , et al. "Hierarchically ordered arrays with platinum coated PANI nanowires for highly efficient fuel cell electrodes." Journal of Materials Chemistry A 5.29(2017). [3] "Electrodeposited conductive polypyrrole/polyaniline composite film for the corrosion protection of copper bipolar plates in proton exchange membrane fuel cells." Journal of Power Sources 302(2016). [4] Wang, Qin , et al. "Hierarchical carbon and nitrogen adsorbed PtNiCo nanocomposites with multiple active sites for oxygen reduction and methanol oxidation reactions." J. Mater. Chem. A 4.31(2016). [5] Bordet, Pierre , et al. "Beyond Strain and Ligand Effects: Microstrain-Induced Enhancement of the Oxygen Reduction Reaction Kinetics on Various PtNi/C Nanostructures." Acs Catalysis 7.1(2016). [6] Xu, Ran , et al. "Improving sulfur tolerance of noble metal catalysts by tungsten oxide-induced effects." RSC Advances 3(2012). [7] Han, Jie, et al. "Conducting polymer-noble metal nanoparticle hybrids: Synthesis mechanism application." Progress in Polymer Science (2017). [8] Li, Bingzhen, et al. "Synthesis of Fe3O4 /polypyrrole/polyaniline nanocomposites by in-situ method and their electromagnetic absorbing properties." Journal of Saudi Chemical Society 21.4(2016). [9] Lemos, Hugo G., S. F. Santos, and E. C. Venancio. "Polyaniline-Pt and polypyrrole-Pt nanocomposites: Effect of supporting type and morphology on the nanoparticles size and distribution." Synthetic Metals 203(2015):22-30. [10] Bhattacharjya D, Mukhopadhyay I. Controlled growth of polyaniline fractals on HOPG through potentiodynamic electropolymerization[J]. Langmuir, 2012, 28: 5893-5899 [11] Qiufeng L. Unstirred preparation of soluble electroconductive polypyrrole nanoparticles[J]. Microchim Acta, 2010( 168) : 205-213． [12] Watanabe M, Tryk D A, Wakisaka M, et al. Overview of recent developments in oxygen reduction electrocatalysis[J]. Electrochimica Acta, 2012, 84: 187-201. [13] Li B H, Chan S H. PtFeNi tri-metallic alloy nanoparticles as electrocatalyst for oxygen reduction reaction in proton exchange membrane fuel cells with ultra-low Pt loading[J]. International Journal of Hydrogen Energy, 2013, 38(8): 3338-3345. [14] Nores-Pondal, F. J. , et al. "Catalytic activity vs. size correlation in platinum catalysts of PEM fuel cells prepared on carbon black by different methods." International Journal of Hydrogen Energy 34.19(2009). [15] "Electrodeposited conductive polypyrrole/polyaniline composite film for the corrosion protection of copper bipolar plates in proton exchange membrane fuel cells." Journal of Power Sources 302(2016). [16] Authayanun S, Im-Orb K, Arpornwichanop A. A review of the development of high temperature proton exchange membrane fuel cells[J]. Chinese Journal of Catalysis, 2015, 36(4): 473-483. [17] Cheng W, Shubo W, Jianbo Z, et al. The Durability Research on the Proton Exchange Membrane Fuel Cell for Automobile Application[J]. PROGRESS IN CHEMISTRY, 2015, 27(4): 424-435. [18] Shih N C, Weng B J, Lee J Y, et al. Development of a 20 kW generic hybrid fuel cell power system for small ships and underwater vehicles[J]. International Journal of Hydrogen Energy, 2014, 39(6):1-8. [19] Cheng W, Shubo W, Jianbo Z, et al. The Key Materials and Components for Proton Exchange Membrane Fuel Cell[J]. PROGRESS IN CHEMISTRY, 2015, 27(2-3): 310-320. [20] Malek K, FrancoA A. Microstructure-Based Modeling of Aging Mechanisms in Catalyst Layers of Polymer Electrolyte Fuel Cells[J]. The Journal of Physical Chemistry B, 2011, 115(13): 8088-8101. [21] Nepel T C M, Lopes P P, Paganin V A, et al. CO tolerance of proton exchange membrane fuel cells with Pt/C and PtMo/C anodes operating at high temperatures: A mass spectrometry investigation[J]. Electrochimica Acta, 2013, 8(1): 217-224. [22] Li, Peipeng , et al. "Electrochemical synthesis and characterization of polyaniline-coated PEMFC metal bipolar plates with improved corrosion resistance." Ionics (2017). 学生在此基础上自行查阅相关文献至少10篇。

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 备 注 2018.12.18-2019.1.5 了解课题背景，查阅相关文献 2019.1.6-2019.1.10 文献综述，翻译英文文献 2019.1.11-2019.1.15 完成开题，确定实验方案 2019.2.23-2019.3.1 实验准备 2019.3.2-2019.3.20 聚苯胺膜以及Pt催化剂的制备 2019.3.21-2019.4.15 电化学性能测试、XRD、SEM等测试 2019.4.16-2019.5.6 数据分析、中期检查 2019.5.7-2019.5.15 SEM测试分析 2019.5.16-2019.6.7 撰写毕业论文、修改论文 2019.6.8-2019.6.17 论文答辩