构建多孔g-C3N4/ZnO异质结及其光催化性质研究任务书
2020-05-01 08:47:31
1. 毕业设计(论文)的内容和要求
1.毕业论文主要内容 近年来,世界经济的快速发展,现代工业化的迅猛发展,人们对能源的需求日益增大。
为了满足日益增长的能源需求,消耗了大量的煤、石油、天然气等不可再生的化石能源,造成严重的能源危机和环境污染问题。
因此,寻找清洁可再生的清洁能源成为全世界关注的课题。
2. 参考文献
(1) Zou, Z. G.; Ye, J. H.; Sayama, K.; Arakawa, H. Direct Splitting of Water under Visible Light Irradiation with An Oxide Semiconductor Photocatalyst. Nature 2001, 414, 625-627. (2) Zheng, Y.; Liu, J.; Liang, J.; Jaroniec, M.; Qiao, S. Z. Graphitic Carbon Nitride Materials: Controllable Synthesis and Applications in Fuel Cells and Photocatalysis. Energy Environ. Sci. 2012, 5, 6717-6731. (3) Xiang, Q. J.; Yu, J. G.; Jaroniec, M. Synergetic Effect of MoS2 and Graphene as Cocatalysts for Enhanced Photocatalytic H2 Production Activity of TiO2 Nanoparticles. J. Am. Chem. Soc. 2012, 134, 6575-6578. (4) Malato, S.; Blanco, J.; Vidal, A.; Richter, C. Photocatalysis with Solar Energy at A Pilot-plant Scale: An Overview. Appl. Catal. B. 2002, 37, 1-15. (5) Chen, X.; Liu, L.; Yu, P. Y.; Mao, S. S. Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals. Science 2011, 331, 746-750. (6) Liu,G.; Yin,L.-C.; Wang, J.; Niu, P.; Zhen, C.; Xie, Y.; Cheng, H. M. A Red Anatase TiO2 Photocatalyst for Solar Energy Conversion. Energy Environ. Sci. 2012, 5, 9603-9610. (7) Wang, X. C.; Maeda, K.; Thomas, A.; Takanabe, K.; Xin, G.; Carlsson, J. M.; Domen, K.; Antonietti, M. A Metal-Free Polymeric Photocatalyst for Hydrogen Production from Water under Visible Light. Nat. Mater. 2009, 8, 76-80. (8) Yan, S. C.; Li, Z. S.; Zou, Z. G. Photodegradation Performance of g-C3N4 Fabricated by Directly Heating Melamine. Langmuir 2009, 25, 10397-10401. (9) Yang, S. B.; Gong, Y. J.; Zhang, J. S.; Zhan, L.; Ma, L. L.; Fang, Z. Y.; Vajtai, R.; Wang, X. C.; Ajayan, P. M. Exfoliated Graphitic Carbon Nitride Nanosheets as Efficient Catalysts for Hydrogen Evolution under Visible Light. Adv. Mater. 2013, 25, 2452-2456. (10) Wang, X. C.; Maeda, K.; Chen, X. F.; Takanabe, K.; Domen, K.; Hou, Y. D.; Fu, X. Z.; Antonietti, M. Polymer Semiconductors for Artificial Photosynthesis: Hydrogen Evolution by Mesoporous Graphitic Carbon Nitride with Visible Light. J. Am. Chem. Soc. 2009, 131, 1680-1681. (11) Liu, J.; Liu, Y.; Liu, N. Y.; Han, Y. Z.; Zhang, X.; Huang, H.; Lifshitz, Y.; Lee, S. T.; Zhong, J.; Kang, Z. H. Metal-Free Efficient Photocatalyst for Stable Visible Water Splitting via A Two-Electron Pathway. Science 2015, 347, 970-974. (12) Ong, W. J.; Tan, L. L.; Chai, S. P.; Yong, S. T. Graphene Oxide as A Structure-Directing Agent for The Two-Dimensional Interface Engineering of Sandwich-like Graphene/g-C3N4 Hybrid Nanostructures with Enhanced Visible-Light Photoreduction of CO2 to Methane. Chem. Commun. 2015, 51, 858-861. (13) Shi, H. F.; Chen, G. Q.; Zhang, C. L.; Zou, Z. G. Polymeric g-C3N4 Coupled with NaNbO3 Nanowires Toward Enhanced Photocatalytic Reduction of CO2 into Renewable Fuel. ACS Catal. 2014, 4, 3637-3643. (14) Dong, F.; Wu, L. W.; Sun, Y. J.; Fu, M.; Wu, Z. B.; Lee, S. C. Efficient Synthesis of Polymeric g-C3N4 Layered Materials as Novel Efficient Visible Light Driven Photocatalysts. J. Mater. Chem. 2011, 21, 15171-15174. (15) Xu, J.; Wang, Y. J.; Zhu, Y. F. Nanoporous Graphitic Carbon Nitride with Enhanced Photocatalytic Performance. Langmuir 2013, 29, 10566-10572. (16) Wang, X. C.; Blechert, S.; Antonietti, M. Polymeric Graphitic Carbon Nitride for Heterogeneous Photocatalysis. ACS Catal. 2012, 2, 1596-1606. (17) Yan, H. Soft-Templating Synthesis of Mesoporous Graphitic Carbon Nitride with Enhanced Photocatalytic H2 Evolution under Visible Light. Chem. Commun. 2012, 48, 3430-3432. (18) Ma, T. Y.; Tang, Y. H.; Dai, S.; Qiao, S. Z. Proton‐Functionalized Two‐Dimensional Graphitic Carbon Nitride Nanosheet: An Excellent Metal‐Label‐Free Biosensing Platform. Small 2014, 10, 2382-2389. (19) Wu, F.; Liu, Y. F.; Yu, G. X.; Shen, D. F.; Wang, Y. L.; Kan, E. Visible-Light-Absorption in Graphitic C3N4 Bilayer: Enhanced by Interlayer Coupling. J. Phys. Chem. Lett. 2012, 3, 3330-3334. (20) Liao, G. Z.; Chen, S.; Quan, X.; Yu, H. T.; Zhao, H. M. Graphene Oxide Modified g-C3N4 Hybrid with Enhanced Photocatalytic Capability under Visible Light Irradiation. J. Mater. Chem. 2012, 22, 2721-2726. (21) Xu, M.; Han, L.; Dong, S. J. Facile Fabrication of Highly Efficient g-C3N4/Ag2O Heterostructured Photocatalysts with Enhanced Visible-Light Photocatalytic Activity. ACS Appl. Mater. Interfaces. 2013, 5, 12533-12540.
3. 毕业设计(论文)进程安排
2018.12.23~2018.12.28 课题任务书 2018.12.28~2019.1.18 开题报告 2019.1.18~2019.2.21 文献综述、英文翻译与试验材料准备 2019.2.21~2019.4.9 设计实验方案、进行实验 2019.4.10~2019.5.2 实验 2019.5.3~2019.5.8 实验、中期答辩 2019.5.9~2019.5.30 实验、整理实验数据、毕业论文撰写 2019.5.31~2019.6.10 毕业论文撰写、答辩