1. 毕业设计（论文）的内容和要求

1.毕业论文主要内容 含巯基官能团（-sh）的一类非芳香化合物称为硫醇。

硫醇具有难闻气味，有毒；对人体和环境都会造成严重的危害。

而增塑剂中硫醇含量较高，如何有效的脱除硫醇成为研究的重点。

2. 参考文献

[1] Afshar A S, Hosseini H M, Mir A.et al. Study on Effective Parameters in Caustic Regeneration on LPG Sweetening[J]. Petroleum Science and Technology, 2014, 32(15): 1861-1867. [2] Chauhan Deepak, Kumar. Pawan, Joshi Chetan, et al. Photo-assisted oxidation of thiols to disulfides using cobalt "Nanorust'' under visible light[J]. New Journal of Chemistry, 2015, 39(8): 6193-6200. [3] Chauhan Deepak K, Kumar Pawan, Painuly Rahul, Kinetics and feasibility studies of thiol oxidation using magnetically separable Mg-Al layered double hydroxide supported cobalt phthalocyanine catalyst[J]. Fuel Processing Technology, 2017, 162: 135-146. [4] Chauhan Deepak K, Patnam Padma L, Ganguly Sudip K, et al. A two in one approach: renewable support and enhanced catalysis for sweetening using chicken feather bound cobalt(II) phthalocyanine under alkali free environment[J]. Rsc Advances, 2016, 6(57): 51983-51988. [5] Cui Na, Song Zhaoyang, Zhu Lijun, et al. SYNTHESIS OF DISCARBOXYL PHENOXY PHTHALOCYANINE COBALT AND APPLICATION IN OXIDATION DESULFURIZATION OF MERCAPTAN COMPOUNDS[J]. Petroleum Processing and Petrochemicals, 2016, 47(2): 60-64. [6] Das Gautam, Sain Bir, Kumar Sunil, et al, Synthesis, characterization and catalytic activity of cobalt phthalocyanine dichloride in sweetening of heavier petroleum fractions[J]. Catalysis Today, 2012, 198(1): 228-232. [7] Filippova Anna, Vashurin Artur, Znoyko Serafima, et al. Novel Co(II) phthalocyanines of extended periphery and their water-soluble derivatives. Synthesis, spectral properties and catalytic activity[J]. Journal of Molecular Structure, 2017, 1149: 17-26. [8] Jiang Ming, Bai Yangwei, Ning Ping, Adsorption removal of arsine by modified activated carbon[J]. Adsorption-Journal of the International Adsorption Society, 2015, 21(1): 135-141. [9] Kumar Pawan, Gill Kareena, Kumar Sunil, et al. Magnetic Fe3O4@MgAl-LDH composite grafted with cobalt phthalocyanine as an efficient heterogeneous catalyst for the oxidation of mercaptans[J]. Journal of Molecular Catalysis a-Chemical, 2015, 41: 48-54. [10] Li Zhan-Hong, Guedri Houssemeddine, Viguier Bruno, et al. Optimization of Hydrogen Peroxide Detection for a Methyl Mercaptan Biosensor[J]. Sensors, 2013, 13(4): 5028-5039. [11] Mirzaeian Masoumeh, Rashidi Ali Morad, Zare Masoud, et al. Mercaptan removal from natural gas using carbon nanotube supported cobalt phthalocyanine nanocatalyst[J]. Journal of Natural Gas Science and Engineering, 2014, 18: 439-445. [12] Motahari Kazem, Ahmadi Hojatollah, et al. Synthesis and characterization of graphene oxide supported cobalt (II) tetrasulfophthalocyanine as an efficient heterogeneous nanocatalyst for mercaptans oxidation from gasoline[J]. Journal of Porphyrins and Phthalocyanines. 2017, 21(7): 510-522. [13] Motahari Kazem, Salabat Alireza, Ahmadi Hojatollah, et al, Co (II) phthalocyanine - amine functionalized graphene oxide as a solid base catalyst for the oxidation of thiols[J] Fullerenes Nanotubes and Carbon Nanostructures, 2018, 26(6): 342-350. [14] Reid Nellone, Barat Robert, et al. Impact of Fluorinated Cobalt(II) Phthalocyanine Catalysts on Aerobic Thiol Oxidation Kinetics[J]. Chemical Engineering Communications, 2016, 203(6): 714-723. [15] Singh Garima, Khatri Praveen K, Ganguly Sudip K, et al. Magnetic silica beads functionalized with cobalt phthalocyanine for the oxidation of mercaptans in an alkali free aqueous medium[J].Rsc Advances, 2014, 4(55): 29124-29130. [16] Sun Zhiyong, Jin Lan, Zhao Yufei. A Structured Catalyst toward Mercaptan Sweetening with Largely Enhanced Synergistic Effect[J]. Industrial Engineering Chemistry Research, 2014, 53(12): 4595-4603. [17] Vashurin Artur, Kuzmin Ilya, Razumov Mikhail, et al. Sulfonated Co(II) phthalocyanines covalently anchored at organic polymers as catalyst for mild oxidation of mercaptans[J]. Journal of Porphyrins and Phthalocyanines, 2015, 19(11): 1159-1167. [18] Vashurin Artur, Maizlish Vladimir, Kuzmin Ilya, et al. Aza-substitution, benzo-annulation effects and catalytic activity of beta-octaphenyl-substituted tetrapyrrolic macroheterocyclic cobalt complexes. I. heterogeneous catalysis[J]. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2017, 81(7): 37-43. [19] Vashurin Artur, Marfin Yury, Tarasyuk Ilya, et al. Sulfonated octa-substituted Co(II) phthalocyanines immobilized on silica matrix as catalyst for Thiuram E synthesis[J]. Applied Organometallic Chemistry, 2018, 32(9). [20] Vashurin A. S, Kuz'min I. A, Kuz'micheva L. A, et al. Surfactant-modified polypropylene as a catalyst for oxidation of mercaptans[J]. Russian Journal of General Chemistry, 2016, 86(9): 2203-2208. [21] Voronina A. A, Tarasyuk I. A, Marfin Yu S, et al. Silica nanoparticles doped by cobalt(II) sulfosubstituted phthalocyanines: Sol-gel synthesis and catalytic activity[J]. Journal of Non-Crystalline Solids, 2014, 406: 5-10. [22] Zhang Yufen, Liu Zhenyi, Ren Shenyong, et al. Study on the basic centers and active oxygen species of solid-base catalysts for oxidation of iso-mercaptans Wang[J]. Applied Catalysis a-General, 2014, 473: 125-131.

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 2018.12.23～2018.12.25 课题任务书 2018.12.25~2019.1.18 英文翻译、开题报告 2019.1.18~2019.2.21 文献综述、试验材料准备 2019.2.21~2019.3.9 设计实验方案、进行实验 2019.3.10~2019.5.2 实验 2019.5.3~2019.5.8 实验、中期答辩 2019.5.9~2019.5.30 实验、整理实验数据、毕业论文撰写 2019.5.31~2019.6.10 毕业论文撰写、答辩