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毕业论文网 > 任务书 > 材料类 > 材料科学与工程 > 正文

氢键增强有机长余辉发光材料的合成与性能研究任务书

 2020-05-01 08:49:14  

1. 毕业设计(论文)的内容和要求

毕业设计的内容和要求: 有机长余辉发光材料由于其超长的发光寿命、大的斯托克斯位移、丰富的激发态性质等特点,使其在数据加密、传感、光电显示等应用领域引起了人们的广泛关注。

近年来,通过研究者们的不断努力,开发出了一些实现有机长余辉的策略。

包括晶体诱导,h-聚集,金属有机框架、碳量子点、引入杂原子等策略。

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2. 参考文献

[1] Z. An, C. Zheng, Y. Tao, R. Chen, H. Shi, T. Chen, Z. Wang, H. Li, R. Deng, X. Liu, W. Huang. Stabilizing triplet excited states for ultralong organic phosphorescence[J]. Nat. Mater., 2015, 14(7): 685-690. [2] S. Cai, H. Shi, Z Zhang, X Wang, H Ma.Z. An, W. Huang. Hydrogen-Bonded Organic Aromatic Frameworks for Ultralong Phosphorescence by Intralayer π-π Interactions[J]. Angew. Chem., 2018, 57(15): 4005-4009. [3] Gu, L.; Shi, H.; Gu, M.; Ling, K.; Ma, H.; Cai, S.; Song, L.; Ma, C.; Li, H.; Xing, G.; Hang, X.; Li, J.; Gao, Y.; Yao, W.; Shuai, Z.; An, Z.; Liu, X.; Huang, W. Dynamic ultralong organic phosphorescence by photoactivation[J]. Angew. Chem., 2017, 57(28): 8425-8431. [4] Gu, L.; Shi, H.; Miao, C.; Wu, Q.; Cheng, Z.; Cai, S.; Gu, M.; Ma, C.; Yao, W.; Gao, Y.; An, Z.; Huang, W. Prolonging the lifetime of ultralong organic phosphorescence through dihydrogen bonding[J]. Mater. Chem., 2018, 6(2): 226#8722;233. [5] S. Dalapati, E. Jin, M. Addicoat, T. Heine, D. Jiang. Highly Emissive Covalent Organic Frameworks[J]. J. Am. Chem. Soc., 2016, 138(18): 5797-5800. [6] R. Xue, H. Guo, T. Wang, L. Gong, Y. Wang, J. Ai, D. Huang, H. Chen, W. Yang. Fluorescence properties and analytical applications of covalent organic frameworks[J]. Analytical Methods., 2017, 9(25): 3737-3750. [7] T. Yu, D. Ou, Z. Yang, Q. Huang, Z. Mao, J. Chen, Y. Zhang, S. Liu, J. Xu, M. R. Bryce, Z. Chi. The HOF structures of nitrotetraphenylethene derivatives provide new insights into the nature of AIE and a way to design mechanoluminescent materials[J]. Chemical Science., 2017, 8(2): 1163-1168. [8] C. Sun, X. Ran, X. Wang, Z. Cheng, Q. Wu, S. Cai, L. Gu, N. Gan, H. Shi, Z. An, H. Shi, W. Huang. Twisted Molecular Structure on Tuning Ultralong Organic Phosphorescence[J]. J. Phys. Chem. Lett., 2018, 9(2): 335-339. [9] E. Lucenti, A. Forni, C. Botta, L. Carlucci, C. Giannini, D. Marinotto, A. Previtali, S. Righetto, E. Cariati. H-Aggregates Granting Crystallization-Induced Emissive Behavior and Ultralong Phosphorescence from a Pure Organic Molecule[J]. J. Phys. Chem. Lett., 2017, 8(8): 1894-1898. [10] Y. Shoji, Y. Ikabata, Q. Wang, D. Nemoto, A. Sakamoto, N. Tanaka, J. Seino, H. Nakai, T. Fukushima. Unveiling a New Aspect of Simple Arylboronic Esters: Long-Lived Room-Temperature Phosphorescence from Heavy-Atom-Free Molecules[J]. J. Am. Chem. Soc., 2017, 139(7): 2728-2733. [11] Z. Cheng, H. Shi, H. Ma, L. Bian, Q. Wu, L. Gu, S. Cai, X. Wang, W. W. Xiong, Z. An, W. Huang. Ultralong Phosphorescence from Organic Ionic Crystals under Ambient Conditions[J]. Angew. Chem. Int. Ed., 2018, 57(3): 678-682. [12] S. Hirata, K. Totani, J. Zhang, T. Yamashita, H. Kaji, S. R. Marder, T. Watanabe, C. Adachi. Efficient Persistent Room Temperature Phosphorescence in Organic Amorphous Materials under Ambient Conditions[J]. Adv. Funct. Mater., 2013, 23(27): 3386-3397. [13] F. Hu, C. Liu, M. Wu, J. Pang, F. Jiang, D. Yuan, M. Hong. An Ultrastable and Easily Regenerated Hydrogen‐Bonded Organic Molecular Framework with Permanent Porosity[J]. Angew. Chem. Int. Ed., 2017, 56(8): 2101-2104. [14] Hirata, S. Recent Advances in Materials with Room-Temperature Phosphorescence: Photophysics for Triplet Exciton Stabilization[J]. Adv. Opt. Mater., 2017, 5(17): 1700116#8722;1700165. [15] W. P. Lustig, S. Mukherjee, N. D. Rudd, A. V. Desai, J. Li, S. K. Ghosh. Metal-organic frameworks: functional luminescent and photonic materials for sensing applications[J]. Chem. Soc. Rev., 2017, 46(11): 3242-3285.

3. 毕业设计(论文)进程安排

毕业设计进度安排 19.01.11~19.02.20 文献调研 19.02.20~19.05.10 外文翻译,开题报告,开展实验工作 19.05.10~19.05.28 中后期实验阶段及数据收集 19.05.28~19.06.10 数据整理,撰写论文

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