1. 毕业设计（论文）的内容和要求

毕业论文内容： 课程论文是对大学四年级学习情况以及对所做的课题情况的真实反映，其内容应该包括一下方面： 1. 查阅相关文献资料，提出实验计划，明确实验内容。

2. 了解课题的研究目的，进行大量实验，掌握二步水热法法合成石墨烯基复合材料制备工艺，并分析讨论改变工艺制度对合成gnss/co3o4复合材料的形貌及尺寸的影响。

并在这些基础上要总结实验操作经验及注意事项，并按要求完成毕业论文的全部内容。

2. 参考文献

[1] Abdelraheem, W. H. M.; He, X. X.; Duan, X. D.; Dionysiou, D. D. Degradation and mineralization of organic UV absorber compound 2-phenylbenzimidazole- 5-sulfonic acid (PBSA) using UV-254 nm/H2O2. J. Hazard. Mater. 2015, 282, 233#8722;240. [2] Xiong, X.; Sun, B.; Zhang, J.; Gao, N.; Shen, J.; Li, J.; Guan, X. Activating persulfate by Fe0 coupling with weak magnetic field: Performance and mechanism. Water Res. 2014, 62, 53#8722;62. [3] Juretic, H.; Montalbo-Lomboy, M.; van Leeuwen, J.; Cooper, W. J.; Grewell, D. Hydroxyl radical formation in batch and continuous flow ultrasonic systems. Ultrason. Sonochem. 2015, 22, 600#8722;606. [4] Shi, P. H.; Su, R. J.; Zhu, S. B.; Zhu, M. C.; Li, D. X.; Xu, S. H. Supported cobalt oxide on graphene oxide: Highly efficient catalysts for the removal of Orange II from water. J. Hazard. Mater. 2012, 229#8722;230, 331#8722;339. [5] Zeng, T.; Zhang, X.; Wang, S.; Niu, H.; Cai, Y. Spatial Confinement of a Co3O4 catalyst in hollow metal#8722;organic frameworks as a nanoreactor for improved degradation of organic pollutants. Environ. Sci. Technol. 2015, 49, 2350#8722;2357. [6] Saputra, E.; Muhammad, S.; Sun, H.; Ang, H. M.; Tade#769;, M. O.; Wang, S. A comparative study of spinel structured Mn3O4, Co3O4 and Fe3O4 nanoparticles in catalytic oxidation of phenolic contaminants in aqueous solutions. J. Colloid Interface Sci. 2013, 407, 467#8722;473. [7] Duan, X.; Ao, Z.; Sun, H.; Indrawirawan, S.; Wang, Y.; Kang, J.; Liang, F.; Zhu, Z. H.; Wang, S. Nitrogen-doped graphene for generation and evolution of reactive radicals by metal-free catalysis. ACS Appl. Mater. Interfaces 2015, 7, 4169#8722;78. [8] Shi, P. H.; Su, R. J.; Wan, F. Z.; Zhu, M. C.; Li, D. X.; Xu, S. H. Co3O4 nanocrystals on graphene oxide as a synergistic catalyst for degradation of Orange II in water by advanced oxidation technology based on sulfate radicals. Appl. Catal., B 2012, 123#8722;124, 265#8722;272. [9] Liang, H.; Sun, H. Q.; Patel, A.; Shukla, P.; Zhu, Z. H.; Wang, S. B. Excellent performance of mesoporous Co3O4/MnO2 nanoparticles in heterogeneous activation of peroxymonosulfate for phenol degradation in aqueous solutions. Appl. Catal., B 2012, 127, 330#8722;335. [10] Li, S.; Zhao, C.; Shu, K.; Wang, C.; Guo, Z.; Wallace, G. G.; Liu, H. Mechanically strong high performance layered polypyrrole nano fibre/graphene film for flexible solid state supercapacitor. Carbon 2014, 79, 554#8722;562. [11] Dong, C.; Xiao, X.; Chen, G.; Guan, H.; Wang, Y. Hydrothermal synthesis of Co3O4 nanorods on nickel foil. Mater. Lett. 2014, 123, 187#8722;190. [12] Lv, Y.; Li, Y.; Shen, W. Synthesis of Co3O4 nanotubes and their catalytic applications in CO oxidation. Catal. Commun. 2013, 42, 116#8722;120. [13] Zhang, W.; Tay, H. L.; Lim, S. S.; Wang, Y.; Zhong, Z.; Xu, R. Supported cobalt oxide on MgO: Highly efficient catalysts for degradation of organic dyes in dilute solutions. Appl. Catal., B 2010, 95, 93#8722;99. [14] Natile, M. M.; Glisenti, A. New NiO/Co3O4 and Fe2O3/Co3O4 nanocomposite catalysts: Synthesis and characterization. Chem. Mater. 2003, 15, 2502#8722;2510. [15] Bai, B.; Li, J. Positive Effects of K Ions on Three-dimensional mesoporous Ag/Co3O4 catalyst for HCHO oxidation. ACS Catal. 2014, 4, 2753#8722;2762. [16] Wang, X.; Zhong, Y.; Zhai, T.; Guo, Y.; Chen, S.; Ma, Y.; Yao, J.; Bando, Y.; Golberg, D. Multishelled Co3O4-Fe3O4 hollow spheres with even magnetic phase distribution: Synthesis, magnetic properties and their application in water treatment. J. Mater. Chem. 2011, 21, 17680. [17] Abdelkader, A. M. Electrochemical synthesis of highly corrugated graphene sheets for high performance supercapacitors. J. Mater. Chem. A 2015, 3, 8519#8722;8525. [18] Zhang, S.; Zhu, L.; Song, H.; Chen, X.; Zhou, J. Enhanced electrochemical performance of MnO nanowire/graphene composite during cycling as the anode material for lithium-ion batteries. Nano Energy 2014, 10, 172#8722;180. [19] Gao, M. R.; Cao, X.; Gao, Q.; Xu, Y. F.; Zheng, Y. R.; Jiang, J.; Yu, S. H. Nitrogen-doped graphene supported CoSe2 nanobelt composite catalyst for efficient water oxidation. ACS Nano 2014, 8, 3970#8722;3978. [20] Duan, X.; Sun, H. Q.; Wang, Y.; Kang, J.; Wang, S. B. N-dopinginduced nonradical reaction on single-walled carbon nanotubes for catalytic phenol oxidation. ACS Catal. 2015, 5, 553#8722;559. [21] Xiang, Q.; Yu, J.; Jaroniec, M. Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles. J. Am. Chem. Soc. 2012, 134, 6575#8722;6578. [22] Zhou, G.; Wang, D. W.; Yin, L. C.; Li, N.; Li, F.; Cheng, H. M. Oxygen bridges between NiO nanosheets and graphene for improvement of lithium storage. ACS Nano 2012, 6, 3214#8722;3223. [23] Nguyen, V. H.; Shim, J. J. Ionic liquid-assisted synthesis and electrochemical properties of ultrathin Co3O4 nanotube-intercalated graphene composites. Mater. Lett. 2015, 157, 290#8722;294. [24] Qiu, D. F.; Bu, G.; Zhao, B.; Lin, Z. X.; Pu, L.; Pan, L. J.; Shi, Y. In situ growth of mesoporous Co3O4 nanoparticles on graphene as a high-performance anode material for lithium-ion batteries. Mater. Lett. 2014, 119, 12#8722;15. [25] Wang, Q.; Zhang, C. Y.; Xia, X. B.; Xing, L. L.; Xue, X. Y. Extremely high capacity and stability of Co3O4/graphene nanocomposites as the anode of lithium-ion battery. Mater. Lett. 2013, 112, 162#8722;164. [26] Zhang, Z.; Hao, J.; Yang, W.; Lu, B.; Ke, X.; Zhang, B.; Tang, J. Porous Co3O4 nanorods#8722;reduced graphene oxide with intrinsic peroxidase-like activity and catalysis in the degradation of methylene blue. ACS Appl. Mater. Interfaces 2013, 5, 3809#8722;3815.

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 备 注 2017.12~2018.1 阅读相关文献及资料，了解课题的基本知识及相关背景 2018.1~2018.2 对于已阅读的文献材料，进行总结，完成开题报告与文献翻译 2018.2~2018.4 进行相关实验内容，并对实验的结果进行分析讨论 2018.4~2018.5 分析整理实验数据，撰写毕业论文 2018.5~2018.6 修改毕业论文及进行毕业答辩