1. 毕业设计（论文）的内容和要求

毕业论文内容： 课程论文是对大学四年级学习情况以及对所做的课题情况的真实反映，其内容应该包括以下方面： 1. 查阅相关文献资料，提出实验计划，明确实验内容。

2. 了解课题的研究目的，进行大量实验，掌握金属有机框架材料的合成及硅纳米粒子的表面修饰，并在修饰后的硅纳米粒子上原位生长金属有机框架材料。

并进一步在这些基础上总结实验操作经验及注意事项，并按要求完成毕业论文的全部内容。

2. 参考文献

[1]. Fengwei Huo et Imparting functionality to a metal-organic framework material by controlled nanoparticle encapsulation[J] nature chem.2012 1272,310-316 [2]. Po-Chun Hsu Kai Liu Yi Cui et High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO2 Nanospheres in Poly(ethylene oxide)Nano Lett 2016 16 459#8722;465 [3]. Jong Won Chung , Zhenan Bao ,* and Yi Cui et A Stretchable Graphitic Carbon/Si Anode Enabled by Conformal Coating of a Self-Healing Elastic Polymer Adv Mater 2016 10 1-7 [4]. Zhenda Lu Nian Liu and Yi Cui1 et Growth of conformal graphene cages on micrometre-sized silicon particles as stable battery anodes nature energy 2016 29 1-8 [5].Jia Liu1 Yi Cui Zhenan Bao et Fast and reversible thermoresponsive polymer switching materials for safer batteries 2016 9 1-8 [6]. Aristidis P T. Athanasopoulos Vladimir Kitaev etFacile Preparation of Highly Monodisperse Small Silica Spheres(15 to 200 nm) Suitable for Colloidal Templating and Formation of Ordered Arrays Langmuir 2008, 24, 1714-1720 [7].Junwen Zhou Xingguo Li Bo Wang et In Situ Growth of MOFs on the Surface of Si Nanoparticles for Highly Efficient Lithium Storage: Si@MOF Nanocomposites as Anode Materials for Lithium-Ion Batteries ACS Appl. Mater. Interfaces 2015, 7, 2178#8722;2182 [8].Ying Chuan Tan Hua Chun Zeng et A General Synthetic Approach for Integrated Nanocatalysts of Metal-Silica@ZIFs Chem. Mater. 2016, 28, 326#8722;336 [9].Yang Liu ac Shuit-Tong Lee et Small-sized silicon nanoparticles: new nanolights and nanocatalysts Nanoscale 2011, 3, 777#8211;791 [10]. Kee Suk Nahm,#167; and Chong Rae Park et Preparation and Enhanced Hydrostability and Hydrogen Storage Capacity of CNT@MOF-5 Hybrid Composite Chem. Mater. 2009, 21, 1893#8211;1897 [11]. Hua-jun GUO, Jie-xi WANG et Synthesis of Ni0.8Co0.1Mn0.1(OH)2 precursor and electrochemical performance of LiNi0.8Co0.1Mn0.1O2 cathode material for lithium batteries Trans Nonferrous Met Soc China 25(2015) 2253-2259 [12]. Mihai Irimia-Vladu Green electronics: biodegradable and biocompatible materials and devices for sustainable futureChem. Soc. Rev., 2014, 43, 588 [13]. Hiesang Sohn , and Donghai Wang et Infl uence of Silicon Nanoscale Building Blocks Size and Carbon Coating on the Performance of Micro-Sized Si#8211;C Composite Li-Ion AnodesAdv. Energy Mater. 2013, 3, 1507#8211;1515 [14]. Hyun-Wook Lee Wenting Zhao Yi Cui et A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes 2014, 10, 1832-1838 [15]. Chongmin Wang Yi Cui et A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes Nano Lett. 2012, 12, 3315#8722;3321

3. 毕业设计（论文）进程安排

第1周 查阅中外文献，写出文献总结 第2-3周 翻译文献，确定实验方案，编写开题报告，并在老师指导下修改完善实验方案。

熟悉实验仪器及设备，准备实验原材料、化学药品，开展实验工作。

第4周 开题 第5-13周 实验研究 第14周 撰写论文 第15周 评阅论文