1. 毕业设计（论文）的内容和要求

论文主要内容有：对环氧树脂固化剂咪唑进行潜伏性改性；了解热固性树脂的固化原理，研究对比固化剂改性前后固化环氧树脂的特性；对改性咪唑/环氧固化体系建立合适的固化动力学模型，将模型应用于对固化过程的预测，并对预测结果进行验证，为实际生产提供指导性作用。

实验安排：第一周～第二周： 文献查阅，查阅有关环氧树脂潜伏型固化剂的相关文献，要求学习并掌握利用中国期刊网、维普、ei、ca、elsevier、欧洲 专利等查阅文献，不少于15篇。

第三周：英文文献的翻译：文献字数3000字以上 开题：完成开题报告。

2. 参考文献

[1] L. Guadagno, M. Raimondo, V. Vittoria, L. Vertuccio, C. Naddeo, S. Russo, B. De Vivo, P. Lamberti, G. Spinelli, V. Tucci, Development of epoxy mixtures for application in aeronautics and aerospace, RSC Adv 4 (2014) 15474-15488. [2] J. Gu, X. Yang, Z. Lv, N. Li, C. Liang, Q. Zhang, Functionalized graphite nanoplatelets/epoxy resin nanocomposites with high thermal conductivity, Int J Heat Mass Tran 92 (2016) 15-22. [3] S.J. Park, M.K. Seo, J.R. Lee, D.R. Lee, Studies on epoxy resins cured by cationic latent thermal catalysts: the effect of the catalysts on the thermal, rheological, and mechanical properties, J Polym Sci Pol Chem 39 (2001) 187-195. [4] K. Kudo, S. Fuse, M. Furutani, K. Arimitsu, Imidazole-type thermal latent curing agents with high miscibility for one-component epoxy thermosetting resins, J Polym Sci Pol Chem 54 (2016) 2680-2688. [5] K. Suzuki, H. Horii, Y. Sugita, F. Sanda, T. Endo, Promotion effect of bifunctional five-membered cyclic dithiocarbonate on curing of one-component epoxy resin by imines as latent initiator, J Appl Polym Sci 94 (2004) 961-964. [6] K. Kudo, M. Furutani, K. Arimitsu, Imidazole derivatives with an intramolecular hydrogen bond as thermal latent curing agents for thermosetting resins, ACS Macro Lett 4 (2015) 1085-1088. [7] K. Chen, Y. Shen, M. Yeh, F.F. Wong, Complexes of imidazole with poly(ethylene glycol)s as the thermal latency catalysts for epoxy-phenolic resins, J Taiwan Inst Chem E 43 (2012) 306-312. [8] K. Arimitsu, S. Fuse, K. Kudo, M. Furutani, Imidazole derivatives as latent curing agents for epoxy thermosetting resins, Mater Lett 161 (2015) 408-410. [9] L. Feng, Y. Wang, Y. Wang, H. Liu, J. Zhao, Study on reaction kinetics of epoxy resin cured by a modified dicyandiamide, J Appl Polym Sci 127 (2013) 1895-1900. [10] 王永超, 林树东, 涂园园, 李江华, 胡继文, 李妃, 一种环氧树脂潜伏性固化剂二苯基双胍的合成与性能, 精细化工, (2016) 224-230. [11] 余文俊, 张道洪, 陈苏芳, 低温发泡用热固性酚醛树脂的固化动力学研究, 化学与生物工程, (2016) 32-35. [12] M. Tripathi, D. Kumar, C. Rajagopal, P.K. Roy, Curing kinetics of self-healing epoxy thermosets, Journal of Thermal Analysis and Calorimetry, 119 (2015) 547-555. [13] J. Rocks, L. Rintoul, F. Vohwinkel, G. George, The kinetics and mechanism of cure of an amino-glycidyl epoxy resin by a co-anhydride as studied by FT-Raman spectroscopy, POLYMER, 45 (2004) 6799-6811.

3. 毕业设计（论文）进程安排

第一周～第二周： 文献查阅，查阅有关环氧树脂潜伏型固化剂的相关文献，要求学习并掌握利用中国期刊网、维普、ei、ca、elsevier、欧洲 专利等查阅文献，不少于15篇。

第三周：英文文献的翻译：文献字数3000字以上 开题：完成开题报告。

第四周～第十五周：开展实验工作，主要有以下几个部分 1、改性咪唑的合成及表征；2、几种固化动力学模型的建立； 3、利用动力学模型对固化过程进行预测并验证。