等离子体引发乙烯基单体聚合行为研究任务书
2020-04-21 16:58:18
1. 毕业设计(论文)的内容和要求
首先简单介绍了等离子体引发乙烯基单体聚合的原理。
其次叙述了实验的原料、流程及聚合以等离子体引发MMA、St等单体进行均聚或共聚研究,研究其聚合速率、分子量、分子量分布等动力学行为,以FTIR、NMR等方法对聚合物结构进行表征,探讨等离子体引发聚合与传统自由基聚合、阴离子聚合的差异,以及与溶剂化引发聚合的关系。
2. 参考文献
[1] Coad, B. R.; Scholz, T.; Vasilev, K.; Hayball, J. D.; Short, R. D.; Griesser, H. J. Functionality of Proteins Bound to Plasma Polymer Surfaces ACS Appl. Mater. Interfaces 2012,4,2455-2463. [2] Yao, W. H.; Tsou, C. H.; Chen, J. C. Plasma Grafting with Methyl Di-Ally Ammonium Salt to Impart Anti-Bacterial Properties to Polypropylene Fibres Text. East.Eur.2016,24(3)117-123 [3] Inagaki, N.; Tasaka, S.; Shimada, S. Comparative Studies on Surface Modification of Poly(ethylene terephthalate) by Remote and Direct Argon Plasmas J. Appl. Polym. Sci. 2001,79,808-815. [4] Persin, Z.; Jesih, A.; Stana-Kleinschek, K. The Plasma Polymerisation Process For The Deposition Of Amino-Containing Film On The Poly(Ethylene Terephthalate) Dressing-Layer For Safe Wound-Healing Mater. Technol.2012,46(1)63-68. [5] Tsou, C. H.; Suen, M. C.; Tsou, C. Y.; Chen, J. C.; Yeh, J. T.; Lin, S. M.; Yao, W. H.; Lai, Y. C.; Hwang, J. Z.; Huang, S. H.; Hong, W. S.; Hu, C. C.; Lee, K. R.; Lai, J. Y. Argon Plasma for Improving the Physical and Anti-bacterial Properties of Crosslinked Cotton Cellulose with Dimethyloldihydroxyethyleneurea-Maleic Acid Fibres Text. East. Eur.2015,23(1)49-56. [6] Jaleh, B.; Parvin, P.; Wanichapichart, P.; Pourakbar Saffar, A.; Reyhani, A. Document Induced Super Hydrophilicity Due to Surface Modification of Polypropylene membrane Treated by O2 plasma Appl.Surf.Sci.2010,257,1655. [7] Yao, W. H.; Chen, J. C.; Chen, C. C. Excellent Anti-Bacterial Activity and Surface Properties of Polyamide-6 Films Modified with Argon-Plasma and Methyl Diallyl Ammonium Salt-Graft Polym. Adv. Technol.2008,19,1513-1521. [8] Zhao, J.; Song, L. J.; Shi, Q.; Luan, S. F.; Yin, J. H. Antibacterial and Hemocompatibility Switchable Polypropylene Nonwoven Fabric Membrane Surface ACS Appl. Mater. Interfaces 2013,5,5260-5268. [9] Huh, M. W.; Kang, I. K.; Lee, D. H.; Kim, W. S.; Lee, D. H. Surface Characterization and Antibacterial Activity of Chitosan-Grafted Poly(ethylene terephthalate) Prepared by Plasma Glow Discharge J.Appl.Polym.Sci.2001,81,2769-2778. [10] Guimond, S.; Radu, I.; Czeremuszkin, G.; Carlsson, D. J.; Wertheimer, M. R. Biaxially Oriented Polypropylene (BOPP) Surface Modification by Nitrogen Atmospheric Pressure Glow Discharge (APGD) and by Air Corona Plasmas Polym.2002,7,71-88. [11] Duan, S. X.; Liu, X.; Wang, Y. N.; Meng, Y. D.; Alsaedi, A.; Hayat, T.; Li, J. X. Plasma surface modification of materials and their entrapment of water contaminant: A review Plasma Processes Polym. 2017,14(9). [12] Duan, S. X.; Wang, Y. N.; Liu, X.; Shao, D.; Hayat, T.; Alsaedi, A.; Li, J. X. Removal of U(VI) from aqueous solution by amino functionalized flake graphite prepared by plasma treatment ACS Sustainable Chem. Eng.2017,5(5)4073-4085. [13] Zhu, H. S.; Duan, S. X.; Chen, L.; Alsaedi, A.; Hayat, T.; Li, J. X. Plasma-induced grafting of acrylic acid on bentonite for the removal of U(VI) from aqueous solution Plasma Sci. Technol. 2017,19(11). [14] Pedrosa, P.; Chapp#233;, J. M.; Fonseca, C.; Machado, A. V.; N#243;brega, J.; Vaz, M. F. Plasma Surface Modification of Polycarbonate and Poly(propylene) Substrates for Biomedical Electrodes Plasma Processes Polym. 2010,7,676-686. [15] Petersen, J.; Fouquet, T.; Michel, M.; Toniazzo, V.; Dinia, A.; Ruch, D.; Bomfim, J. A. S. Enhanced Adhesion over Aluminum Solid Substrates by Controlled Atmospheric Plasma Deposition of Amine-Rich Primers ACS Appl.Mater.Interfaces 2012,4,1072-1079. [16] Liu, Z. M.; Xu, Z. K.; Wang, J. Q.; Wu, J.; Fu, J. J. Surface Modification of Polypropylene Microfiltration Membranes by Graft Polymerization of N-vinyl-2-pyrrolidone Eur. Polym. J. 2004, 40,2077-2087. [17] Anjum, N.; Gulrez, S. K. H.; Singh, H.; Gupta, B. Development of Antimicrobial Polypropylene Sutures by Graft Polymerization. I. Influence of Grafting Conditions and Characterization J. Appl. Polym. Sci.2006,101,3895-3901. [18] Ruckenstein E,Li Z F.Surfance Modification and Functionalization through the Self-Assembled Monolayer and Graft Polymerization[J].Advances in Colloid Interface Science,2005,113(1):43-63. [19] Derkaoui, S. M.; Avramoglou, T.; Barbaud, C.; Letourneur, D. Synthesis and Characterization of A New Polysaccharide-Graft-Polymethacrylate Copolymer for Three-Dimensional Hybrid Hydrogels Biomacromolecules 2008,9,3033-3038. [20] Yaman, N.; Ouml;Zdo#287;an, E.; Seventekin, N.; Ayhan, H. Plasma treatment of polypropylene fabric for improved dyeability with soluble textile dyestuff Appl. Surf. Sci. 2009,255,6764-6770.
3. 毕业设计(论文)进程安排
1.26-2.26:撰写开题报告,翻译参考文献 2.26-3.26:进行聚合实验 3.26-4.26:对产物进行表征 4.26-5.26:撰写毕业论文,制作答辩ppt
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