聚甲基丙烯酸甲酯及其嵌段共聚物的酰胺化改性与表征任务书
2020-04-26 12:56:02
1. 毕业设计(论文)的内容和要求
利用离子液体和酯交换反应进行嵌段聚合物聚苯乙烯-聚甲基丙烯酸甲酯的后聚合改性。
具体包括:嵌段聚合物聚苯乙烯-聚甲基丙烯酸甲酯分别与乙醇胺,2-甲氧基乙醇胺,2-(2-氨基乙氧基)乙醇,n-甲基乙醇胺,苄胺和正己胺的酯 - 酰胺交换反应,之后用离子液体再进一步处理。
具体分为: 第一周~第二周:文献查阅 查阅有关嵌段聚合物后聚合反应改性和离子液体在嵌段聚合物中的应用方面的文献,要求学习并掌握利用中国期刊网、ca、ei、elsevier等查阅文献,不少于30篇。
2. 参考文献
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Multi-Component Post-Polymerization Modification Reactions of Polymers Featuring Lignin-Model Compounds[J]. Polymer Chemistry, 2018, 9(16). [6] Kong T , Guo G , Zhang H , et al. Post-synthetic Modification of Polyvinyl Alcohol with a Series of N Alkyl Substituted Carbamates towards Thermo and CO2-Responsive Polymers[J]. Polym. Chem. 2017:10.1039.C7PY01136A. [7] Heba G , Shaojian L , Jiaojiao S , et al. A synthetic approach toward a pH and sugar-responsive diblock copolymer ,#160;via , post-polymerization modification[J]. Polymer Chemistry, 2018:10.1039.C8PY00660A-. [8] Guo X , Choi B , Feng A , et al. Polymer Synthesis with More Than One Form of Living Polymerization Method[J]. Macromolecular Rapid Communications, 2018. [9] Kaditi E , Mountrichas G , Pispas S . Amphiphilic block copolymers by a combination of anionic polymerization and selective post-polymerization functionalization[J]. European Polymer Journal, 2011, 47(4):415-434. [10] He Y , Liu Q , Hu J , et al. 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[18] Guillaume, Sophie M . Recent advances in ring-opening polymerization strategies toward α,ω-hydroxy telechelic polyesters and resulting copolymers[J]. European Polymer Journal, 2013, 49(4):768-779. [19] Pei Y , Lowe A B , Roth P J . Stimulus‐Responsive Nanoparticles and Associated (Reversible) Polymorphism via Polymerization Induced Self‐assembly (PISA)[J]. Macromolecular Rapid Communications, 2016, 38(1). [20] Lee S , Kim H , Chae S , et al. Diblock copolymer micelles as surface-functionalized particles and direct decoration of nanoparticles on their surface[J]. Polymer, 2015, 61:15-19. [21] Bode S, Enke M, G#246;rls H, et al. Blocked isocyanates: an efficient tool for post-polymerization modification of polymers[J]. Polymer Chemistry, 2014, 5(7):2574-2582. Biedermann F, Appel E A, Barrio J D, et al. Postpolymerization Modification of Hydroxyl-Functionalized Polymers with Isocyanates[J]. Macromolecules, 2011, 44(12):4828-4835. [23] Neindre M L, Nicola#255; R. One-pot deprotection and functionalization of polythiol copolymers via six different thiol#8211;X reactions[J]. Polymer International, 2014, 63(5):887-893. [24] Xi W, Scott T F, Kloxin C J, et al. Click Chemistry in Materials Science[J]. Advanced Functional Materials, 2014, 24(18):2572-2590. [25] 佚名.调控氢键作用力在多组分嵌段共聚物共混体系中的自组装结构[J]. 高分子学报, 2018(8). [26] 石家华, 孙逊, 杨春和,等. 离子液体研究进展[J]. 化学通报, 2002, 65(4):243-250. [27] 顾彦龙, 石峰, 邓友全. 室温离子液体:一类新型的软介质和功能材料[J]. 科学通报, 2004, 49(6):515-521. [28] 邓友全, 石峰, 彭家建,等. 离子液体介质与材料研究进展[J]. 中国科学院院刊, 2005, 20(4):297-300. [29] 盛平厚, 余瑛, 吴刚. 关于控制PET/PEN共混物酯交换反应的研究[J]. 塑料工业, 2001, 29(1):10-12. [30] 宋睿, 金光远, 崔政伟,等. 酯交换反应体系混合物料的介电特性[J]. 化工学报, 2018, 69(8).
3. 毕业设计(论文)进程安排
18. 12.31-19.1.11 文献查阅,了解课题 19. 2.25-19.3.10 英文文献翻译以及完成开题报告 19.3.11-19.4.4 按照实验计划进行试验 19.4.5-19.4.7 清明节休假 19.4.8-19.4.28 按照实验计划进行试验 19.4.29-19.4.30 进行中期检查 19.5.1-19.5.3 劳动节休假 19.5.4-19.5.31 进行实验并整理数据 19.6.1-19.6.9 撰写完成毕业论文 19.6.10-19.6.16 毕业论文答辩
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