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毕业论文网 > 任务书 > 材料类 > 高分子材料与工程 > 正文

溶剂响应性聚合物刷表面的自清洁性能任务书

 2020-05-20 20:08:03  

1. 毕业设计(论文)的内容和要求

本课题以等离子方法制备了溶剂响应性的聚(聚乙二醇甲基丙烯酸酯-甲基丙烯酸十二氟庚酯)(p(pegma-dfhma))共聚物刷。

以接触角、xps等方法评价分析共聚物刷表面的溶剂响应性质。

利用粘附力测试、粘附功及剩余功理论计算等方法考察共聚物刷表面油滴的脱离特性。

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2. 参考文献

[1] 黄健,王晓琳.低温等离子体对聚合物多孔膜的亲水化改性[J] .高分子通报,2005,6:16-26. [2] Schild G H. Poly(N-isopropylacrylamide):Experiment,theory and application[J]. Progress in Polymer Science,1992,17:163-249. [3] 黄健,王晓琳,陈秀珍.聚(N-异丙基丙烯酰胺) 的体积相转变及在分离领域中的应用研究. [J].高分子材料科学与工程,2001,17(6):35-39. [4] Zhou C,Qian S S,Li X J,et al. Synthesis and characterization of well-defined PAA-PEG multi-responsive hydrogels by ATRP and click chemistry[J]. Royal Society of Chemistry Advances,2014,4:54631-54640. [5] Liu R,Liao P H,Liu J K,et al. Responsive polymer-coated mesoporous silica as a pH-sensitive nanocarrier for controlled release.[J]. Langmuir,2011,27:3095-3099. [6] AZZARONI O.Polymer brushes here,there,and everywhere:Recent advances in their practical applications and emerging opportunities in multiple research fields[J].Journal of Polymer Science Part A-Polymer Chemistry,2012,50:3225-3258. [7] XU Y L,CHEN X Q,HAN X,et al. Lock/Unlock mechanism of solvent-responsive binary polymer brushes:Density functional theory approach.[J].Langmuir,2013,29:4988-4997. [8] Muquan Yang, Jun Mao, Wei Nie,et al. Facile synthesis and responsive behavior of PDMS-b-PEG diblock copolymer brushes via photoinitiated ”Thiol-ene” click reaction.[J]. Polymer Chemistry. 2012, 50: 2075#8211;2083. [9] 黄伟欣,黄洪.超亲水涂料的研究进展.[J].广东化工,2008,35(186):46-49. [10] Cong Qian, Chen Guanghua, Fang Yan, Ren Luquan.Superhydrophobic characteristics of butterfly wingsurface.[J]. Journal of Bionics Engineering, 2004, 4(1):249-255 [11] 粟常红,陈庆民,仿荷叶表面研究进展.[J].化学通报,2008,1:24-31 [12] 魏增江,田冬,肖成龙等,超疏水表面:从制备方法到功能应用[J].化学进展,2009,28(11):1965-1973 [13] Ma X , Tian H. Stimuli-responsive supramolecular polymers in aqueous solution[J]. Accounts of Chemical Research,2014,47:1971-1981. [14] 李雪梅,贺继东. 两亲性聚合物分子自组装的研究进展[J]. 化工进展,2014,33(10):2665-2699. [15] Lu Y , Sun W J , Gu Z. Stimuli-responsive nanomaterials for therapeutic protein delivery[J]. Journal of Controlled Release,2014,194:1-19. [16] Islam R M,Gao Y F,Li X,et al. Stimuli-responsive polymeric materials for human health applications[J].Chinese Science Bulletin,2014,59(32): 4237-4255. [17] Li G Y ,Guo L , Wen Q W , et al. Thermo- and pH-sensitive ionic-crosslinked hollow spheres from chitosan-based graft copolymer for 5-fluorouracil release[J]. International Journal of Biological Macromolecules,2013,55:69-74

3. 毕业设计(论文)进程安排

起讫日期 设计(论文)各阶段工作内容 2016.02.22-2016.02.28 文献查阅 2016.02.29-2016.03.06 文献翻译 2016.03.07-2016.03.13 开题报告 2016.03.14-2016.04.30 实验工作 2016.05.04-2016.05.07 论文阶段及中期检查 2016.06.01-2016.06.11 撰写论文 2016.06.12-2016.06.14 论文答辩

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