1. 毕业设计（论文）的内容和要求

内容： 1. 查阅文献，拟定实验方案； 2. 以1173为光引发剂，4210为光敏树脂，通过大量实验评价不同粒径的填料滑石粉、铜粉、空心玻璃微珠、陶瓷微球、炭黑等在不同光照强度和不同光照时间等条件下的体积收缩率及其他性能； 3. 评价不同复配纳米材料体系的固化速度、凝胶率和收缩率； 4.找出凝胶率与收缩率的关系； 5 评价最优体系的力学性能； 要求： 1. 查阅相关文献，写出开题报告，文献占有量不少于15篇。

2. 翻译一篇相关英文文献。

3. 合理利用时间，完成实验内容。

2. 参考文献

[1] Jiajing Zhang, Sue Hao, Qingyan Shang, Fangwei Wang, Yong Wu,Shengjie You. Synthesis of epoxy acrylate and preparation of dual-curable ECAs based on conductive ceramic powders[J].J Mater Sci: Mater Electron (2015) 26:6266#8211;6275. [2] 张聪超. 基于EA体系的光固化三维打印材料的制备及其改性研究[D]. 南京航空航天大学, 2015. [3] 杜宇雷, 孙菲菲, 原光, 等. 3D打印材料的发展现状[J]. 徐州工程学院学报(自然科学版), 2014(01):20-24. [4] 段玉岗, 王素琴, 卢秉恒. 用于立体光造型法的光固化树脂的收缩性研究[J]. 西安交通大学学报, 2000(03):45-48. [5] 贺锡挺, 王德海, 马国杰. 环氧树脂/环氧丙烯酸酯混杂光固化材料的结构与性能[J]. 化工学报, 2009(03):769-774. [6] Cesaretti G, Dini E, De Kestelier X, et al. Building components for an outpost on the Lunar soil by means of a novel 3D printing technology[J]. ACTA ASTRONAUTICA, 2014,93:430-450. [7] Bergmann C, Lindner M, Zhang W, et al. 3D printing of bone substitute implants using calcium phosphate and bioactive glasses[J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2010,30(12):2563-2567. [8] Crivello J V, Kong S Q. Synthesis and characterization of second-generation dialkylphenacylsulfonium salt photoinitiators[J]. MACROMOLECULES, 2000,33(3):825-832. [9] Crivello J V, Song S Y. The synthesis and cationic photopolymerization of monomers based on dicyclopentadiene[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1999,37(16):3427-3440. [10] 蔡晓路, 陆明湖. 阳离子光引发剂的发展动态[J]. 感光材料, 1999(S1):79-83. [11] 郑耀臣, 魏无际. 光固化涂料用光引发剂的进展[J]. 涂料工业, 2002,32(1):31-35. [12] Crivello J V. Photoinitiated cationic polymerization with triarylsulfonium salts - Reflections[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1996,34(16):3227-3228. [13] Crivello J V. The discovery and development of onium salt cationic photoinitiators[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1999,37(23):4241-4254. [14] Crivello J V, Kong S, Jang M. Cationic polymerization: New developments and applications[J]. MACROMOLECULAR SYMPOSIA, 2004,217:47-61. [15] CRIVELLO J V. CATIONIC POLYMERIZATION - IODONIUM AND SULFONIUM SALT PHOTOINITIATORS[J]. ADVANCES IN POLYMER SCIENCE, 1984,62:1-48. [16] Crivello J V, Ma J, Jiang F, et al. Advances in the design of photoinitiators, photo-sensitizers and monomers for photoinitiated cationic polymerization[J]. MACROMOLECULAR SYMPOSIA, 2004,215:165-177. [17] ARSU N, DAVIDSON R S, HOLMAN R. FACTORS AFFECTING THE PHOTOYELLOWING WHICH OCCURS PHOTOINITIATED POLYMERIZATION OF ACRYLATES[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1995,87(2):169-175.

3. 毕业设计（论文）进程安排

2018.2.26-2018.3.8 结合前期查阅文献，充分了解课题背景，完成文献综述，翻译外文资料 2018.3.6-2018.3.17 确定实验方案，基本掌握实验设备操作。

2018.3.16-2018.5.30 根据实验方案评价不同粒径的填料滑石粉、铜粉、空心玻璃微珠、陶瓷微球、炭黑等在不同光照强度和不同光照时间等条件下的体积收缩率。

2018.4.20-2018.4.30 参加中期答辩 2018.5.20-2018.6.4 实验数据整理，撰写毕业论文，准备论文答辩。