多孔MnO2微米马达的制备和有机杂质吸附性能研究任务书
2020-06-28 20:17:50
1. 毕业设计(论文)的内容和要求
微纳米马达由于其自主运动性能,能够完成一系列复杂的任务。
它的出现将推动诸多领域发生革命性变化,例如:生物医药,微纳米加工,环境检测与修复,以及食品安全等。
最近,化学驱动的微纳米马达由于在介质中的有效运动受到了广泛关注,驱动燃料包括酸性介质hcl、h2so4、h3po4,胃酸、水、肼、br2、i2、双氧水等。
2. 参考文献
1. H. Wang, G. Zhao, M. Pumera,Beyond Platinum: Bubble-Propelled Micromotors Based on Ag and MnO2 Catalysts,J. Am. Chem. Soc. 136 (2014) 2719#8722;2722. 2. G. Yang, L. Xu, Y. Chao, J. Xu, X. Sun, Y. Wu, R. Peng, Z. Liu, Hollow MnO2 as a tumor-microenvironmentresponsive biodegradable nano-platform for combination therapy favoring antitumor immune responses, Nature Communications 902 (2017) doi:10.1038/s41467-017-01050-0. 3. J. Li, P. Angsantikul, W. Liu, B. Esteban-Fern#225;ndez de Aacute;vila, X. Chang, E. Sandraz, Y. Liang, S. Zhu, Y. Zhang, C. Chen, W. Gao, L. Zhang, J. Wang, Biomimetic Platelet-Camouflaged Nanorobots for Binding and Isolation of Biological Threats, Adv. Mater. (2017), DOI: 10.1002/adma.201704800. 4. M.W. Ambrogio, C.R. Thomas, Y.L. Zhao, J.I. Zink, J.F. Stoddartt, Mechanized silica nanoparticles: a new frontier in theranostic nanomedicine, Acc. Chem. Res. 44 (2011) 903#8211;913. 5. V. V. Singh, B. Jurado-Sacute;anchez, S. Sattayasamitsathit, J. Orozco, J. X. Li, M. Galarnyk, Y. Fedorak, J. Wang, Multifunctional Silver‐Exchanged Zeolite Micromotors for Catalytic Detoxification of Chemical and Biological Threats,Adv. Funct. Mater., 25 (2015)2147#8211;2155.. 6. Z. Wu, Y. Wu, W. He, X. Lin, J. Sun, Q. He, Self‐propelled polymer‐based multilayer nanorockets for transportation and drug release Angew. Chem. Int. Ed. 52 (2013) 7000#8211;7003. 7. J. Li, S. Thamphiwatana, W. Liu, B. Esteban-Fern#225;ndez de Aacute;vila, P. Angsantikul, E. Sandraz, J. Wang, T. Xu, F. Soto, V. Ramez, X. Wang, W. Gao, L. Zhang, J.Wang,Enteric micromotor can selectively position and spontaneously propel in the gastrointestinal tract, ACS Nano 10 (2016) 9536#8211;9542 8. W. Wang, S. Li, L. Mair, S. Ahmed, T.J. Huang, T.E. Mallouk, Acoustic propulsion of nanorod motors inside living cells Angew. Chem. 126 (2014) 3265#8211;3268. 9. D. A. Wilson, R. J. M. Nolte and J. C. M. van Hest, Autonomous movement of platinum-loaded stomatocytes, Nat. Chem.,4 (2012) 268#8211;274.. 10. X. Ma, A.C. Hortelatilde;o, T. PatinOtilde;, S. S#225;nchez, Enzyme catalysis to power micro/nanomachines, ACS Nano 10 (2016) 9111#8211;9122. 11. L. Wang, J. Chen, X. Feng. W. Zeng, R. Liu, X. Lin, Y. Ma, L. Wang, Self-propelled manganese oxide-based catalytic micromotors for drug delivery, RSC Adv., 6 (2016) 65624#8211;65630. 12. M .Safdar, T. Do Minh, N. Kinnunen, J. Ja#776;nis, Manganese Oxide Based Catalytic Micromotors: E#64256;ect of Polymorphism on Motion, ACS Appl. Mater. Interfaces 8 (2016) 32624#8722;32629. 13. D.A. Uygun, B. Jurado-Sa#769;nchez, M. Uygun, J.Wang, Self-Propelled Chelation Platforms for Efficient Removal of Toxic Metals. Environ. Sci.: Nano 3 (2016) 559#8722;566. 14. S. Chou, F. Cheng, J. Chen, Electrodeposition Synthesis and Electrochemical Properties of Nanostructured Gamma-MnO2 Films. J. Power Sources, 162 (2006) 727#8722;734. 15. L. Wu, J. Xia, G. Hou, H. Cao, Y. Tang, G. Zheng,Potentiodynamical deposition of nanostructured MnO2 film at the assist of electrodeposited SiO2 as template, Electrochimica Acta, 191 (2016) 375#8211;384
3. 毕业设计(论文)进程安排
2017-12-17~2018-01-5 查阅中外文资料,翻译外文资料 要求定期参加讨论 2017-01-06~2018-01-12 撰写开题报告,要求参加开题报告答辩 2017-02-26~2018-03-31 制定实验方案,采用模板法,探索电化学沉积参数对多孔MnO2形貌和催化活性的影响,定期汇报实验进展,参与论文讨论 2018-04-01~2018-04-29 研究双氧水浓度对多孔MnO2微米马达运动速率的影响,定期讨论 2018-05-01~2014-05-07 撰写中期报告,参加中期检查答辩 2018-05-08~2018-06-09 探讨多孔MnO2马达对有机杂质的吸附降解作用,总结实验结果,补充实验参加讨论 2018-06-10~2018-06-14 撰写毕业论文,按时完成毕业论文,参加毕业论文答辩
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