1. 毕业设计（论文）的内容和要求

探究掺和物对碱激发粉煤灰-矿渣的耐酸性的影响，这主要包括试样的抗压强度变化和掺和物对粉煤灰-矿渣体系的水化放热的影响。分析碱激发剂的种类、掺和物的掺量及粉煤灰/矿渣固料比对耐酸性的影响。通过向碱激发粉煤灰-矿渣中掺入粒度细小的沸石分子筛作为形核剂以及添加活性组分球形二氧化硅，探讨此种方法对碱激发胶凝材料耐酸性能的改善作用及其原因。

2. 参考文献

[1] Duxson P, Fern#225;ndez-Jim#233;nez A, Provis JL, Lukey GC, Palomo A, van Deventer JSJ. Geopolymer technology: the current state of the art. J Mater Sci 2007;42:2917-2933. [2] Provis JL, Lukey GC, van Deventer JSJ. Do geopolymers actually contain nanocrystalline zeolites? A reexamination of existing results. Chem Mater 2005;17:3075-3085. [3] Granizo ML, Blanco MT. Alkaline activation of metakaolin an isothermal conduction calorimetry study. J Therm Anal 1998;52:957-965. [4] Lee WKW, van Deventer JSJ. Structural reorganization of class F fly ash in alkaline silicate solutions. Colloids Surf A 2002;211:49-66. [5] Duxson P, Mallicoat SW, Lukey GC, Kriven WM, van Deventer JSJ. The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers. Collids Surf A 2007;292:8-20. [6] Provis JL, van Deventer JSJ. Geopolymerisation kinetics. 1. In situ energy-dispersive X-ray diffractometry. Chem Eng Sci 2007;62:2309-2317. [7] Provis JL, van Deventer JSJ. Geopolymerisation kinetics. 2. Reaction kinetics modeling. Chem Eng Sci 2007;62:2318-2329. [8] Zhang Z, Wang H, Provis JL, Bullen F, Reid A, Zhu Y. Quantitative kinetic and structural analysis of geopolymers. Part 1. The activation of metakaolin with sodium hydroxide. Thermochim Acta 2012;539:23-33. [9] Provis JL, Duxson P, van Deventer JSJ, Lukey GC. The role of mathematical modeling and gel chemistry in advancing geopolymer technology. Chem Eng Res Des 2005;83:853-860. [10] Lee WKW, van Deventer JSJ. Use of infrared spectroscopy to study geopolymerization of heterogeneous amorphous aluminosilicates. Langmuir 2003;19:8726-8734.

3. 毕业设计（论文）进程安排

12月16日~1月17日 开始初期实验（包括样品制备，早期养护，以及浸泡实验试样制备）。

3月10日~5月1日 进行浸泡实验的强度损失、并在其间补充微量热法实验及适量xrd和sem微观实验。

5月1日~6月7日 完成毕业论文。