ZIF-67衍生碳材料的制备及催化降解苯酚性能研究任务书
2020-04-17 20:29:39
1. 毕业设计(论文)的内容和要求
酚类化合物是工业生产中极其重要的原材料和中间产物,被广泛应用于石油化工、造纸、苯酚及酚醛树脂生产、皮革、农药合成、医药等领域,含酚废水主要来源于上述行业产生和排放的废水。
其指主要成分为酚类及其衍生物(苯酚、甲苯酚、苯二酚)。
酚类化合物是对一切生物个体都有毒害作用,一旦进入水体,会对水生生物、农业及人体生命健康造成严重威胁。
2. 参考文献
[1] Li, M., Liu, X., Xiong, Y. Journal of Materials Chemistry A, 2015, 3(8), 4255-4265. [2] Pan, Y., Sun, K., Liu, S. J. Am. Chem. Soc., 2018, 140 (7), 2610#8211;2618. [3]李卫平, 卢雪枫, 杨文焕,等. 厌氧/特异性移动床生物膜反应器(A/SMBBR)组合工艺处理农药含酚废水[J].环境工程学报, 2017, 11(3):1569-1574. [4] 张剑桥, 迟惠中, 宋阳,等.Ce3 与 Cu2 协同强化芬顿体系氧化苯酚的效能与机制研究[J]. 环境科学, 2016, 37(8):3067-3072. [5]牛凤兴, 付峰, 高晓明,等. WO3/Cu2O 光催化剂的制备及其光催化降解苯酚的研究[J]. 精细石油化工, 2014, 31(2):6-9. [6]毕强, 薛娟琴, 于丽花,等. 镧掺杂对Ti/Sb-Sn O2 阳极电催化性能影响的研究[J]. 中国稀土学报, 2013, 31(4):465-472. [7]Saratale R G,Hwang K J, Song J Y,et al. Electrochemical oxidation of phenol for wastewater treatment using Ti/Pb O2 electrode[J]. Journal of Environmental Engineering, 2015, 142(2): 04015064. [8]Zhu C, Hu C, Lu J, et al. Electrocatalytic degradation of bisphenol a in aqueous solution using β-Pb O2/Ti as anode[J]. Russian Journal of Electrochemistry, 2015, 51(4): 353-361. [9]Kong H, Lu H, Zhang W, et al. Performance characterization of Ti substrate lead dioxide electrode with different solid solution interlayers [J]. Journal of Materials Science, 2012, 47(18): 6709-6715. [10]Wang Z, Xu M, Wang F, et al. Preparation and characterization of a novel Ce doped PbO2 electrode based on Ni O modified Ti/TiO2 NTs substrate for the electrocatalytic degradation of phenol wastewater [J]. Electrochimica Acta, 2017, 247: 535-547. [11]魏金枝, 张少平, 胡琴,等. 碳纳米管改性 Sb-Sn O2/Ti 电极制备及性能[J]. 哈尔滨理工大学学报, 2017, 22(3):107-111. [12]Liang F, Zhu Y. Enhancement of mineralization ability for phenol via synergetic effect of photoelectrocatalysis of g-C3N4 film[J]. Applied Catalysis B: Environmental, 2016, 180: 324-329. [13]Xu W, Wang S Q, Zhang Q Y, et al. Abnormal Oxidation of Ag Films and Its Application to Fabrication of Photocatalytic Films with a-TiO2/h-Ag2O Hetero structure[J]. The Journal of Physical Chemistry C, 2017, 121(18): 9901-9909. [14]Paul K K, Ghosh R, Giri P K. Mechanism of strong visible light photo catalysis by Ag2O-nanoparticle-decorated monoclinic TiO2 (B) porous nanorods[J]. Nanotechnology, 2016, 27(31): 315703. [15]Tan C, Zhang Z, Qu Y, et al. Ag2O/Ti O2Nanocomposite Hetero structure as a Dual Functional Semiconducting Substrate for SERS/SEIRAS Application[J]. Langmuir, 2017, 33(22): 5345-5352. [16] Zeng, T.; Zhang, X.; Wang, S.; Niu, H.; Cai, Y., Spatial confinement of a Co3O4 catalyst in hollow metal-organic frameworks as a nanoreactor for improved degradation of organic pollutants. Environmental Science Technology 2015, 49, (4), 2350-2357.
3. 毕业设计(论文)进程安排
起讫日期 设计(论文)各阶段工作内容 备 注 2019.1~2019.3 查阅文献,撰写文献综述和开题报告,并修改开题报告。
2019.3~2019.5 实验阶段(制定实验步骤、实验方案、实验、分析实验数据、补充实验) 2019.5~2019.6.10 撰写论文、修改论文,准备答辩。