1. 毕业设计（论文）的内容和要求

查阅相关文献与专业书籍了解目前锆mof的改性以及其co2的吸附性能，了解锆mof课题的相关背景。

通过合成配体tcpp，然后溶剂热法合成锆mof，研究其二氧化碳吸附性能，并通过引入其他金属位对锆mof进行改性，考察其他金属掺入对锆mof吸附性能的影响。

在完成实验，撰写论文的过程中，培养学生自主学习和独立思考的能力，了解如何使用相关实验设备和分析仪器，学会正确的实验操作技能，并养成良好的科研习惯。

2. 参考文献

[1] Rochford J, Chu D, Hagfeldt A, et al. Tetrachelate porphyrin chromophores for metal oxide semiconductor sensitization: effect of the spacer length and anchoring group position.[J]. Journal of the American Chemical Society, 2007, 129(15):4655-65. [2] Liu W, Yin X B. Metal#150;organic frameworks for electrochemical applications[J]. Energy Environmental Science, 2012, 5(11):9269-9290. [3] Zhu X, Li B, Yang J, et al. Effective Adsorption and Enhanced Removal of Organophosphorus Pesticides from Aqueous Solution by Zr-Based MOFs of UiO-67[J]. Acs Applied Materials Interfaces, 2015, 7(1):223-31. [4] And H J S, Gam K T, Bestaoui N, et al. Epoxy Nanocomposites Based on the Synthetic α-Zirconium Phosphate Layer Structure[J]. Chemistry of Materials, 2004(16). [5] Liao Y, Weber J, Faul C F J. Fluorescent Microporous Polyimides Based on Perylene and Triazine for Highly CO2-Selective Carbon Materials[J]. Macromolecules, 2015, 48(7). [6] Tsuruoka T, Furukawa S, Takashima Y, et al. Nanoporous nanorods fabricated by coordination modulation and oriented attachment growth.[J]. Angewandte Chemie International Edition, 2009, 48(26):4739-43. [7] Bauer S, Serre C, Devic T, et al. High-throughput assisted rationalization of the formation of metal organic frameworks in the Iron(III) aminoterephthalate solvothermal system.[J]. 2008, 47(17):7568-7576. [8] 陈志敏, 左霞, 吴谊群. 高密度可录光盘存储材料:金属卟啉配合物[J]. 化学进展, 2004, 16(5):820-828. [9] Horcajada P, Gref R, Baati T, et al. Metal-organic frameworks in biomedicine.[J]. Chemical Reviews, 2012, 112(2):1232-68. [10] Sun L, Boo W J, Sue H J, et al. Preparation of ?-zirconium phosphate nanoplatelets with wide variations in aspect ratios[J]. New Journal of Chemistry, 2007, 31(1):39-43. [11] 谢先宇, 任奇志, 马紫峰. 金属卟啉制备及其电化学特性[J]. 化工学报, 2004, 55(12):2086-2090. [12] Li G, Yu W, Cui Y. A homochiral nanotubular crystalline framework of metallomacrocycles for enantioselective recognition and separation.[J]. Journal of the American Chemical Society, 2008, 130(14):4582-3. [13] Cavka J H, Jakobsen S, Olsbye U, et al. A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability.[J]. Journal of the American Chemical Society, 2008, 130(42):13850-1. [14] Gao W Y, Chrzanowski M, Ma S. Metal-metalloporphyrin frameworks: a resurging class of functional materials.[J]. Chemical Society Reviews, 2014, 43(16):5841-66. [15] 杨晓燕, 刘俊龙, 张绍印,等. Meso-5,10,15,20-四(对羧基苯基)卟啉配合物的合成新方法[J]. 大连工业大学学报, 2005, 24(1):26-29. [16] Wilson J N, Smith M D, Enkelmann V, et al. Cruciform pi-systems: effect of aggregation on emission.[J]. Chemical Communications, 2004, 10(15):1700-1701. [17] Chelmowski R, K#246;ster S D, Kerstan A, et al. Peptide-Based SAMs that Resist the Adsorption of Proteins[J]. Journal of the American Chemical Society, 2008, 130(45):14952-3. [18] 胡学雷, 邱立, 梅光泉,等. 八苄硫基四氮杂卟啉金属配合物的合成与表征[J]. 武汉工程大学学报, 2006, 28(2):1-4. [19] Kadish K M, Smith K M, Guilard R. Handbook of porphyrin science : with applications to chemistry, physics, materials science, engineering, biology and medicine[M]. World Scientific, 2010. [20] 师同顺, 柳巍. 四(对#8212;羟基苯基)卟啉过渡金属配合物的合成[J]. 应用化学, 1998(3):73-75.

3. 毕业设计（论文）进程安排

2016.12.29 ~ 2017.1.20 查阅文献，确定实验方法和实验条件，完成外文文献翻译和开题报告； 2017.3.11 ~ 2017.4.15 利用课题组已有基础，制备锆MOF材料，并将该MOF用于CO2的吸附；. 2017.4.16 ~ 2017.5.20 对制备的锆MOF进行一系列的改性，以提高锆MOF对CO2的吸附量，考察其吸附性能，同时测试其稳定性； 2017.5.21 ~ 2017.6.3 对所得的测试结果进行分析，完成毕业设计的相关内容。