1. 毕业设计（论文）的内容和要求

掌握过渡金属催化合成方法和原理，熟悉磷类化合物的各种合成方法，掌握合成反应的实验操作，完成合成新化合物的实验步骤和检测方法。

2. 参考文献

1 (a) Selected reviews on allene chemistry: (a) Progress in allene chemistry, ed. B. Alcaide, P. Almendros,Special issue, Chem. Soc. Rev.,2014, 43, 2879#8211;3206; (b) S. Yu and S. Ma, Angew. Chem., Int. Ed., 2013,51, 13074; (c) S. Ma, Chem. Rev., 2005, 105, 2829; (d) A. Hoffmann-Ro#168;der
and N. Krause, Angew. Chem., Int. Ed., 2004, 43, 1196.
2 (a) H. Guo, R. Qian, Y. Guo and S. Ma, J. Org. Chem., 2008, 73, 7934;(b) G. He, C. Fu and S. Ma, Tetrahedron, 2009, 65, 8035; (c) G. He,H. Guo, R. Qian, Y. Guo, C. Fuand S. Ma, Tetrahedron, 2009,65, 4877.
3 (a) K. C. K. Swamy, E. Balaraman and N. S. Kumar, Tetrahedron,2006, 62, 10152; (b) M. Chakravarty and K. C. K. Swamy, Synthesis,2007, 3171; (c) S. E. Denmark, J. E. Marlin and G. Rajendra, J. Org.Chem., 2013, 78, 66; (d) Y.-Z. Chen, L. Zhang, A.-M. Lu, F. Yang andL. Wu, J. Org. Chem., 2015, 80, 673; (e) J. K. E. T. Berton, T. S. A.
Heugebaert, W. Debrouwer and C. V. Stevens, Org. Lett., 2016, 18, 208.
4 (a) T. Nishimura, S. Hirabayashi, Y. Yasuhara and T. Hayashi, J. Am.Chem. Soc., 2006, 128, 2556; (b) T. Kawamoto, S. Hirabayashi,X.-X. Guo, T. Nishimura and T. Hayashi, Chem. Commun., 2009, 3528.
5 (a) F. Yu, X. Lian and S. Ma, Org. Lett., 2007, 9, 1703; (b) F. Yu,X. Lian, J. Zhao, Y. Yu and S. Ma, J. Org. Chem., 2009, 74, 1130;(c) P. Li, Z.-J. Liu and J.-T. Liu, Tetrahedron, 2010, 66, 9729; (d) N. Xin and S. Ma, Eur. J. Org. Chem., 2012, 3806.
6 (a) C. Mukai, M. Ohta, H. Yamashita and S. Kitagaki, J. Org. Chem.,2004, 69, 6867; (b) S. Kitagaki, Y. Okumara and C. Mukai, Tetrahedron,2006, 62, 10311; (c) Y. Gu, T. Hama and G. B. Hammond, Chem.
Commun., 2000, 395.

3. 毕业设计（论文）进程安排

2月，文献调研，论文翻译。

3-5月，实验工作。

5月底整理实验数据，撰写论文。