1. 毕业设计（论文）的内容和要求

本文设计简单的金属掺杂的碳材料，并应用于氧气体系下的苯羟基化。

与传统的浸渍法进行比较。

2. 参考文献

（1）Passoni L C, Cruz A T, Buffon R, et al. Direct selective oxidation of benzene to phenol using molecular oxygen in the presence of palladium and heteropolyacids [J]. J Mol Catal A: Chem, 1997, 120(1): 117-123. [2] Burton H A, Kozhevnikov I V. Biphasic oxidation of arenes with oxygen catalysed by Pd(II)-heteropoly acid system: oxidative coupling versus hydroxylation [J]. J Mol Catal A: Chem, 2002, 185(1): 285-290. [3] Passoni L C, Luna F J, Wallau M, et al. Heterogenization of H6PMo9V3O40 and palladium acetate in VPI-5 and MCM-41 and their use in the catalytic oxidation of benzene to phenol [J]. J Mol Catal A: Chem, 1998, 134(1): 229-235. [4] Liu Y, Murata K, Inaba M. Direct oxidation of benzene to phenol by molecular oxygen over catalytic systems containing Pd(OAc)2 and heteropolyacid immobilized on HMS or PIM [J]. J Mol Catal A: Chem, 2006, 256(1): 247-255. [5] Gao X, L#252; X, Xu J. Direct oxidation of benzene to phenol by dioxygen over nano-vanadium oxide [J]. Chin J Chem, 2009, 27(11): 2155-2158. [6] Gao X, Lv X, Xu J. Oxidation of benzene to phenol by dioxygen over vanadium oxide nano-plate [J]. Kinet Catal, 2010, 51(3): 394-397.

3. 毕业设计（论文）进程安排

3月上旬，查阅文献，掌握相关的背景知识。

3月下旬-4月下旬，以水为溶剂，自由基聚合方式合成有序介孔聚离子液体。

5月上旬-5月中旬，合成金属掺杂碳材料并应用于苯羟基化反应。