基于d-f金属构建的分子材料的设计合成及其性质研究任务书
2020-06-09 22:42:35
1. 毕业设计（论文）的内容和要求
(1) 学会查阅中外文文献资料，通过查阅文献，了解课题的背景、意义。
(2) 文献阅读量不低于15篇，翻译一篇相关的外文文献。
在老师的指导下完成开题报告的写作。
2. 参考文献
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[1] Seo J S, Whang D, Lee H, et al. A Homochiral Metal-Organic Porous Material for Enantioselective Separation and Catalysis [J]. Nature, 2000, (404): 982～986. [2] Eddaoudi M, Kim J, Rosi N, et al. Systematic Design of Pore Size and Functionality in Isoreticular MOFs and their Application in Methane Storage [J]. Science, 2002, (295): 469～472. [3 Paul G, Choudhury A, Rao C N R. Organically Templated Linear and Layered Iron Sulfates [J]. Chem. Mater., 2003, (15): 1174～1180. [4] Choudhury A, Krishnamoorthy J, Rao C N R. An Approach to the Synthesis of Organically Templated Open-Framework Metal Sulfates by The Amine-Sulfate Route [J]. Chem. Comm., 2001, (24): 2610～2611. [5] Choudhury A, Kumar D U, Rao C N R. Three-dimensional Organically Templated Open-Framework Transition Metal Selenites [J]. Angew. Chem. Int. Ed., 2002, (41): 158～161. [6] Rao C N R, Behera J N, Dan M. Organically-templated Metal Sulfates, Selenites and Selenates [J]. Chem. Soc. Rev., 2006, (35): 375～387. [7] Wickleder M S. Inorganic Lanthanide Compounds with Complex Anions [J]. Chem. Rev., 2002, (102): 2011～2087. [8] Xu Y, Ding S H, Zheng X F. Hydrothermal Synthesis, Crystal Structure and Properties of 2-D and 3-D Lanthanide Sulfates [J]. J. Solid. State. Chem., 2007, (180): 2020～2025. [9] Kim J M, Jeong Y K, Sohn Y, et al. Synthesis and Photophysical Properties of an Eu(II)-Complex/PS Blend: Role of Ag Nanoparticles in Surface-Enhanced Luminescence [J]. Langmuir, 2012, (28): 9842～9848. [10] Chiang P Y, Lin T W, Dai J. H, et al. Flux synthesis, Crystal Structure, and Luminescence Properties of a New Europium Fluoride-Silicate: K5Eu2FSi4O13 [J]. Inorg. Chem., 2007, (46): 3619～3622. [11] Guo H L, Zhu Y Z, Qiu S L, et al. Coordination Modulation Induced Synthesis of Nanoscale Eu1-XTbx-Metal-Organic Frameworks for Luminescent thin Films [J]. Adv. Mater., 2010, (22): 4190～4192. [12] Choi C L, Yen Y F, Sung H H Y, et al. Quantifying Enhanced Photoluminescence in Mixed-Lanthanide Carboxylate Polymers: Sensitization Versus Reduction of Self-Quenching [J]. J. Mater. Chem., 2011, (21): 8547～8549. [13] Tang Q, Liu S, Liu Y, et al. Color Tuning and White Light Emission via in Situ Doping of Luminescent Lanthanide Metal-Organic Frameworks [J]. Inorg. Chem., 2013, (53): 289~293. [14] Cui Y J, Zou W F, Song R J. et al. A Ratiometric and Colorimetric Luminescent Thermometer over a Wide Temperature Range Based on a Lanthanide Coordination Polymer [J]. Chem. Commun., 2014, (50): 719~721. |
3. 毕业设计（论文）进程安排
第一周查阅资料学习相关理论知识；第二周 继续学习理论知识，了解所用实验仪器的 相关操作，进行安全性实验教育学习；第三周至第五周 正式开始实验部分并完成开题报告及其相关部分；第六周至第九周进行实验并完成中期小结及其相关部分；第九周至第十三周 完成实验部分内容并完成实验数据处理的总结，准备撰写论文的材料；第十三周至第十五周 完成毕业生论文写作，完成相关毕业材料
