1. 毕业设计（论文）的内容和要求

异丁烯与乙二醇醚化反应生成乙二醇单叔丁基醚，并伴随着乙二醇二叔丁基醚、二异丁烯等副反物。

因此研发高活性、高选择性的催化剂是关键。

mofs材料最大的优点是可以通过合理的设计引入不同的官能团和调控孔道结构。

2. 参考文献

[1].沈景余. 国外乙二醇叔丁基醚的生产和利用[J]. 精细石油化工, 1996(5):45-51. [2]. 李凤琴. 乙二醇单叔丁基醚的合成及应用[J]. 合成橡胶工业, 1989(6):23-26. [3]. 宋坤. DBSA微乳催化醚化、酯化反应的研究[D]. 东北师范大学, 2008. [4]. Klep#225;#269;ov#225; K, Mravec D, Bajus M. tert -Butylation of glycerol catalysed by ion-exchange resins[J]. Applied Catalysis A General, 2005, 294(2):141-147. [5]. Frusteri F, Arena F, Bonura G, et al. Catalytic etherification of glycerol by tert -butyl alcohol to produce oxygenated additives for diesel fuel[J]. Applied Catalysis A General, 2009, 367(1#8211;2):77-83. [6]. Wang S, Guin J A. Catalytic activity of silica supported sulfated zirconia catalysts for liquid phase etherification of C6 olefins with alcohols[J]. Fuel Processing Technology, 2003, 84(1):135#8211;146. [7]. Cruz V J, Izquierdo J F, Cunill F, et al. Acid ion-exchange resins catalysts for the liquid-phase dimerization/etherification of isoamylenes in methanol or ethanol presence[J]. Reactive Functional Polymers, 2005, 65(1):149-160. [8]. Nikolopoulos A A. Etherification on Zeolites: MTBE synthesis[J]. Catalysis Reviews, 2002, 44(2):287-320. [9]. Xiao L, Mao J, Zhou J. Enhanced performance of HY zeolites by acid wash for glycerol etherification with isobutene[J]. Applied Catalysis A General, 2011, 393(1):88#8211;95. [10]. Knifton J F, Edwards J C. Methyl tert -butyl ether synthesis from tert -butanol via inorganic solid acid catalysis[J]. Applied Catalysis A General, 1999, 183(1):1-13. [11]. Lee H J, Seung D, Jung K S, et al. Etherification of glycerol by isobutylene: Tuning the product composition[J]. Applied Catalysis A General, 2010, 390(1#8211;2):235-244. [12]. Luo D, Corey R, Propper R, et al. Comprehensive environmental impact assessment of exempt volatile organic compounds in California[J]. Environmental Science Policy, 2011,14, 585-593. [13]. Huang H, Li J R, Wang K, et al. An in situ self-assembly template strategy for the preparation of hierarchical-pore metal-organic frameworks [J]. Nature Communications, 2015, 6:8847. [16]. Jin Y, Shi J, Zhang F, et al. Synthesis of sulfonic acid-functionalized MIL-101 for acetalization of aldehydes with diols[J]. Journal of Molecular Catalysis A Chemical, 2014, s 383#8211;384(1):167-171. [17]. Chung Y M, Kim H Y, Ahn W S. Friedel#8211;Crafts Acylation of p -Xylene over Sulfonated Zirconium Terephthalates[J]. Catalysis Letters, 2014, 144(5):817-824. [18]. Zhang G, Wei G, Liu Z, et al. A Robust Sulfonate-Based Metal#8211;Organic Framework with Permanent Porosity for Efficient CO2 Capture and Conversion[J]. 2016. [19]. Goesten M G, Juan-Alca#241;iz J, Ramos-Fernandez E V, et al. Sulfation of metal#8211;organic frameworks: Opportunities for acid catalysis and proton conductivity[J]. Journal of Catalysis, 2011, 281(1):177-187. [20]. Chen J, Li K, Chen L, et al. Conversion of fructose into 5-hydroxymethylfurfural catalyzed by recyclable sulfonic acid-functionalized metal#8211;organic frameworks[J]. Green Chemistry, 2014, 16(5):2490-2499. [21]. Jiang J, G#225;ndara F, Zhang YB,等. Superacidity in sulfated metal-organic framework-808.[J]. Journal of the American Chemical Society, 2014, 136(37):12844-7.

3. 毕业设计（论文）进程安排

（1）2018/01/10-2018/02/05:查阅mof相关文献，找出合理调控孔径的方法。

（2）2018/02/06-2018/03/05:撰写文献综述和开题报告。

（3）2018/03/05-2018/03/25：制备十种不同孔径载体及催化剂。